The preliminary stage of asphalt mixture production involves the drying and dedusting of coarse aggregates. The most common types of coarse aggregates used are limestone and basalt. In the process of drying and dedusting the dryer filter accumulates large quantities of waste in the form of mineral powder. This paper introduces an investigation into limestone powder waste as a potential microfiller of polymer composites. Physical characteristics such as the granulation the of powder collected from the filter - in terms of the season of its collection and the type of input materials used - were analysed. A scanning electron microscope (SEM) was used for the investigation described within this paper. The obtained results were compared against those of other materials which can be used as polymer composites microfillers.
For a very long period of time, Polish waste management was based mainly on landfilling at landfills, which had a negative impact on the surrounding environment. The EU requirements for the Member States have led to a revolution in Polish legislation on waste management and local governments have become responsible for creating local waste management systems that will affect the achievement of EU targets. One of the solutions undertaken by several municipalities is the construction and operation of a municipal waste thermal treatment installation, which not only reduced the amount of waste deposited, but also supported the local power industry by generating electricity and heat. The emission standards for installations producing energy from waste, as in the case of conventional power plants and combined heat and power plants, are very strict, therefore, the continuous monitoring of emitted pollutants is carried out, and waste gas treatment systems are developed based on the best available techniques (BAT). The article presents emission standards applicable to waste incineration plants, including duties in the field of the environment, as well as issues related to the installation as a source of energy. In addition, the currently functioning waste incineration plants in Poland have been briefly characterized, and development plans in this area in the country have been described.
The utilization of mining waste is an important problem in Poland and Ukraine. The article presents one of the variants of waste mining in the quarry in Płaza. An analysis of the resource base of the deposit and their location at the area of Płaza deposit is carried out. The Płaza deposit is located in the western part of the Małopolskie province, in the entire Chrzanów commune. The Płaza deposit is constructed of Middle Triassic carbonates represented by the limestone-dolomite Olkusz Formation and the limestone-marlized Gogolin Formation. The deposit series lies on the dolomites of Röt age (Lower Triassic – Olenekian). The most valuable raw material was the pure limestone from the lower part of the Olkusz Formation, now almost completely exploited. The article presents the current state of mineable reserves of the deposit and their quality (chemical and physical characteristics). Moreover the article shows potential consumers of raw material and the possibility of extending the life of the mine work. According to the results of the environmental monitoring the ground and hydrogeological conditions were evaluated, the results of which allowed a more efficient use of the existing quarry area for mining waste disposal to be proposed. The paper presents a conceptual waste transport scheme, planned distribution and compaction of wastes belonging to the first, second and third group and then a surface reclamation. In view of the absence of similar decisions analogs, the consideration of the open-pit as a one solid geomechanical system functioning under the conditions of uncertainty is suggested. In order to examine the dynamics of the waste compaction process, some measures are foreseen to constantly observe their subsidence. The proposed measures for the synchronous disposal of mining waste in the worked-out area of the open-pit and the simultaneous mining operation in the quarry will allow the life cycle of the open-pit to be prolonged for 15–20 years.
