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Abstrakt

Stosowanie biomasy w energetyce jest działaniem w ramach zastępowania paliw kopalnych pozyskiwaniem energii ze źródeł odnawialnych. Jednak jej stosowanie jako paliwa stałego ze względu na różnorodność stosowanej biomasy powoduje powstawanie odpadów o bardzo zróżnicowanym i niestabilnym składzie chemicznym. Odpady ze spalania biomasy są surowcem o bardzo zróżnicowanym składzie nawet w przypadku spalania biomasy jednego rodzaju. Zawartość poszczególnych pierwiastków w popiołach lotnych ze spalania biomasy waha się od zera do kilkudziesięciu procent. To zróżnicowanie powoduje, że trudno znaleźć dla nich metody odzysku. Najczęściej rozpatrywane kierunki stosowania popiołów ze spalania biomasy to produkcja materiałów budowlanych i rolnictwo. W artykule przedstawiono wyniki badań pierwiastkowych składów chemicznych z podziałem na najczęściej stosowane paliwa z biomasy. Zaprezentowane zostały wyniki dotyczące pierwiastkowych składów chemicznych popiołów lotnych ze spalania biomasy leśnej i rolniczej w kotłach fluidalnych w energetyce zawodowej. Popioły te charakteryzują się wysoką zawartością: wapnia (12,3–19,4%), krzemu (1,2–8,3%), potasu (0,05–1,46%), chloru (1,1–6,1%), żelaza (0,8–6,5%). Nie stwierdzono w nich obecności sodu. Tylko w jednym z 5 popiołów stwierdzono obecność glinu. We wszystkich badanych popiołach stwierdzono obecność: manganu, chromu, miedzi, niklu, ołowiu, cynku, siarki, bizmutu, cyrkonu, tytanu. Analiza pierwiastkowych składów chemicznych może pozwolić na wstępne określenie kierunku odzysku dla danego popiołu.
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The article discusses issues related to the generation, use, and transboundary movement of waste labeled with the code 191210 according to the waste catalogue regardless of its origin (municipal, industrial or mixed). Data contained in voivodship reports related to waste management and information about transboundary shipments shared by the Chief Inspectorate of Environmental Protection were also used in the article. The imbalance in the amount of produced and energetically used alternative fuels in Poland in the years 2015 to 2017 has been confirmed. This affects the economy of the waste management sector involved in the production of alternative fuels. The oversupply causes the prices of alternative fuels to fall and increases the need for subsidies in the case of the recovery or disposal of alternative fuels of lower quality. In the near future one should expect a stabilization of the supply of combustible waste to the cement industry, which is now beginning to achieve its technological potential; this is due to a high degree of replacement of fossil fuels. One should also expect an increase in the demand for alternative fuels from the commercial power sector and heating sector. It has been shown that much more alternative fuel is imported than exported from Poland. The amount of imported alternative fuel in the market is relatively low compared to the amount of fuel produced in the country. This oversupply affects, although not significantly, the possibility of using domestic waste for energy recovery. The export of the alternative fuel produced in the country is a favorable phenomenon when there is no possibility of sale on the domestic market. It seems rational, especially in the case of exports from installations producing fuels in border provinces.
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The policy of sustainable development seeks to improve energy efficiency of industrial equipment. Efforts to improve energy efficiency also apply to the paint shops, where the recovery of waste heat is sought. The main source of a large amount of low-temperature waste heat in the paint shop is the spray booth. The second place where a large amount of low temperature waste heat is released is the room where the compressed air is prepared. Low energy efficiency of air compressors requires a large electric power supply. As a result, the emitted large heat fluxes become waste energy of the technological process. Heat is equivalent to up to 93% of the electric power supplied in the air compression process. There are solutions for recovering heat from compressors coming from the oil cooling water, but then the waste heat from the cooling of the compressed air and from the electric motor is released into air in the room. A method for recovering low-temperature waste heat from the air preparation room by means of an air-source heat pump has been proposed. An energy balance of the air compression and dehumidification process for the paint shop was made. A Matlab’s built-in numerical model includes air compressor and dehumidifier, heat recovery and accumulation for the purposes of use in the spray booth. A simulation experiment was carried out on the effectiveness of heat recovery from the air preparation room. The use of combined energy management in paint shops was proposed.
