The problem of of the use of fly ash still constitutes a research and exploration area for scientists. This is due to the fact that, 6,000,000 Mg of coal combustion by-products (CCB) are storage on landfills yearly in Poland alone. One of the potential directions of using fly ash is to use it as a substrate in hydrothermal syntheses of mesoporous materials (synthetic zeolites). Zeolites are aluminosilicates with a spatial structure. Due to their specific structure they are characterized by a number of specific properties among others molecular-sieve, ion-exchange and catalytic that can be used in engineering and environmental protection. So far, the synthesis has been carried out using coal combustion by-products such as fly ash or microsphere. The article analyzes whether separation from the fly ash of the appropriate fraction (below 63 μm) will affect the formation of zeolite grains. The syntheses were carried out using class F fly ash and the fraction separated from it, which was obtained by sieving the ash through a 63 μm sieve. Chemical (XRF) and mineralogical (XRD, SEM-EDS) analyzes were carried out for substrates as well as the obtained reaction products. In the case of substrates, the analysis did not show any significant differences between the ash and the separated fraction. However, in products after synthesis (Na-X zeolite with a small amount of Na-P1 zeolite, and small amounts of quartz and unreacted aluminosilicate glass - mullite) higher aluminum and sodium contents were observed from the separated fraction, with a lower calcium and potassium content. A small proportion of illite was observed on the diffraction curve of the zeolite from the fraction. Observations of grain morphology showed no differences in formation. Based on the conducted analyzes, it can be stated that, considering the economics of the synthesis process, the separation of fine fractions from the fly ash does not affect the quality of the synthesis process.
The article is an attempt to analyze the spatio-pedagogical discourse of the German social pedagogy. It represents only a fragment of reflection on the turns in paradigm of place/ space (spatial turn), as pedagogical terms. & e authors seek to answer the question what is the space and place, and what concepts in the field of reflection on the place/space run in the German social pedagogy. The text introduces, inter alia, the relational concept of space developed by Martina Löw, duality of space and the concept of spacing. Active creation of urban space, the spatial dimension of the relationship and its dynamics are subjected to discussion. The article presents critical approach to the notion of transdisciplinary space, and space-oriented social work. Finally, it provides the incentive for in-depth, international analyzes of spatio-pedagogical theories.
Attempts to perform synthesis of a passive vibroinsulation two-mass system intended for the simultaneous reduction of machine frame vibrations and forces transmitted to foundations by supporting elements were undertaken in the study. In view of the variable frequency of the machine operation, it was necessary for the frequency interval, encompassed by the vibroinsulation system operation, to be within given limits. On the grounds of properties of the linear massive-elastic system formulated in the works of Genkin and Ryaboy (1998), the problem of vibroinsulation system synthesis was formulated in the parametric type optimisation approach with equality and inequality limitations. For piston compressor vibroinsulation, the mass and elasticity matrices of the vibroinsulating system, as well as its physical structure, were determined. Its operation was verified on the basis of simulation investigations, taking into account the system loss and transient states.
Nano-sized yttria (Y2O3) powders were synthesized by a polymer solution route using polyvinyl alcohol (PVA) as an organic carrier. The PVA polymer affected the dispersion of yttrium ions in precursor sol. In this study, three kinds of PVA polymer (different molecular weight) were applied for synthesis of yttria powder. The PVA type as well as calcination temperature had a strongly influence on the particle morphology. Single crystal nano wire particles were observed at the temperature of polymer burn out range and the size was dependent on the PVA type. The stable, fully crystallized yttria powder was obtained through the calcination at 800°C for 1 h. The yttria powder prepared with the high weight PVA (MW: 153,000) revealed a particle size of 30 nm with a surface area of 18.8 m2/g.
In the paper we consider fast transformation of a multilevel and multioutput circuit with AND, OR and NOT gates into a functionally equivalent circuit with NAND and NOR gates. The task can be solved by replacing AND and OR gates by NAND or NOR gates, which requires in some cases introducing the additional inverters or splitting the gates. In the paper the quick approximation algorithms of the circuit transformation are proposed, minimizing number of the inverters. The presented algorithms allow transformation of any multilevel circuit into a circuit being a combination of NOR gates, NAND gates or both types of universal gates.
In the paper the squared voltage-current functionals are minimized, which represent the global power losses in the network. In that way it is possible to find the voltage-current distributions on the net without the use of immitance operators and basing only on the Kirchhoff laws. Farther the individual branch parameters are defined in the syntheses process. Many optimal power analysis examples are also shown to illustrate the thesis included in the paper.