Municipal waste management has been an area of special interest of the European Commission (EC) for many years. In 2018, the EC pointed out issues related to municipal waste management as an important element of the monitoring framework for the transition towards a circular economy (CE), which is currently a priority in the economic policy of the European Union (EU). In the presented monitoring framework, 10 CE indicators were identified, among which issues related to municipal waste appear directly in two areas of the CE – in the field of production and in the field of waste management, and indirectly – un two other areas – secondary raw materials, and competitiveness and innovation. The paper presents changes in the management of municipal waste in Poland in the context of the implementation of the CE assumptions, a discussion of the results of CE indicators in two areas of the CE monitoring framework in Poland (production and waste management), and a comparison of the results against other European countries. In Poland, tasks related to the implementation of municipal waste management from July 1, 2013 are the responsibility of the municipality, which is obliged to ensure the conditions for the system of selective collection and collection of municipal waste from residents, as well as the construction, maintenance and operation of regional municipal waste treatment installations (RIPOK). The municipality is also committed to the proper management of municipal waste, in accordance with the European waste management hierarchy, whose overriding objective is to prevent waste formation and limiting its amount, then recycling and other forms of disposal, incineration and safe storage. The study analyzed changes in the value of two selected CE indicators, i.e. (1) the municipal waste generation indicator, in the area of production and (2) the municipal waste recycling indicator, in the area of waste management. For this purpose, statistical data of the Central Statistical Office (GUS) and Eurostat were used. Data has been presented since 2014, i.e. from the moment of initiating the need to move to the CE in the EU. In recent years, there has been an increase in the amount of municipal waste generated in Poland as well as in the EU. According to Eurostat, the amount of municipal waste generated per one inhabitant of Poland increased from 272 kg in 2014 to 315 kg in 2017. It should be noted that the average amount of municipal waste generated in Poland in 2017 was one of the lowest in EU, with a European average of 486 kg/person. Poland has achieved lower levels of municipal waste recycling (33.9%) than the European average (46%). The reason for Poland’s worse results in the recycling of municipal waste may be, among others, the lack of sufficiently developed waste processing infrastructure, operating in other countries such as Germany and Denmark, and definitely higher public awareness of the issue of municipal waste in developed countries. Municipal waste management in Poland faces a number of challenges in the implementation of GOZ, primarily in terms of achieving the recycling values imposed by the EC, up to a minimum of 55% by 2025.
With the increase in the mass of municipal waste generated, the demand for facilities dealing with their development is increasing. The aim of the research was to determine environmental and anthropogenic factors affecting the location of waste management facilities and an attempt to indicate potential locations for selected waste management facilities in the communes of the Sądecko-Gorlicki region. The scope of work included: a review of existing waste management facilities in the studied region, acquisition of geodatabase for digital data, analysis of the distance between the waste management facilities and environmental or anthropogenic elements, and analysis of potential locations designated in the GIS based on the developed criteria.As a result of spatial analyzes, it was found that in the study area, there are 3 places of potentiallocations for installation of municipal solid waste treatment facilities.
Waste management is a challenging problem for most of the countries. The current waste segregation and the collection method are not efficient and cost-effective. In this paper, a prototype is presented for smart waste management. It is also capable of waste segregation at the ground level and providing real-time data to the administrator. Impact and cost analysis of the deployment of smartbin is also presented considering one ward of Ahmedabad Municipal Corporation. It is clear from that deployment of this smartbin will save about 40% of the current expenditure for that ward.
The problem of hazardous medical waste resulting from the provision of healthcare services by healthcare institutions is becoming increasingly relevant in the context of the need to ensure environmental protection and safety to human life and health. This requires efficient management of waste in order to minimise its level of hazard. The most common problems in this respect are found at the stage of the temporary storage of hazardous medical waste, as confirmed by irregulari-ties reported over the last six years at healthcare institutions in the 388 (16.4%) from the Great Poland Province voivodship, which is the third voivodship in terms of hazardous medical waste generation in Poland. Violations of sanitary and building regulations in the storage of hazardous medical waste could lead to widespread infection and infectious diseases in humans and to the environment. This should be prevented through the introduction of continuing education for the personnel having direct contact with waste and for the management staff of healthcare institutions with a view to fostering awareness and responsibility regarding sanitary security and environmen-tal protection.
One of the consequences of the dynamic technological development is the rapidly increasing amount of electro-waste (WEEE, e-waste). Because there are no uniform legal regulations regarding the ways of collecting such waste, the separate-collection systems used in various areas are not homogeneous, and they usually also differ in effectiveness. The aim of this study was to evaluate the electro-waste collection system implemented in Lublin (the largest city in Eastern Poland). Taking into account the fact that the reliability of a collection system depends on the degree of its adaptation to the functions it performs, the evaluation consisted in determining how big a problem improper electro-waste segregation was. The article presents the results of a study of the causes of citizens’ failure to properly manage e-waste and indicates what measures should be taken to amend the problem. During two research steps, 347 pieces of e-waste with a total weight of 77.218 kg were found in the analyzed waste samples (0.33% of all samples). This means that the mechanisms of selective e-waste collection still do not work correctly, despite the ten years of Poland’s membership in the EU and implementation of European legislation in this area. The fact that residents throw away electric waste into municipal mixed waste containers poses a serious problem for proper waste management – even if only a part of the e-waste is disposed in this illegal way. This indicates the necessity of improving waste collection (more frequent waste reception, convenient access to e-waste containers, raising public awareness, etc.).
