The study presents the results of the research into different phosphorus forms in the bottom sediments of anthropogenic limnic ecosystems i.e. the reservoirs of Pławniowice, Rybnik and Goczałkowice (SP). The bottom sediments of dam reservoirs were investigated by chemical extraction procedure for phosphorus forms. The lowest value of the mean AAP form percentage in the Pławniowice bottom sediments reflected the effect of reclamation with the hypolimnetic removal that had been conducted in the reservoir since 2003. The highest percentage of the RDP form (2%) was found in the Goczałkowice bottom sediments. The order of the specific speciation forms in the bottom sediments of the examined reservoirs was: Rybnik: AAP > EP > WDP > RDP; 4,630> 3,740 > 117 > 65 > 3.5 mgP/kg Pławniowice: AAP > EP > WDP > RDP; 916 > 783 > 107 > 15 > 1.4 mgP/kg Goczałkowice: AAP > WDP > EP > RDP; 686 > 628 > 51 > 7 > 0.14 mgP/kg The mutual correlations between the phosphorus speciation forms (AAP : EP : WDP : RDP) were as follows: Rybnik: 1,323 : 1,068 : 33 : 18 : 1; Pławniowice: 654 : 559 : 76 : 11 : 1; Goczałkowice: 4,900 : 4,485 : 364 : 50 : 1. The comparison of the mean concentration values for specific phosphorus forms in the bottom sediments of the three investigated reservoirs demonstrated that the Rybnik sediments had the highest contents of phosphorus. The contents in Pławniowice and Goczałkowice were 5-7 times lower
Water and bottom sediment samples collected from a few fish-breeding ponds/reservoirs were subjected to tests. The aim of this paper was to determine the total content of aluminium and its fractions in the samples tested to estimate the potential risk to fish caused by the toxic forms of aluminium. The monomeric inorganic aluminium in waters was determined using the ion exchange and extraction-colorimetric method with oxychinoline according to Barnes's-Driscoll's procedure. The bottoms were fractionated using a three-step sequential extraction procedure and the microwave mineralisation. The total content of aluminium in waters and extracts was determined using the spectrophotometric method with eriochromocyanine R, and comparatively using the ICP OES technique. The results were subjected to statistical analysis. The level of concentration of labile Al in the waters about 26-34 μg/dm3 and content of exchangeable Al 5-34 mg/g range in bottom sediments are possibly hazardous to aquatic organisms.
The research objective was to study temporal and spatial relations between specific phosphorus species as well as to examine total phosphorus content in the bottom sediments of an anthropogenic, hypertrophic limnic ecosystem Rybnik Reservoir, functioning under thermal pollution conditions. The chemical extraction procedure for the speciation of bioavailable phosphorus forms was used. It was found that available algae phosphorus was the most dominant phosphorus species in both sediment layers (83%), while the lower share was readily desorbed phosphorus form (0.1%). The phosphorus species concentrations depended on the organic matter concentration. The differences between phosphorus species contents in the upper (5 cm) and lower (15–20 cm) sediment core layers were low. The biologically active sediment layer extended from the sediment surface to at least 20 cm depth of the sediment core. Distributions of the concentrations within the year and at specific sampling points resulted from the variability observed for particular points and transformation intensity. Furthermore in the following study, the reaction rate constant for the increase and decrease in the concentrations of the phosphorus species in sediments was given. It was indicated that the speed of the phosphorus species transformations was affected by the environment temperature. In the heated water discharge zone (water temp. 17–35°C) the concentrations of selected speciation phosphorus forms increased more than in the dam zone (5–25°C). It was also found that the abundance of the bottom sediments with phosphorus species was related to the oblong and transverse asymmetry of reservoir depth.
