In this work, an assessment and comparison of the quality of selected bentonites and bentonite mixtures was made. The samples consisted of available foundry materials used for bonding green sands. Determining the homogeneity degree and specific surface area of the grains allowed us to compare the examined materials and determine their influence on other parameters. On the basis of a thermal analysis of the bentonites or bentonite mixtures, the changes occurring in the sample during its heating were determined. Determining the potential for ion exchange and montmorillonite content enabled us to assess the binding properties of the materials. The preparation of six green sands with different bentonites or bentonite mixtures gave us the opportunity to assess the changes in apparent density, permeability, compressive strength and friability as a function of humidity, and the impact of different materials on the mentioned parameters. Their charts were analyzed, and the molding sand with the addition of bentonite or a bentonite mixture was selected for which these parameters are favorable. On this basis, the best-presented binding material was assessed and selected.
Until now, the mould sand in general use in the foundry industry are based on bentonite, which resulted from the fact that a good recognition properties and phenomena associated with this material. Come to know and normalized content of montmorillonite and carbonates and their important role in the construction of bentonite, and mass properties of the participation of compressive strength or scatter. Halloysite is widely used in industry and beyond them. However, little is known about its use in the foundry in Poland and abroad. This article presents preliminary research conducted at the Foundry Department of Silesian University of Technology on this material. Will raise the question of the representation of this two materials, which contains information connected with history and formation of materials, their structure and chemical composition. In the research, the results of compressive strength tests in wet masses of quartz matrix, where as a binder is used halloysite and bentonite in different proportions.
Casting quality depends on many factors including the quality of the input materials, technology, material securing and last but not least, the mould into which the casting is casted. By pouring into a single-shot mould, based mainly on 1st generation binders, is is a very important factor. Basically, a bentonite mixture represents either a three- or four-component system, but each component of the system is a heterogeneous substance. This heterogeneity punctuates mainly a non-stationary heat field, presented throughout the whole process of the casting production. The most important component is a binder and in the case of first generation binders mostly bentonites are used - clays that contain minimum of 80% of montmorillonite
Bentonite is clay rock, which is created by decomposition of vulcanic glass. It is formed from mixture of clay minerals of smectite group, mainly montmorillonite, beidellite and nontronite. Its typical characteristics is, that when in contact with water, it intensively swells. First who used this term was W.C. Knight in 1887. The rock had been named after town Fort Benton in American state Montana. For its interesting technological properties and whiteness has wide technological use. Bentonite is selectively mined and according to its final use separately modified, which results in high quality product with specific parameters. In the beginning of 21st century belong bentonite moulding mixtures in foundry to always perspective. Mainly increased ratio of ductile cast iron castings production cannot be ensured without the need of quality bentonite. Great area of scope remains to further research of moulding materials, which return also to bentonite producers.
The criteria, with which one should be guided at the assessment of the binding properties of bentonites used for moulding sands, are proposed in the paper. Apart from the standard parameter which is the active bentonite content, the unrestrained growth indicator should be taken into account since it seems to be more adequate in the estimation of the sand compression strength. The investigations performed for three kinds of bentonites, applied in the Polish foundry plants, subjected to a high temperature influences indicate, that the pathway of changes of the unrestrained growth indicator is very similar to the pathway of changes of the sand compression strength. Instead, the character of changes of the montmorillonite content in the sand in dependence of the temperature is quite different. The sand exhibits the significant active bentonite content, and the sand compression strength decreases rapidly. The montmorillonite content in bentonite samples was determined by the modern copper complex method of triethylenetetraamine (Cu(II)-TET). Tests were performed for bentonites and for sands with those bentonites subjected to high temperatures influences in a range: 100-700ºC.
A determination of the heating degree of the moulding sand with bentonite on the grounds of simulating investigations with the application of the MAGMA program, constitutes the contents of the paper. To this end the numerical simulation of the temperature distribution in the virtual casting mould was performed. It was assumed that the mould cavity was filled with a moulding sand with bentonite of a moisture content 3,2 % and bentonite content 8 %. A computer simulation can be used for predicting the heating degree of moulding sands with bentonite. Thus, prediction of the active bentonite (montmorillonite) content in individual layers of the overheated moulding sand can be done by means of the simulation. An overheating degree of a moulding sand with bentonite, and thus the bentonite deactivation depends on a temperature of a casting alloy, casting mass, ratio of: masssand : masscasting, moulding sand amount in the mould and contact area: metal – mould (geometry of the casting shape). Generally it can be stated, that the bentonite deactivation degree depends on two main factors: temperature of moulding sand heating and time of its operation.
The paper presents results of measuring thermal conductivity and heat capacity of bentonite foundry sand in temperature range ambient – 900 OC. During the experiments a technical purity Cu plate was cast into the green-sand moulds. Basing on measurements of the mould temperature field during the solidification of the casting, the temperature relationships of the measured properties were evaluated. It was confirmed that water vaporization strongly influences thermal conductivity of the moulding sand in the first period of the mould heating by the poured casting.
Zinc (II) removal using low-cost sorbents requires a proper process parametric study to determine its optimal performance characteristics. In this respect, the present study proposes a new modeling and simulation procedure for heavy metal removal system and is carried out to optimize input variables such as initial pH, adsorbent dosage, and contact time for biosorption of Zinc (II) by using bentonite. The proposed experimental system is cost-effective and requires less calculation for determining optimal values, i.e., input variables and their related removal capacity, Rem%. To optimize the adsorption process, cubic spline curve fitting and numerical differentiation techniques are used for required calculations. According to the proposed calculations, the removal capacity is calculated as 98.66%, while the optimal values are calculated as initial pH – 6.76, adsorbent dosage – 1.14 g L-1, contact time – 13 minutes. To evaluate the results, full factor experimental design and 3 way ANOVA test are used for comparison.