For years, the Polish hard coal mining has been struggling with the problem of fire hazards in areas with coal residue, mainly in goafs. Currently, a common method of limiting this hazard is the fire prevention involving use of fine-grained hydromixtures based on power generation waste, mainly fly ashes. The hydromixture is introduced into the caving zone created by the advancement of exploitation face and its task is to fill in voids, limiting the possibility of access to the mine air oxygen to a minimum. The first part of the article presents theoretical fundamentals of determining the parameters of gravitational hydraulic transport of water and ash hydromixtures used in the mining pipeline systems. Each hydromixture produced based on fine-grained wastes is characterized by specified rheological parameters that have a direct impact on the future flow parameters of a given pipeline system. Additionally, the gravitational character of the hydraulic transport generates certain limitations concerning the so-called correct hydraulic profile of the system in relation to the applied hydromixture characterized by required rheological parameters that should ensure safe flow at a correct efficiency. This paper shows an example of optimisation of the composition of a selected fly ash-water hydromixture in relation to its capacity for hydrotransport in gravity pipeline installations, as well as the amount of excess water that will always drain from the location of feeding the hydromixture to the underground workings.
As of the spring of 2017, the HAŁDY Database is available on the Polish Geological Institute – NRI website. The geodatabase contains information and data on waste mineral raw materials collected on old heaps, industrial waste stock-piles and in post-mining settlers, from the Polish part of the Sudety Mountains. The article presents the types of data and information contained in the geodatabase and the methodology for their collection. As a result of four-year research works, field reconnaissance, archives and geological basic research, 445 objects of former mining and mineral processing were inventoried. There are 403 mine heaps, 16 industrial settlers, 23 stock-piles and 3 external dumps. These are mainly objects after coal mining and metal ores, including post-uranium. The greatest opportunities for the economic use of waste are associated with coal sludge accumulated in settlers of the liquidated Lower Silesian Coal Basin. The material from stone heaps after polymetallic, iron and fluorite ore mining is also easy to use. The issue of the economic use of post-flotation copper ore waste or the recovery of metals (including gold) from dumps of arsenic mining remains open. The limitation here is the efficiency of metal recovery technologies and environmental restrictions. Some of the objects are located in protected areas, which excludes the possibility of waste management. Some stock-piles and heaps should be carefully reclaimed and covered by environmental monitoring, due to their harmful impact on environmental components.
This publication presents an assessment of the economic efficiency of a hypothetical installation for the gasification of the municipal and industrial waste for the production of syngas used subsequently for the production of energy or chemical products. The first part of the work presents an example of a technological system for the energo-chemical processing of coal mud and municipal waste, based on the gasification process using a fluidized bed reactor. A hypothetical installation consists of two main blocks: a fuel preparation unit and a gasification unit. In the fuel preparation installation, reception operations take place, storage, and then grinding, mixing, drying and transporting fuel to the gasification unit. In the gasification installation, fuel gasification, oxygen production, cooling and purification of raw process gas and ash treatment are carried out. The following key assumptions regarding the gasification process, as well as the capital expenditures and operating costs related to the process, were estimated. Consequently, based on the method of discounted cash flows, the unit cost of generating energy contained in the synthesis gas (cost of energy, COE) was determined and the results were interpreted. In order to obtain an acceptable efficiency of the gasification process for waste fuels for the production of alternative fuel (process gas), it is necessary to supplement the mixture of waste coal and coal mud with the RDF. In this case, the unit cost of fuel measured by the PLN/GJ index is lower than in the case of hard coal and comparable with brown coal. The use of coal mud for the production of process gas in an economically efficient way is possible only in the case of changes in the legal system allowing for charging fees for the utilization of industrial waste – coal mud.