The object of the investigation was metal contamination of bottom sediments of the Skroda and Chwaliszówka rivers, which are the right contributaries of the Lusatian Neisse river, draining the territory of the so called “anthropogenic lake district”. The district came into existence as a result of mining activities in the border of Silesia and Lusatia, which date from the half of 19th century to 1974. The district includes about 100 reservoirs, of the total area of over 150 ha, which are from about 30 to 100 years old. The rocks accompanying the Miocene coal-bearing formations were deposited on waste dumps. The dumps form embankments of the aquifers arising as a result of post-exploitation mining subsidence. The streams dewatering waste dumps inflow directly or indirectly to the Chwaliszówka and Skroda rivers. The pyrite is the mineral present in mine waste material. The pyrite weathering products inflow into surface waters and affect adversely the water quality. In the last stage of migration the pollutants are accumulated in the bottom sediments of rivers and lakes. The samples of bottom sediments of the two rivers were analysed by means of a five-step sequential extraction procedure performed for the partitioning of selected trace metals (Fe, Mn, As, Cr and Al). It was determined that the bottom sediments of the two analysed rivers contain significant concentrations of aluminium and iron. The concentrations of other metals (Mn, Cr and As) are in the range of geochemical background of water sediments in Poland. Concentrations of arsenium, chromium and manganese, which are bound to easy-available fractions (I – exchangeable and II – bound to carbonates) are not significant, so it could be assumed that they are not expected to be released and they do not threaten the river ecological system. There is, however, the possibility of the aluminium and iron re-mobilisation, taking into account the high concentrations of easy-available fractions of these metals in the sediment. Fe and Al are potential source of water contamination, and re-mobilisation of these metals will produce the aggravation of quality parameters of river waters.
On the ground of results obtained by the seismoacoustic profiling carried out in 1985 and primary examination of core samples the following main seismoacoustic units are distinguished and characterized: unit A — bedrock, unit B — till and/or compacted glaciomarine deposit, unit C — glaciomarine ice-front deposit, unit D — glaciomarine mud. These results enabled to present the distribution of seismoacoustic units along the fiord and its extension on the shelf, as well as to determine a relation of bottom structures to Late Vistulian(?) deglaciation and the action of Holocene tributary glaciers, probably during the Little Ice Age. The position of marginal structures corresponding to local retreat stages of the glacier front is also presented.
This article presents characteristics of the Quaternary deposits and landforms of Ebbadalen, the Nordenskióldbreen foreląnd and the Wordiekammen massif on the basis of geomorphological mapping of this area and a number of geologic profiles A—L studied in detail. Glaciers were much more expanded during the Pleistocene than they are nowadays. Over a period referred to by the present authors as the Petuniabukta-Adolfbukta Stage they occupied the whole Ebbadalen area and the eastern part of Adolfbukta. Marine terraces of 70- 80, 60—65 and 50—55 m a.s.l. were formed earlier. At the turn of the Pleistocene three marine terraces were produced at 40—45, 30—35 and 20—25 m a.s.l. Throughout the Early Holocene transgression (the Ebbadalen Stage = the Thomsondalen Stage) glaciers occurred in nearly the entire Ebbadalen area and occupied a larger part of Adolfbukta than nowadays. During the Middle and Late Holocene marine terraces of 12—15, 5—8, 3—4 and 1—2 m a.s.l. were initiated. Two more glacier advances, the later relating to the Little Ice Age, took place during the Late Holocene
The paper presents results of investigations of bottom sediments in Hornsund, Wijdefjorden and Isfjorden as well as of the shelf around the Bjornoya. carried out in 1982—1985 by a continuous seismic profiling. Geophysic structures and bottom sediments on the bedrock to a depth of 170 ms have been recognized, particularly in the Hornsund region. The following seismoacoustic units have been distinguished: unit A — bedrock, unit В — till and/or compacted glaciogenic deposit, unit С — glaciomarine ice-front deposit, unit D — glaciomarine mud. These results allowed to present a model of glaciomarine sedimentation in a fiord, fed by warm tidewater glaciers.