The paper deals with linear circuits synthesis with periodic parameters. It was proved that the time-varying voltages and currents of inner branches of such circuits can be calculated using linear recursive equations with periodic coefficients if signals on port are given. The stability theorem of periodic solution was formulated. Hereby described the synthesis problems appear when compensation of power supply systems is considered.
Because of excellent properties, similar to natural bone minerals, and variety of possible biomedical applications, hydroxyapatite (HAp) is a valuable compound among the calcium phosphate salts. A number of synthesis routes for producing HAp powders have been reported. Despite this fact, it is important to develop new methods providing precise control over the reaction and having potential to scale-up. The main motivation for the current paper is a view of continuous synthesis methods toward medical application of produced hydroxyapatite, especially in the form of nanoparticles.
In August 2016, tomato plants grown during a hot, wet summer with heavy soil flooding, displaying symptoms of wilting, dead plant, root rot with crown and stem rot, at Beni Suef and Fayoum governorates were examined. A number of 16 fungal isolates were isolated from tomato plants displaying the above symptoms. These isolates were classified as belonging to six species, namely: Alternaria solani, Chaetomium globosum, Fusarium solani, Fusarium oxysporum, Pythium spp. and Rhizoctonia solani. Isolates of Pythium spp. were prevalent and were found to be more pathogenic than the other fungal isolates. This species causes damping-off, root rot, sudden death, stem rot and fruit rot. The pathogen was identified as Pythium aphanidermatum based on morphological, cultural, and molecular characteristics. Biogenic silver nanoparticles (AgNPs) were produced using the F. oxysporum strain and characterized by transmission electron microscopy (TEM). The size of these spherical particles ranged from 10 to 30 nm. In vitro, biogenic AgNPs showed antifungal activity against P. aphanidermatum. In greenhouse and field experiments, AgNPs treatment significantly reduced the incidence of dead tomato plants due to root rot caused by P. aphanidermatum compared to the control. All of the investigated treatments were effective and the treatment of root dipping plus soil drenching was the most effective. To the best of our knowledge, this study describes P. aphanidermatum on tomato in Egypt for the first time. Also, biogenic AgNPs could be used for controlling root rot disease caused by this pathogen.
A method for manufacturing of Al-Si alloy (EN AC-44200) matrix composite materials reinforced with MAX type phases in Ti-Al-C systems was developed. The MAX phases were synthesized using the Self-propagating High-Temperature Synthesis (SHS) method in its microwave assisted mode to allow Ti2AlC and Ti3AlC2 to be created in the form of spatial structures with open porosity. Obtained structures were subjected to the squeeze casting infiltration in order to create a composite material. Microstructures of the produced materials were observed by the means of optical and SEM microscopies. The applied infiltration process allows forming of homogeneous materials with a negligible residual porosity. The obtained composite materials possess no visible defects or discontinuities in the structure, which could fundamentally deteriorate their performance and mechanical properties. The produced composites, together with the reference sample of a sole matrix material, were subjected to mechanical properties tests: nanohardness or hardness (HV) and instrumental modulus of longitudinal elasticity (EIT).
Preparation and properties of hierarchically structured porous silica monoliths have been discussed from the viewpoint of their application as continuous microreactors for liquid-phase synthesis of fine chemical in multi kilogram scales. The results of recent topical papers published by two research teams of Institute of Chemical Engineering Polish Academy of Sciences (ICE) and Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology (SUT) have been analyzed to specify the governing traits of microreactors. It was concluded that even enhancement factor of 100 in activity, seen in enzyme catalyzed reactions, can be explained by a proportional reduction of its physical constraints, i.e. huge enhancement of external mass transfer and micromixing. It is induced by very chaotic flows of liquid in tens of thousands of waving connected channels of ca. 25–50 mm in diameter, present in the skeleton. The scale of enhancement in the case of less active catalysts was smaller, but still large enough to consider the most practical applications.
In this paper a new pitch shifter using a complex instantaneous frequency rescaler and direct digital synthesizer is presented aimed at an application in a handset calling signal composer. The pitch shifter introduced here exhibits an excellent performance as a generator of different melodies, where the sound of each note in a melody, e.g., imitating a popular hit, is derived from a short recording of a voice of a chosen creature via complex dynamic representation processing.