In the process of determining the content of impurities, including fossil fuels, crude oil, coke, pitch, plastics, glass, slag, rust, metals, and rock dust, in charcoal and wood briquettes via microscopic examination, the question of the use of ashes from the combustion of grill fuels (taking the scale of the new national sport into account, commonly referred to as „weekend grilling”) was raised. Another reason for addressing this issue was the question regarding the use of organic additives to acidified soil (mineral) fertilizers submitted by one of the clients of the bituminous coal and reservoir rocks analysis laboratory. In addition, the manufacturer of gardening soil has also expressed an interest in an unconventional deacidifying agent; the introduction of a new product with a unique ingredient is considered as a chance to stand out from the competition. A review of the literature shows that attempts to use ashes obtained from the biomass combustion in power boilers have been made. However, due to the biomass composition and additives and pollutants used in biomass for energy purposes, the production of such mixtures has been dropped. Based on the data from numerous samples of grill fuel, which meet the requirements regarding the content of impurities set out in the PN-EN 1860-2 standard, the question of the possible use of ash obtained from charcoal and wood briquette grilling as a component for use in the production of acidified soil (mineral) fertilizers was discussed. The article will present the amount of material obtained based on the statistical sales of barbecue fuels based on the experimentally calculated ash mass resulting from the combustion of 1 kg of starting material. In addition, a logistic proposal for obtaining ash from individual grill users will be developed. On the day of the submission of the present work, the results of the chemical analysis of charcoal and wood briquettes subjected to the gasification process have not yet been obtained. However, based on the microscopic analysis, it can be concluded that the content of impurities in the examined samples is highly unlikely to prevent the use of the mentioned ashes in agriculture.
Based on laboratory tests of selected properties of secondary waste (ashes and dusts) from municipal waste incineration plants, the possibility of recovering some properties of waste in the process of filling the post-mining voids in the salt mine was assessed. The furnace bottom ash and the waste from the flue gas treatment from one of the national incineration plants were examined. The grain curves of dry waste and the density of the prepared mixtures were characterized. Twelve variants of the compositions of ash-based mixtures with varying proportions of the individual components were considered, taking into account both fresh water and brine. For each variant of the composition, the amount of redundant liquid appeared as well as the time of solidifying of the mixture to a certain strength and the compressibility values obtained. Considering the possibility of transporting mixtures in mines by means of pipelines at relatively long distances, and allowing the filling of large salt chambers to be filled and evenly filled, flow parameters were determined. In addition, the permeability of solidified waste samples was investigated, showing the potential for reducing the strength of the waste mass due to the action of water or brine. The technical feasibility of eliminating redundant liquid in the binding process has been confirmed, which is particularly important in salt mines. Preliminary values for the amount of binder (5%÷10%) to be added to the mixtures to obtain the specified strength properties of the artificially formed mass at Rc = 0.5 MPa. Attention was paid to the important practical aspect resulting from the rapid increase of this type of waste in the comming years in Poland and at the same time vast potential for their use in salt mining, where we have a huge capacity of salt chambers available.
The article discusses issues related to the generation, use, and transboundary movement of waste labeled with the code 191210 according to the waste catalogue regardless of its origin (municipal, industrial or mixed). Data contained in voivodship reports related to waste management and information about transboundary shipments shared by the Chief Inspectorate of Environmental Protection were also used in the article. The imbalance in the amount of produced and energetically used alternative fuels in Poland in the years 2015 to 2017 has been confirmed. This affects the economy of the waste management sector involved in the production of alternative fuels. The oversupply causes the prices of alternative fuels to fall and increases the need for subsidies in the case of the recovery or disposal of alternative fuels of lower quality. In the near future one should expect a stabilization of the supply of combustible waste to the cement industry, which is now beginning to achieve its technological potential; this is due to a high degree of replacement of fossil fuels. One should also expect an increase in the demand for alternative fuels from the commercial power sector and heating sector. It has been shown that much more alternative fuel is imported than exported from Poland. The amount of imported alternative fuel in the market is relatively low compared to the amount of fuel produced in the country. This oversupply affects, although not significantly, the possibility of using domestic waste for energy recovery. The export of the alternative fuel produced in the country is a favorable phenomenon when there is no possibility of sale on the domestic market. It seems rational, especially in the case of exports from installations producing fuels in border provinces.
