The article characterizes geological formations occurring in the Polish lignite deposits having the characteristics of raw materials, i.e. accompanying minerals, giving their location, quality characteristics, estimated resources and potential applications. Attention has also been paid to the economic suitability, e.g. in infrastructure works and for the reclamation of many geological formations found in the overburden, classified as so-called earth or rock mass. There are also raw materials of sorption properties representing a huge potential source of minerals valuable for the economy and environmental protection. This refers to e.g.: beidellite clays from Bełchatów, Poznań clays from the region of Konin and Adamów, lacustrine chalk from Bełchatów, as well as Mesozoic limestone from the lignite bedding in Bełchatów. The reasons for the unsatisfactory use of accompanying minerals have been given. The authors described the methods used in the mining operation and processing of associated minerals, also applicable in Poland, as the legal basis for the extraction of these minerals and the economic and financial conditions. They stressed the need to protect mined not associated minerals used by the construction of anthropogenic deposits. This activity primarily requires regulating the legal status of these deposits and the development and application of an economic and financial system that stimulates the economy of these minerals. In summary, the necessary actions were taken to increase the use of the accompanying minerals and their contribution to the balance of mineral resources in the country.