In this paper, explain the preparation of CaTiO3 ceramics synthesized by the solid-state reaction method. Calcium carbonate and titanium dioxide were high energy mixed in stoichiometric amounts, and the obtained mixture was calcined at different temperatures (800, 900, 1000 and 1300ºC) for 2 h. The obtained samples were characterized by measurement of particle size, Energy Dispersive X-Ray (EDX) Analysis; differential thermal analysis, X-ray diffraction and SEM images. XRD patterns indicated that CaTiO3 ceramics with the structure of perovskite is obtained from calcined powders at 1,300°C for 2 h. SEM images show the formation of a very fine and homogeneous morphology. The measured values of electrical resistivity were within the typical range of insulating materials and approach values corresponding to insulating ceramics.
The paper presents optimization of 5-rod (5-link) suspension mechanism used in passenger cars for independent guiding of the wheels. Selected stiffness coefficients defined for five elastomeric bushings installed in joints of the suspension rods are considered as design variables. Two models with lumped parameters (i.e. elastokinematic and dynamic) of wheel-suspension-car body system are formulated to describe relationships between the design variables and the performance indexes including car active safety and ride comfort, respectively. The multi-criteria goal function is minimized using a deterministic algorithm. The suspension with optimized bushings rates fulfils desired elastokinematic criteria together with a defined dynamic criterion, describing the so-called rolling comfort. An event of car passing over short road bump is considered as dynamic conditions. The numerical example deals with an actual middle-class passenger car with 5-rod suspension at the front driven axle. Estimation of the models parameters and their verification were carried out on the basis of indoor and outdoor experiments. The proposed optimization procedure can be used to improve the suspension design or development cycle.
Fe-40wt% TiB2 nanocomposites were fabricated by mechanical activation and spark-plasma sintering of a powder mixture of iron boride (FeB) and titanium hydride (TiH2). The powder mixture of (FeB, TiH2) was prepared by high-energy ball milling in a planetary ball mill at 700 rpm for 3 h followed by spark-plasma sintering (SPS) at various conditions. Analysis of the change in relative sintered density and densification rate during sintering showed that a self-propagating high-temperature synthesis reaction occurs to form TiB2 from FeB and Ti. A sintered body with relative density higher than 98% was obtained after sintering at 1150°C for 5 and 15 min. The microstructural observation of sintered compacts with the use of FE-SEM and TEM revealed that ultrafine particulates with approximately 5 nm were evenly distributed in an Fe-matrix. A hardness value of 83 HRC was obtained, which is equivalent to that of conventional WC-20 Co systems.
In the paper, two preprocessing methods for virtual view synthesis are presented. In the first approach, both horizontal and vertical resolutions of the real views and the corresponding depth maps are doubled in order to perform view synthesis on images with densely arranged points. In the second method, real views are filtered in order to eliminate blurred or improperly shifted edges of the objects. Both methods are performed prior to synthesis, thus they may be applied to different Depth-Image-Based Rendering algorithms. In the paper, for both proposed methods, the achieved quality gains are presented.
The work presents results of solution combustion method utilization for yttria (Y2O3) nanopowder fabrication. Experiments were carried out with four different reducing agents: urea, glycine, citric acid and malonic acid added in stoichiometric ratio. The reactions were investigated using simultaneous DSC/DTA thermal analysis. After synthesis the reaction products were calcined at temperature range of 800-1100°C and analyzed in terms of particle size, specific surface area and morphology. Best results were obtained for nanoyttria powder produced from glycine. After calcination at temperature of 1100°C the powder exhibits in a form of nanometric, globular particles of diameter <100 nm, according to SEM analysis. The dBET for thus obtained powder is 104 nm, however the powder is agglomerated as the particle size measured by dynamic light scattering analysis is 1190 nm (dV50).
In this paper, a modification of the graph-based depth estimation is presented. The purpose of proposed modification is to increase the quality of estimated depth maps, reduce the time of the estimation, and increase the temporal consistency of depth maps. The modification is based on the image segmentation using superpixels, therefore in the first step of the proposed modification a segmentation of previous frames is used in the currently processed frame in order to reduce the overall time of the depth estimation. In the next step, a depth map from the previous frame is used in the depth map optimization as the initial values of a depth map estimated for the current frame. It results in the better representation of silhouettes of objects in depth maps and in the reduced computational complexity of the depth estimation process. In order to evaluate the performance of the proposed modification the authors performed the experiment for a set of multiview test sequences that varied in their content and an arrangement of cameras. The results of the experiments confirmed the increase of the depth maps quality — the quality of depth maps calculated with the proposed modification is higher than for the unmodified depth estimation method, apart from the number of the performed optimization cycles. Therefore, use of the proposed modification allows to estimate a depth of the better quality with almost 40% reduction of the estimation time. Moreover, the temporal consistency, measured through the reduction of the bitrate of encoded virtual views, was also considerably increased.