The policy of sustainable development seeks to improve energy efficiency of industrial equipment. Efforts to improve energy efficiency also apply to the paint shops, where the recovery of waste heat is sought. The main source of a large amount of low-temperature waste heat in the paint shop is the spray booth. The second place where a large amount of low temperature waste heat is released is the room where the compressed air is prepared. Low energy efficiency of air compressors requires a large electric power supply. As a result, the emitted large heat fluxes become waste energy of the technological process. Heat is equivalent to up to 93% of the electric power supplied in the air compression process. There are solutions for recovering heat from compressors coming from the oil cooling water, but then the waste heat from the cooling of the compressed air and from the electric motor is released into air in the room. A method for recovering low-temperature waste heat from the air preparation room by means of an air-source heat pump has been proposed. An energy balance of the air compression and dehumidification process for the paint shop was made. A Matlab’s built-in numerical model includes air compressor and dehumidifier, heat recovery and accumulation for the purposes of use in the spray booth. A simulation experiment was carried out on the effectiveness of heat recovery from the air preparation room. The use of combined energy management in paint shops was proposed.
The purpose of the research was mapping, inventorization, and valorization of coal mining waste dumps from the mines of JSW SA company, for the needs of recovery of coal from the dump material as well as the reclamation and management of examined facilities. The valorization of post-mining waste dumps has been carried out using a methodology which considers the problems of reclamation, management, accessibility of the dumps as well as environmental hazards connected with disposing of mining and preparation wastes on the ground surface. An inventorization of 10 coal mining waste dumps coming from 6 mines of JSW SA including in their range 7 deposits: Borynia, Jastrzębie, Zofiówka, Budryk, Knurów, Szczygłowice and Pniówek was carried out. The source material within the localization of particular dumps was obtained from archival materials coming from coal mines and municipalities where the dumps are located. Verified data has been drawn on topographical map, which results in the map of coal mining waste dumps. The results of the valorization of the dumps comprise the defining of: the name of the dump, state of the dump, surface of the dump, accessibility, name of the coal mine from where the wastes come from, type of technical and biological reclamation and possibilities of coal recovery, which have been brought on the drawn map. Basing on collected and elaborated data, an attempt of defining of potential possibilities of recovery of coal from the dumps and connection of coal quality in the deposits of JSW SA and in waste material was made. The results of the research showed that in spite of preliminary information that a majority of the investigated dumps may be considered as potential facilities for coal recovery, ultimately the recovery is economically justified only in several cases (5 facilities).
The new legislative provisions, regulating the trade in solid fuels in our country, draw attention to the need to develop and improve methods and methods of managing hard coal sludge. The aim of the work was to show whether filtration parameters (mainly the permeability coefficient) of hard coal sludge are sufficient for construction of insulating layers in landfills at the stage of their closing and what is the demand for material in the case of such a procedure. The analysis was carried out for landfills for municipal waste in the Opolskie, Śląskie and Małopolskie provinces. For hard coal sludge, the permeability coefficient values are in the range of 10–8–10–11 m/s, with the average value of 3.16 × 10–9 m/s. It can be concluded that this material generally meets the criteria of tightness for horizontal and often vertical flows. When compaction, increasing load or mixing with fly ash from hard coal combustion and clays, the achieved permeability coefficient often lowers its values. Based on the analysis, it can be assumed that hard coal sludge can be used to build mineral insulating barriers. At the end of 2016, 50 municipal landfills were open in the Opolskie, Śląskie and Małopolskie Provinces. Only 36 of them have obtained the status of a regional installation, close to 1/3 of the municipal landfill are within the Major Groundwater Basin (MGB) range. The remaining storage sites will be designated for closure. Assuming the necessity to close all currently active municipal waste landfills, the demand for hard coal sludge amounts to a total of 1,779,000 m3 which, given the assumptions, gives a mass of 2,704,080 Mg. The total amount of hard coal sludge production is very high in Poland. Only two basic mining groups annually produce a total of about 1,500,000 Mg of coal sludge. The construction of insulating layers in landfills of inert, hazardous and non-hazardous and inert wastes is an interesting solution. Such an application is prospective, but it will not solve the problem related to the production and management of this waste material as a whole. It is important to look for further solutions.