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Słowa kluczowe Slag Copper recovery Recycling

Abstrakt

There are presents the internal recycling in anode furnace, in addition to mainly blister copper and converter copper. During the process there arise the two types of semi-finished products intended for further pyro metallurgical processing: anode copper and anode slag. The stream of liquid blister copper enters into the anode furnace treatment, in which the losses are recovered, e.g. copper, resulting from oxidation and reduction of sulfides, oxides and the oxidation of metallic compounds of lead, zinc and iron. In the liquid phase there are still gaseous states, which gives the inverse relationship relating to the solid phase, wherein the gases found an outlet in waste gas or steam. The results of chemical analysis apparently differ from each other, because crystallite placement, the matrix structure and the presence of other phases and earth elements are not compared, which can be regained in the process of electrorefining. One should not interpret negatively smaller proportion of copper in the alloy, since during the later part of the production more elements can be obtained, for example from sludge, such as platinum group metals and lanthanides. According to the research the quality of blister copper, to a large extent, present in the alloy phase to many other elements, which can be recovered.
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The purpose of this article was to discuss the use of adsorption chillers for waste heat recovery. The introduction discusses the need to undertake broader measures for the effective management of waste heat in the industry and discusses the benefits and technical problems related to heat recovery in industrial plants. In addition, heat sources for adsorption chillers and their application examples were described. The principle of operation of adsorption chillers is explained in the next chapter. Heat sources for adsorption chillers are indicated and their application examples are described. The above considerations have allowed the benefits and technical obstacles related to the use of adsorption chillers to be highlighted. The currently used adsorbents and adsorbates are discussed later in the article. The main part of the paper discusses the use of adsorption chillers for waste heat management in the glassworks. The calculations assumed the natural gas demand of 20.1 million m3 per year and the electricity demand of 20,000 MWh/year. As a result of conducted calculations, a 231 kW adsorption chiller, ensuring the annual cold production of 2,021 MWh, was selected. The economic analysis of the proposed solution has shown that the investment in the adsorption chiller supplied with waste heat from the heat recovery system will bring significant economic benefits after 10 years from its implementation, even with total investment costs of PLN 1,900,000. However, it was noted that in order to obtain satisfactory economic results the production must meet the demand while the cost of building a heat recovery system shall not exceed PLN 1 million.
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There are approx. 250 coal waste dumping grounds in Poland, yet there are countries in which this number is even higher. One of the largest sites for depositing mining and power plant waste in the Upper Silesian Coal Basin is the Przezchlebie dumping ground. In the article, it is considered as a secondary deposit of raw materials. An assessment of mining waste collected on the Przezchlebie dumping ground was carried out in terms of its impact on the environment and the possibility of its use. Mining waste samples were tested to determine their chemical composition. Physicochemical properties and chemical compositions of water extracts obtained from the investigated waste and groundwater in the vicinity of the dumping ground were analyzed. Due to the fire hazard resulting from the natural oxidation process of chiefly carbonaceous matter and pyrite, the thermal condition of the dumping ground was assessed. The results of the obtained tests confirmed the slight impact of mining waste deposited on the Przezchlebie dumping ground on the environment. The chemical composition, low radioactive activity of waste itself and the results of water extract tests referred to the permissible values according to the Polish Journal of Laws allow for multi-directional waste management. Due to the significant carbon content, the risk of self-ignition poses a significant threat on the dumping ground. Re-mining of the dumping ground and the recovery of raw materials, including coal contained in waste, will eliminate the risk of fire, allowing for a wider use of waste and, at the same time, will allow for other benefits, e.g. in the form of financial resources and the possibility of managing the dumping ground area.
