Molybdenum disulfide (MoS2) is one of the most widely used solid lubricants applied in different ways on the surfaces under friction. In this work, AISI 316 austenitic stainless steel was coated with MoS2, using chemical vapor deposition (CVD) at four different temperatures (400, 500, 600 and 700°C). Coatings properties were investigated using SEM, EDX, XRD and FTIR, Hardness Tester and Roughness tester. The results showed that with simultaneous evaporation of sulfur and molybdenum trioxide (MoO3) in the CVD chamber, a uniform coating layer containing MoS2 and MoO2 phases was formed. Increase in the substrate temperature resulted in the rise in the amount of MoS2 to MoO2 phases. The thickness, grain size and the hardness of the coating were 17-29 μm, 50-120 nm and 260-480 HV respectively. Friction tests carried out using pin-on-plate method under normal loads of 10 N under ambient conditions showed values of the friction coefficient 0.25-0.40.
The article presents results of studies of silicon – molybdenum cast iron (4.42% Si, 2.59% Mo and 2.48% C wt.-%) crystallization process. Metallographic analysis was carried out using SEM-scanning electron microscopy with the EDS system. In order to determine the phase composition, X-ray diffraction studies were performed. Thermo-Calc, a computer simulation program, was used to simulate the crystallization process. . The obtained data allowed to describe the effect of some elements on the crystallization process. The silicon phase of MnSi could not be identified during metallographic studies. Also, computer simulation of the crystallization process did not answer the question at which point the silicon phase of MnSi crystallizes in the tested alloy. Therefore, not all results obtained were linked to the registered crystallization process (TDA process). The EDS analysis revealed an unusual distribution of molybdenum in the microstructure of the sample, where it is clearly visible that the area enriched with this element is also the separation of spheroidal graphite. The possibility of occurrence of Mo-rich micro-areas found in graphite is considered. The case is debatable and difficult to resolve at this stage. Perhaps, at such a high concentration of molybdenum (2.59% Mo) in the alloy, conditions are created for simultaneously crystallization of graphite and molybdenum phases.
This work is dealing with the impact of molybdenum on the structure properties of commercial cast AlSi10Mg(Cu) alloy. The solidification path of AlSi10Mg(Cu) alloy with various content of molybdenum has been investigated using cooling curve techniques. The samples for testing have been poured into permanent steel mold. The content of molybdenum has been varied from 0 to 0.20 wt. %.The desired chemical composition was achieved by adding of master alloy AlMo10 into commercial AlSi10Mg(Cu) alloy. The micro hardness of as cast alloys with different content of molybdenum has been measured. The microstructure and EDX analysis from the casted samples has been carried out. The results show that molybdenum in commercial AlSi10Cu(Mg) alloy precipitate in the interdendritic region isolated in the form of Al(FeMnMoMg)Si rich intermetallic. The increased content of molybdenum increase slightly liquidus temperature, prolonging precipitation of the last eutectic and surprisingly decrease the micro hardness of commercial alloy for approximately 16 %.