In this study, high performance magnesium-yttria nanocomposite’s room temperature, strength and ductility were significantly enhanced by the dispersion of nano-sized nickel particles using powder blending and a microwave sintering process. The strengthening effect of the dispersed nano-sized nickel particles was consistent up to 100°C and then it gradually diminished with further increases in the test temperature. The ductility of the magnesium-yttria nanocomposite remained unaffected by the dispersed nano-sized nickel particles up to 100°C. Impressively, it was enhanced at 150°C and above, leading to the possibility of the near net shape fabrication of the nanocomposite at a significantly low temperature.
The paper discusses the possibility of improving resistance of heat exchangers made of gray cast iron with flake graphite to hightemperature corrosion by providing them with metallic coatings. A metallic coating containing 76.9% Ni, 19.8% Cr, 1.7% Si, 0.9% Fe, and 0.9% Mn was applied by means of the plasma spraying method and subjected to cyclically variable thermal loads in the atmosphere of solid fuels combustion products (oxygen, sulfur, chlorine, and sodium). In a 30-day thermal load test held at temperature 500°C it has been found that thickness of the metallic coating decreased from the initial (240 ± 6) μm to (231 ± 6) μm. The depth to which sulfur, chlorine, and sodium penetrated the coating was about 30 μm. Increased oxygen content occurred along the whole coating depth. In the coating area adjacent to the substrate surface, the content was twice as high compared to this observed in the initial coating material. Although presence of oxygen was found within the whole depth of the coating, i.e. (231 ± 6) μm, no signs of susceptibility of the sprayed metallic layer to separation from substrate of gray cast iron with flake graphite were found.
Fe-40wt% TiB2 nanocomposites were fabricated by mechanical activation and spark-plasma sintering of a powder mixture of iron boride (FeB) and titanium hydride (TiH2). The powder mixture of (FeB, TiH2) was prepared by high-energy ball milling in a planetary ball mill at 700 rpm for 3 h followed by spark-plasma sintering (SPS) at various conditions. Analysis of the change in relative sintered density and densification rate during sintering showed that a self-propagating high-temperature synthesis reaction occurs to form TiB2 from FeB and Ti. A sintered body with relative density higher than 98% was obtained after sintering at 1150°C for 5 and 15 min. The microstructural observation of sintered compacts with the use of FE-SEM and TEM revealed that ultrafine particulates with approximately 5 nm were evenly distributed in an Fe-matrix. A hardness value of 83 HRC was obtained, which is equivalent to that of conventional WC-20 Co systems.
Potential sources of rare earth elements are sought after in the world by many researchers. Coal ash obtained at high temperatures (HTA ) is considered among these sources. The aim of the study was an evaluation of the suitability of the high temperature ash (HTA ) formed during the combustion of bituminous coal from the Ruda beds of the Pniówek coal mine as an potential resource of REY . The 13 samples of HTA obtained from the combustion of metabituminous (B) coal were analyzed. The analyses showed that the examined HTA samples varied in their chemical composition. In accordance with the chemical classification of HTA , the analyzed ash samples were classified as belonging to the following types: sialic, sialocalcic, sialoferricalcic, calsialic, fericalsialic, ferisialic. The research has shown that the rare earth elements content (REY ) in examined HTA samples are characterized by high variability. The average REY content in the analyzed ashes was 2.5 times higher than the world average (404 ppm). Among rare earth elements, the light elements (LREY ) were the most abundant. Heavy elements (HREY ) had the lowest share. A comparison of the content of the individual rare earth elements in HTA samples and in UCC showed that it was almost 20 times higher than in UCC. The distribution patterns of REY plotted for all samples within their entire range were positioned above the reference level and these curves were of the M-H or M-L type. The data presented indicate, that the analyzed ash samples should be regarded as promising REY raw materials. Considering the fact that in 7 out of 13 analyzed ash samples the REY content was higher than 800 ppm, REY recovery from these ashes may prove to be economic.
Constantly developing production process and high requirements concerning the quality of glass determine the need for continuous improvement of tools and equipment needed for its production. Such tools like forms, most often made of cast-iron, are characterized by thick wall thickness compared to their overall dimensions and work in difficult conditions such as heating of the surface layer, increase of thermal stresses resulting from the temperature gradient on the wall thickness, occurrence of thermal shock effect, resulting from cyclically changing temperatures during filling and emptying of the mould. There is no best and universal method for assessing how samples subjected to cyclic temperature changes behave. Research on thermal fatigue is a difficult issue, mainly due to the instability of this parameter, which depends on many factors, such as the temperature gradient in which the element works, the type of treatment and the chemical composition of the material. Important parameters for these materials are at high temperature resistance to thermal shock and thermal fatigue what will be presented in this paper.
Nickel-based alloys are widely used in industries such as the aircraft industry, chemicals, power generation, and others. Their stable mechanical properties in combination with high resistance to aggressive environments at high temperatures make these materials suitable for the production of components of devices and machines intended for operation in extremely difficult conditions, e.g. in aircraft engines. This paper presents the results of thermal and mechanical tests performed on precision castings made of the Inconel 713C alloy and intended for use in the production of low pressure turbine blades. The tests enabled the determination of the nil strength temperature (NST), the nil ductility temperature (NDT), and the ductility recovery temperature (DRT) of the material tested. Based on the values obtained, the high temperature brittleness range (HTBR) and the hot cracking resistance index were determined. Metallographic examinations were conducted in order to describe the cracking mechanisms. It was found that the main cracking mechanism was the partial melting of grains and subsequently the rupture of a thin liquid film along crystal boundaries as a result of deformation during crystallisation. Another cracking mechanism identified was the DDC (Ductility Dip Cracking) mechanism. The results obtained provide a basis for improving precision casting processes for aircraft components and constitute guidelines for designers, engineers, and casting technologists.
A high-temperature piezo-resistive nano-crystalline diamond strain sensor and wireless powering are presented in this paper. High-temperature sensors and electronic devices are required in harsh environments where the use of conventional electronic circuits is impractical or impossible. Piezo-resistive sensors based on nano-crystalline diamond layers were successfully designed, fabricated and tested. The fabricated sensors are able to operate at temperatures of up to 250°C with a reasonable sensitivity. The basic principles and applicability of wireless powering using the near magnetic field are also presented. The system is intended mainly for circuits demanding energy consumption, such as resistive sensors or devices that consist of discrete components. The paper is focused on the practical aspect and implementation of the wireless powering. The presented equations enable to fit the frequency to the optimal range and to maximize the energy and voltage transfer with respect to the coils’ properties, expected load and given geometry. The developed system uses both high-temperature active devices based on CMOS-SOI technology and strain sensors which can be wirelessly powered from a distance of up to several centimetres with the power consumption reaching hundreds of milliwatts at 200°C. The theoretical calculations are based on the general circuit theory and were performed in the software package Maple. The results were simulated in the Spice software and verified on a real sample of the measuring probe.