A liquid crystal display (LCD) recycling process is needed to increase its efficiency by recovering the resources in addition to metals and plastics. This study investigates the pre-treatment process for recycling LCD glass. Recycling pre-treatment includes dismantling the LCD from the waste product, crushing the glass, and separating the glass particles from the impurities. Scanning electron microscopy confirmed that the oscillation milling process is more effective in maintaining uniform powder shape and size as compared to the cut milling process. The glass particles crushed by the oscillating mill, optimized at 1500 rpm, had a uniformly distributed particle size of less than 10 µm. These small particles were separated from the organic impurities, achieving a 98% pure powder that can be used as recycled raw materials. The proposed pre-treatment process for recycling LCD glass will enhance the ability to use waste glass as a valuable resource in the manufacturing of future displays.
A mathematical model of waste tyre pyrolysis process is developed in this work. Tyre material decomposition based on a simplified reaction mechanism leads to main product lumps: noncondensable (gas), condensable (pyrolytic oil) and solid (char). The model takes into account kinetics of heat and mass transfer in the grain of the shredded rubber material as well as surrounding gas phase. The main reaction routes were modelled as the pseudo-first order reactions with a rate constant calculated from the Arrhenius type equation using literature values of activation energy determined for main tyre constituents based on TG/DTG measurements and tuned pre-exponential parameter values obtained by fitting theoretical predictions to the experimental results obtained in our laboratory reactor. The model was implemented within the CFD software (ANSYS Fluent). The results of numerical simulation of the pyrolysis process revealed non-uniformity of sample’s porosity and temperature. The simulation predictions were in satisfactory agreement with the experimentally measured mass loss of the tyre sample during pyrolysis process investigated in a laboratory reactor.
The article discusses an innovative system used for aerobic biostabilisation and biological drying of solid municipal waste. A mechanical–biological process (MBT) of municipal solid waste (MSW) treatment were carried out and monitored in 5 bioreactors. A two-stage biological treatment process has been used in the investigation. In the first step an undersize fraction was subjected to the biological stabilisation for a period of 14 days as a result of which there was a decrease of loss on ignition, but not sufficient to fulfill the requirements of MBT technology. In the second stage of a biological treatment has been applied 7-days intensive bio-drying of MSW using sustained high temperatures in bioreactor. The article presents the results of the chemical composition analysis of the undersize fraction and waste after biological drying, and also the results of temperature changes, pH ratio, loss on ignition, moisture content, combustible and volatile matter content, heat of combustion and calorific value of wastes. The mass balance of the MBT of MSW with using the innovative aeration system showed that only 14.5% of waste need to be landfilled, 61.5% could be used for thermal treatment, and nearly 19% being lost in the process as CO2 and H2O.
Rare earth metals including yttrium and europium are one of several critical raw materials, the use of which ensures the development of the so-called high technology. The possibility of their recovery in Europe is limited practically only to secondary materials such as phosphogypsum and electronic waste. The article presents the results of our research concerning the development of recovery technology of yttrium and europium from luminophore CRT used lamps. It describes the principle of separation of elements and the test results of cleaning the concentrate. It was shown that the costs of preparing the concentrate according to the proposed technology are lower than the phosphogypsum processing technology and the composition of the resulting product does not contain hazardous substances.
