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Abstract

In recent years, more and more attention has been paid to the quality of produced coal size categories for energy purposes. This is important from the perspective of promoting clean coal technologies which aim at changing the perception of coal as a fuel friendly for the environment. This is specifically because hard coal resources in Poland allow the national energy security to be guaranteed on the basis of energy production based on hard coal. Fine coals upgraded at coal processing facilities in the separation process in fine coal jigs are mainly used in energy production from coal. In the article, an analysis of hard coal upgrading in a jig regarding the optimum recovery of a useful fraction in the concentrate (combustible and volatile matter) and non-useful fraction in tailings (ash and sulfur) was conducted. Based on the industrial testing of a fine coal jig, the granulometric and densimetric analysis of the taken samples of concentrate, middlings and tailings of coal was conducted in laboratory conditions. Yields of products were calculated in separated size-fractions of separation products, and ash content and total sulfur content were determined in them. Based on the results of granulometric, densimetric and chemical analyses of the obtained size-fractions, the balance of separation products and appropriate calculations, Fuerstenau upgrading curves which allowed the process to be evaluated and a comparison of the results of hard coal upgrading regarding the optimum recovery of the organic phase in the concentrate and mineral components in tailings to be drawn. The obtained results were evaluated on the basis of different criteria for changing the device’s hydrodynamic operational conditions. The ash content and total sulfur content were analyzed as non-useful substances.
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Abstract

The aim of this work was to determine the influence of various variants of bioleaching on effectivity of releasing chosen critical metals: rhodium, cadmium, indium, niobium and chromium from ashes which are a byproduct of municipal waste and sewage sludge thermal processing. The research was conducted in 3 variants that considered different process factors such as temperature (24ºC and 37ºC), mixing intensity and aeration. After 5 days of the process the analyses were made of metals content, sulfate concentration, pH, general number of bacteria number, index of sulfur oxidizing bacteria. The best results of bioleaching were achieved by running the process at the temperature of 24ºC with aeration. The efficiency of rhodium and cadmium release from the byproduct of municipal waste thermal processing was above 90%. The efficiency of indium and chromium release reached 50–60%. Only niobium leached better in mixing conditions. The byproduct of sewage sludge thermal processing was far less susceptible to bioleaching. The highest effectivity (on a level of 50%) was reached for indium in temperature of 24°C with aeration. The efficiency of bioleaching depended on waste’s physiochemical properties and type of metal which will be released. Aeration with compressed air had a positive influence on the increase of sulfur oxidizing bacteria what corresponded with almost double increase of sulfate concentration in leaching culture. Such conditions had a positive influence on the increase of the efficiency of bioleaching process. Heightening the temperature to 37°C and slowly mixing did not impact bioleaching in a positive way.
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Abstract

The combined effect of sulfur (S) and acid soluble aluminum (Als) content on precipitates and microstructures in grainoriented silicon steel were investigated. The results show that there are dominant AlN and a little amount of MnS-AlN composite in annealed hot-rolled band, and the amount of precipitates increases distinctly with increasing Als content, while S content plays a negligible role. The inhibitors that precipitate during hot band annealing can restrain the grain growth during hot band annealing and primary annealing, and the smaller grains of annealed hot-rolled band can contribute to the formation of {111} <112> texture during primary annealing. Lower S content is conducive to the formation of {111} <112> texture during primary annealing by promoting the formation of Goss texture during hot rolling.
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