The aim of the presented research was to analyse the pollution of the Kozłowa Góra Dam Reservoir with PCBs (28, 52, 101, 118, 138, 153, 180) and heavy metals (Zn, Cu, Ni, Cd, Pb, Cr). The investigated water and bottom sediments were sampled from two sampling points in November, 2009. The sampling points were located in the southern part of the Kozłowa Góra Dam Reservoir. The samples of bottom sediments were taken from the surface layer of 5 cm thickness. The extraction of PCBs from the bottom sediments was performed according to the EPA 3550B standard. For the sequential extraction analysis of metals from the sampled bottom sediments, the method suggested by Tessier was applied. Based on the obtained results the water and bottom sediments from the Kozłowa Góra Dam Reservoir were polluted with polychlorinated biphenyls. The highest concentration of the investigated PCB congeners in bottom sediments was determined in the sampling point No. 1 (2.78 µg/kg d.m.), whereas in the sampling point No. 2 this level was over 20-fold lower which might result from the inflow of these compounds with the waters of the Brynica river. In both sampling points the investigated bottom sediments were predominated by higher chlorinated PCBs with comparable contents of 86% and 85%, respectively. The level of pollution in the investigated bottom sediments (calculated per dry matter) with polychlorinated biphenyls did not exceed the level of TEL (< 0.02 mg/kg). The PEL value (3.5 mg/kg) was exceeded in the case of cadmium in the bottom sediment from the sampling point No. 2 and also lead (91 mg/kg) from both sampling points. The first two fractions with the mobile forms of metals are the most sensitive fractions to any changes of the environmental conditions in the benthic zone. In those fractions significant contents of lead, cadmium, nickel and zinc were observed.
The aim of this study was to examine the pollution level of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs) and selected chloroorganic pesticides (HCH isomers, DDT and its metabolites, aldrin, dieldrin, endrin, heptachlor, endosulfan I and II, and methoxychlor) in surface sediments from selected fjords, tidal plains and lakes from the North Svalbard area. The sediments were collected from 34 sampling stations in July 2005. Only endosulfan I and methoxychlor, among selected chloroorganic pesticides, were measured in concentrations near detection limit (LoD) in fourteen sediment samples. The sum of seven PCB congeners varied from < 0.9 to 5.6 ng g-1 d.w. in sediments from fjords and tidal plains and from < 0.1 to 14.6 ng g-1 d.w. in sediments from lakes. The concentrations of analysed PAH compounds in surface sediments from lakes were over ten times higher (Ʃ16PAHs to 429 ng g-1 d.w.) than in sediments from fjords and tidal plains (Ʃ16PAHs to 36 ng g-1 d.w.).
The objective of this research is to determine the impact of waves on the segregation of sediment within the area of its supply in the context of meteorological conditions. The research was conducted on a 4 km section of the shore of Calypsostranda (Bellsund, West Spitsbergen), shaped by waves such as swell, wind waves, and tides. Particular attention was paid to the diversity and variability of the surface texture within the intertidal zone. Meteorological measurements, recording of wave climate, as well as analysis of the grain-size distribution of the beach sediments were performed. Nearshore bathymetry, longshore drifts, episodic sediment delivery from land, as well as resistance of the shore to coastal erosion and direction of transport of sediments in the shore zone are important factors controlling shore development. Data show that wind waves contribute to erosion and discharge of material from the nearshore and intertidal zone. The research also shows that oceanic swell, altered by diffraction, reaching the shore of Calypsostranda contributes to better sorting of sediment deposited on the shore through washing it out from among gravels, and longshore transport of its finest fraction. The grain size distribution of shore sediments is significantly changed already during one tidal cycle. The degree of this modification depends not only on wave height and period but on the direction of wave impact. The shore of Calypsostranda can be regarded as transitional between high and low energy coasts.
The aim of this study was to assess sand accumulation in the gastrointestinal tract and fecal sand excretion in Silesian foals using three diagnostic methods and taking into account the sex and age of the animals. Another aim of the study was to compare the three diagnostic methods. The study was carried out on 21 clinically healthy Silesian foals (10 females and 11 males) from 9-28 weeks old grazed on permanent pasture. The sand intake was assessed using a sedimentation test, abdominal ultrasonography and a quantitative evaluation of sand per 100 g of stool. In the sedimentation test, the sand was palpable in the stool of 57.1% of the horses, and clearly visible in 42.9% of the animals. The ultrasound examination revealed the presence of sand in the gastrointestinal tract in 66.7% of the horses. It was limited to a single location in 60% of the horses, while it was present in several regions in 40% of the horses. The mean amount of sand was 0.14 ± 0.33 g per 100 g of stool. It did not exceed 0.1g in 71.4% foals, while it ranged from 0.1-0.5 g in 23.8% foals. In 4.8% of the animals, it amounted to 1.6 g per 100 g of stool. There was no correlation between age and gender and the results. There was a positive correlation between the ultrasound examination and the sedimentation test. Sand may be accumulated in the gastrointestinal tract of foals without any clinical signs. The amount of sand excreted in the stool is not an indicator of the amount of sand accumulated in the gastrointestinal tract. An abdominal ultrasound examination should be combined with a sedimentation test for more specific results.
