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Abstract

Given its high efficiency, low emissions and multiple fuelling options, the solid oxide fuel cells (SOFC) offer a promising alternative for stationary power generators, especially while engaged in micro-combined heat and power (μ-CHP) units. Despite the fact that the fuel cells are a key component in such power systems, other auxiliaries of the system can play a critical role and therefore require a significant attention. Since SOFC uses a ceramic material as an electrolyte, the high operating temperature (typically of the order of 700–900°C) is required to achieve sufficient performance. For that reason both the fuel and the oxidant have to be preheated before entering the SOFC stack. Hot gases exiting the fuel cell stack transport substantial amount of energy which has to be partly recovered for preheating streams entering the stack and for heating purposes. Effective thermal integration of the μ-CHP can be achieved only when proper technical measures are used. The ability of efficiently preheating the streams of oxidant and fuel relies on heat exchangers which are present in all possible configurations of power system with solid oxide fuel cells. In this work a compact, fin plate heat exchanger operating in the high temperature regime was under consideration. Dynamic model was proposed for investigation of its performance under the transitional states of the fuel cell system. Heat exchanger was simulated using commercial modeling software. The model includes key geometrical and functional parameters. The working conditions of the power unit with SOFC vary due to the several factors, such as load changes, heating and cooling procedures of the stack and others. These issues affect parameters of the incoming streams to the heat exchanger. The mathematical model of the heat exchanger is based on a set of equations which are simultaneously solved in the iterative process. It enables to define conditions in the outlets of both the hot and the cold sides. Additionally, model can be used for simulating the stand-alone heat exchanger or for investigations of a semiadiabatic unit located in the hotbox of the μ-CHP unit.
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Abstract

Heat exchangers of different types find application in power systems based on solid oxide fuel cells (SOFC). Compact plate fin heat exchangers are typically found to perfectly fit systems with power output under 5 kWel. Micro-combined heat and power (micro-CHP) units with solid oxide fuel cells can exhibit high electrical and overall efficiencies, exceeding 85%, respectively. These values can be achieved only when high thermal integration of a system is assured. Selection and sizing of heat exchangers play a crucial role and should be done with caution. Moreover, performance of heat exchangers under variable operating conditions can strongly influence efficiency of the complete system. For that reason, it becomes important to develop high fidelity mathematical models allowing evaluation of heat exchangers under modified operating conditions, in high temperature regimes. Prediction of pressure and temperatures drops at the exit of cold and hot sides are important for system-level studies. Paper presents dedicated mathematical model used for evaluation of a plate fin heat exchanger, operating as a part of micro-CHP unit with solid oxide fuel cells.
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Abstract

Microscale combined heat and power (CHP) unit based on solid oxide fuel cells (SOFC) for distributed generation was analyzed. Operation principle is provided, and the technology development in recent years is briefly discussed. System baseline for numerical analysis under steady-state operation is given. Grid-connected unit, fuelled by biogas corresponds to potential market demand in Europe, therefore has been selected for analysis. Fuel processing method for particular application is described. Results of modeling performed in ASPEN Plus engineering software with certain assumptions are presented and discussed. Due to high system electrical efficiency exceeding 40%, and overall efficiency over 80%, technology is an example of highly competitive and sustainable energy generation unit.
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Abstract

The article discusses the operation of solid oxide electrochemical cells (SOC) developed in the Institute of Power Engineering as prospective key components of power-to-gas systems. The fundamentals of the solid oxide cells operated as fuel cells (SOFC – solid oxide fuel cells) and electrolysers (SOEC – solid oxide fuel cells) are given. The experimental technique used for electrochemical characterization of cells is presented. The results obtained for planar cell with anodic support are given and discussed. Based on the results, the applicability of the cells in power-to-gas systems (P2G) is evaluated.
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Abstract

The paper presents dynamic model of hot water storage tank. The literature review has been made. Analysis of effects of nodalization on the prediction error of generalized finite element method (GFEM) is provided. The model takes into account eleven various parameters, such as: flue gases volumetric flow rate to the spiral, inlet water temperature, outlet water flow rate, etc. Boiler is also described by sizing parameters, nozzle parameters and heat loss including ambient temperature. The model has been validated on existing data. Adequate laboratory experiments were provided. The comparison between 1-, 5-, 10- and 50-zone boiler is presented. Comparison between experiment and simulations for different zone numbers of the boiler model is presented on the plots. The reason of differences between experiment and simulation is explained.
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