In this article, we present a comprehensive measurement system to determine the level of user emotional arousal by the analysis of electrodermal activity (EDA). A number of EDA measurements were collected, while emotions were elicited using specially selected movie sequences. Data collected from 16 participants of the experiment, in conjunction with those from personal questionnaires, were used to determine a large number of 20 features of the EDA, to assess the emotional state of a user. Feature selection was performed using signal processing and analysis methods, while considering user declarations. The suitability of the designed system for detecting the level of emotional arousal was fully confirmed, throughout the number of experiments. The average classification accuracy for two classes of the least and the most stimulating movies varies within the range of 61‒72%.