The aim of the paper was to develop determination methods of sedimentation characteristics using PIV image anemometry and suspension image analysis. Two methods of the investigation of sed- imentation process based on visualization techniques were developed. In the first one, using PIV method, vector fields of the velocity of settling particles are determined and then average particle velocities are calculated to establish the so called sedimentation dynamics curve. In the second one, the methods of suspension image analysis are utilized to determine the positions of the upper dis- continuity and to establish the sedimentation curve. Laboratory research on the sedimentation of agalit particles suspended in glycerine was conducted (using PIV method). Additionally, industrial research on the sedimentation of water-absorbing granular material used after the first carbonation (carbonation I) was conducted in a sugar factory (using the second method). The research consisted of photographic registration of images of the settling suspension by means of the time-lapse photog- raphy technique. A laboratory study was conducted for four values of the volume concentration of agalit particles in glycerine (0.5; 1.0; 1.5 and 2.0 vol%). The research methodology, the scope of the conducted measurements and sample research results together with conclusions are presented in this paper.
The buoyant hypopycnal flow of brackish water and suspended sediment transport and settling were studied in two sub-polar fjords: the glacial Kongsfjörden and the outwash (non-glacial contact) Adventfjörden, Svalbard . The data presented indicates faster water mixing on the tidal flat in comparison to the englacial runoff, which leads to faster horizontal density gradients decreases in the non-glaciated fjord. The fast settling of particles in the narrow zone of the steep slope at the edge of the tidal flat leads to the removal of 25% of the surface suspended sediment. The rapid settling is due to increasing salinity, decreasing velocity, and flocculation of fine particles. The fast settling of suspended particulate matter (SPM) in the tidal flat area causes sediment redeposition and resuspension followed by sediment transport along the bottom with hyperpycnal flows. This leads to grain sorting in the fjord head. In contrast, at the glacier front, SPM is transported farther into the fjord, where tidal pumping and water mixing lead to the removal of 71% of total SPM. The fjords investigated represent two different sedimentological regimes. In the glaciated Kongsfjörden, the buoyant hypopycnal flow of brackish water is the main sediment transporting factor. In the non-glacial Adventfjörden, hyperpycnal flows transport sediment along the bottom.
The Silurian Pelplin Formation is a part of a thick, mud-prone distal fill of the Caledonian foredeep, which stretches along the western margin of the East European Craton. The Pelplin Formation consists of organic carbon- rich mudstones that have recently been the target of intensive investigations, as they represent a potential source of shale gas. The Pelplin mudstones host numerous calcite concretions containing authigenic pyrite and barite. Mineralogical and petrographic examination (XRD, optical microscopy, cathodoluminoscopy, SEM-EDS) and stable isotope analyses (δ13Corg, δ13C and δ18O of carbonates, δ34S and δ18O of barite) were carried out in order to understand the diagenetic conditions that led to precipitation of this carbonate-sulfide-sulfate paragenesis and to see if the concretions can enhance the understanding of sedimentary settings in the Baltic and Lublin basins during the Silurian. Barite formed during early diagenesis before and during the concretionary growth due to a deceleration of sedimentation during increased primary productivity. The main stages of concretionary growth took place in yet uncompacted sediments shortly after their deposition in the sulfate reduction zone. This precompactional cementation led to preferential preservation of original sedimentary structures, faunal assemblages and early- diagenetic barite, which have been mostly lost in the surrounding mudstones during burial. These components allowed for the reconstruction of important paleoenvironmental conditions in the Baltic and Lublin basins, such as depth, proximity to the detrital orogenic source and marine primary productivity. Investigation of the concretions also enabled estimation of the magnitude of mechanical compaction of the mudstones and calculation of original sedimentation rates. Moreover, it showed that biogenic methane was produced at an early-diagenetic stage, whereas thermogenic hydrocarbons migrated through the Pelplin Formation during deep burial.