Results of the investigation of thermal degradation of polyolefins in the laboratory-scale set-up reactors are presented in the paper. Melting and cracking processes were carried out in two different types of reactors at the temperature of 390-420°C. This article presents the results obtained for conversion of polyolefin waste in a reactor with a stirrer. Next, they were compared with the results obtained for the process carried out in a reactor with a molten metal bed, which was described in a previous publication. For both processes, the final product consisted of a gaseous (2-16 % mass) and a liquid (84-98 % mass) part. No solid product was produced. The light, "gasoline" fraction of the liquid hydrocarbons mixture (C4-C10) made up over 50% of the liquid product. The overall (vapor) product may be used for electricity generation and the liquid product for fuel production.
The article presents the directions of foundry waste management, mainly used for spent foundry sands (SFS) and dust after the reclamation of this waste. An important aspect of environmental protection in foundry production is the reduction of the amount of generated waste as a result of SFS regeneration. The advantage is the reuse of waste, which reduces the costs of raw materials purchase and environmental fees for landfilling. Non -recycled spent foundry sands can be used in other industries. SFS is most often used in road and construction industries as well as inert material in closed mines (Smoluchowska and Zgut 2005; Bany-Kowalska 2006). An interesting direction of using SFS is its application in gardening and agriculture. The article presents the advantages and disadvantages of such use. It was found that spent foundry sands can be useful for the production of soil mixtures for many agricultural and horticultural applications. Due to the possibility of environmental pollution with heavy metals and organic compounds, such an application is recommended for the so-called green sands, i.e. SFS with mineral binders. In addition, an innovative solution for the energy use of dusts after spent foundry sands reclamation with organic binders has been discussed and proposed by some researchers. It was shown that dust from reclaimed SFS with organic binders can be used as an alternative fuel and raw material in cement kilns, due to the high percentage of organic substances which determine their calorific value and silica.
The analysis of leaching behavior of harmful substances, such as arsenic, is one of the parameters of risk assessment resulting from the storage or economic use of coal waste. The leachability depends both on the environmental conditions of the storage area as well as on the properties of the waste material itself. There are a number of leaching tests that allow to model specific conditions or measure the specific properties of the leaching process. The conducted research aimed at comparing two methods with different application assumptions. The study of arsenic leaching from waste from the hard coal enrichment process was carried out in accordance with the Polish PN-EN 12457 standard and the US TCLP procedure. The leaching results obtained with both methods did not exceed the limit values of this parameter, defined in the Polish law. Both methods were also characterized by the good repeatability of the results. The use of an acetic acid solution (TCLP method) resulted in three times higher arsenic leaching from the examined waste compared to the use of deionized water as a leaching fluid (method PN-EN 12457). Therefore, the use of organic acid tests for mining waste intended for storage with municipal waste should be considered, as the results of the basic test based on clean water leaching may be inadequate to the actual leaching of arsenic under such environmental conditions.
The purpose of this article was to discuss the use of adsorption chillers for waste heat recovery. The introduction discusses the need to undertake broader measures for the effective management of waste heat in the industry and discusses the benefits and technical problems related to heat recovery in industrial plants. In addition, heat sources for adsorption chillers and their application examples were described. The principle of operation of adsorption chillers is explained in the next chapter. Heat sources for adsorption chillers are indicated and their application examples are described. The above considerations have allowed the benefits and technical obstacles related to the use of adsorption chillers to be highlighted. The currently used adsorbents and adsorbates are discussed later in the article. The main part of the paper discusses the use of adsorption chillers for waste heat management in the glassworks. The calculations assumed the natural gas demand of 20.1 million m3 per year and the electricity demand of 20,000 MWh/year. As a result of conducted calculations, a 231 kW adsorption chiller, ensuring the annual cold production of 2,021 MWh, was selected. The economic analysis of the proposed solution has shown that the investment in the adsorption chiller supplied with waste heat from the heat recovery system will bring significant economic benefits after 10 years from its implementation, even with total investment costs of PLN 1,900,000. However, it was noted that in order to obtain satisfactory economic results the production must meet the demand while the cost of building a heat recovery system shall not exceed PLN 1 million.