The aim of this paper is to present methods of digitally synthesising the sound generated by vibroacoustic systems with distributed parameters. A general algorithm was developed to synthesise the sounds of selected musical instruments with an axisymmetrical shape and impact excitation, i.e., Tibetan bowls and bells. A coupled mechanical-acoustic field described by partial differential equations was discretized by using the Finite Element Method (FEM) implemented in the ANSYS package. The presented synthesis method is original due to the fact that the determination of the system response in the time domain to the pulse (impact) excitation is based on the numerical calculation of the convolution of the forcing function and impulse response of the system. This was calculated as an inverse Fourier transform of the system’s spectral transfer function. The synthesiser allows for obtaining a sound signal with the assumed, expected parameters by tuning the resonance frequencies which exist in the spectrum of the generated sound. This is accomplished, basing on the Design of Experiment (DOE) theory, by creating a meta-model which contains information on its response surfaces regarding the influence of the design parameters. The synthesis resulted in a sound pressure signal in selected points in space surrounding the instrument which is consistent with the signal generated by the actual instruments, and the results obtained can improve them.
The study presents the results of research on the development of composite zones in castings based on the intermetallic phase of Ni3Al. Composite zones were obtained by placing packets with substrates for the reaction of titanium carbide in a foundry mould. To provide a variable carbides content in the composite zone, two compositions of the packets were prepared. The first packet contained only substrates for the reaction of TiC synthesis; the second one also contained a filler. The resulting composite zones in castings were examined for the filler effect on changes in the volume fraction, size and morphology of carbides in the zone. In addition, the effect of filler on the mechanical properties of the zone was verified, observing changes of Vickers hardness in this area. It was found that the presence of filler in the composition of the packet for synthesis reduced the content of carbides, as well as their size and morphology. Lower surface content of carbides reduced hardness of the zone, which enabled smooth control of the mechanical properties. At the same time, the use of the selected filler did not disturb the course of the TiC carbide synthesis.
The aim of the present study was to develop a modifier for water glass. The method of thermal generation of metal oxide nanoparticles was adapted and used in the research. Nanoparticles of ZnO from the thermal decomposition of basic zinc carbonate were used. A method for the modifier introduction was developed, and the effect of modifier content and organic solvent type on the physico-chemical properties of binder (viscosity) and quartz wettability was determined. Binder viscosity was examined from the flow curves plotted with the help of a RHEOTEST 2 rotational rheometer equipped with proper software. Quartz wettability was determined examining timerelated changes in the value of the contact angle in a quartz-binder system, until full stabilisation of the angle value has been achieved. Binder modification was carried out on sodium water glass designated as R"145". The water glass modifiers were suspensions of ZnO nanoparticles in propanol and methanol at a fixed concentration of c = 0.3 M and with the size of nanoparticles comprised in a range of <61 - 981 nm>. Water glass modification with the suspensions of ZnO nanoparticles in methanol and propanol showed the effect of modifier on the water glass viscosity and quartz wettability. This effect depends on the type of alcohol used. The ZnO suspension in propanol (alcohol with a longer hydrocarbon chain) affects more strongly the viscosity of binder and quartz wettability than the methanol suspension.
The synthesis problem for optimal control systems in the class of discrete controls is under consideration. The problem is investigated by reducing to a linear programming (LP) problem with consequent use of a dynamic version of the adaptive method of LP. Both perfect and imperfect information on behavior of control system cases are studied. Algorithms for the optimal controller, optimal estimators are described. Results are illustrated by examples.
Y2O3-MgO nanocomposites are one of the most promising materials for hypersonic infrared windows and domes due to their excellent optical transmittance and mechanical properties. In this study, influence of the calcination temperature of Y2O3-MgO nanopowders on the microstructure, IR transmittance, and hardness of Y2O3-MgO nanocomposites was investigated. It was found that the calcination temperature is related to the presence of residual intergranular pores and grain size after spark plasma sintering. The nanopowders calcined at 1000°C exhibits the highest infrared transmittance (82.3% at 5.3 μm) and hardness (9.99 GPa). These findings indicated that initial particle size and distribution of the nanopowders are important factors determining the optical and mechanical performances of Y2O3-MgO nanocomposites.