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Turbine stages can be divided into two types: impulse stages and reaction stages. The advantages of one type over the second one are generally known based on the basic physics of turbine stage. In this paper these differences between mentioned two types of turbines were indicated on the example of single stage turbines dedicated to work in organic Rankine cycle (ORC) power systems. The turbines for two ORC cases were analysed: the plant generating up to 30 kW and up to 300 kW of net electric power, respectively. Mentioned ORC systems operate with different working fluids: DMC (dimethyl carbonate) for the 30 kW power plant and MM (hexamethyldisiloxane) for the 300 kW power plant. The turbines were compared according to three major issues: thermodynamic and aerodynamic performance, mechanical and manufacturing aspects. The analysis was performed by means of the 0D turbomachinery theory and 3D computational aerodynamic calculations. As a result of this analysis, the paper indicates conclusions which type of turbine is a recommended choice to use in ORC systems taking into account the features of these systems.
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This paper presents studies carried out in a pilot-scale plant for recovery of waste heat from a flue gas which has been built in a lignite-fired power plant. The purpose of the studies was to check the operation of the heat recovery system in a pilot scale, while the purpose of the plant was recovery of waste heat from the flue gas in the form of hot water with a temperature of approx. 90 °C. The main part of the test rig was a condensing heat exchanger designed and built on the basis of laboratory tests conducted by the authors of this paper. Tests conducted on the pilot-scale plant concerned the thermal and flow parameters of the condensing heat exchanger as well as the impact of the volumetric flow rate of the flue gas and the cooling water on the heat flux recovered. Results show that the system with a condensing heat exchanger for recovery of low-temperature waste heat from the flue gas enables the recovery of much higher heat flux as compared with conventional systems without a condensing heat exchanger.
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In the present work, amine based extractant and its mixture with cationic and solvating extractants were tested for the extraction of HCl from chloride solution containing Al(III). The chloride feed solution resulted from the leaching of spent HDS (hydro-desulfurization) catalysts. For this purpose, amine extractants, such as TOA (trioctyl amine), Alamine 336 (a mixture of tri-octyl/decyl amine), Alamine 308 (tri-isooctyl amine), and TEHA (tri 2-ethylhexyl amine) were used and the extraction and stripping behavior of HCl was compared. The extracted HCl was easily stripped from loaded TEHA phase, when compared with the other tested tertiary amine system. Solvent extraction reaction of HCl by TEHA was determined from the extraction data. Unlike TOA and Alamine 336, adding cationic extractant to TEHA had negligible effect on the extraction and stripping of HCl. In our experimental ranges, no Al was extracted by amines and pure HCl was recovered. MaCabe- Thiele diagrams for the extraction and stripping of HCl by TEHA were constructed.
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Abstrakt

Oxide fraction of industrial zinc ash from hot dip galvanizing was characterized in terms of composition and leaching behaviour in 10% sulfuric acid solution. Waste product contained about 68% Zn, 6% Cl, 3% Al, 1% Fe, 0.7% Si, 0.5% Pb and minor percentages of other metals (Mn, Cu, Ti etc.). It consisted mainly of zinc oxide contaminated with metallic zinc, zinc hydroxide chloride and silica. Dissolution of the metals from the material was determined as a function of solid to liquid ratio (50-150 kg/m3), temperature (20°C and 35°C) and agitation rate (300 and 900 rpm). The best results (50 g/dm3 Zn(II) at 78% zinc recovery) were obtained for 100 kg/m3 and the temperature of 20°C. Increase in the agitation rate had weak effect on the zinc yield. The final solutions were contaminated mainly by Fe(II, III) ions. Leaching of the material was an exothermic process with the reaction heat of about 800 kJ/kg.
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Rare earth metals including yttrium and europium are one of several critical raw materials, the use of which ensures the development of the so-called high technology. The possibility of their recovery in Europe is limited practically only to secondary materials such as phosphogypsum and electronic waste. The article presents the results of our research concerning the development of recovery technology of yttrium and europium from luminophore CRT used lamps. It describes the principle of separation of elements and the test results of cleaning the concentrate. It was shown that the costs of preparing the concentrate according to the proposed technology are lower than the phosphogypsum processing technology and the composition of the resulting product does not contain hazardous substances.
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The article analyzes the risk factors related to the energy use of alternative fuels from waste. The essence of risk and its impact on economic activity in the area of waste management were discussed. Then, a risk assessment, on the example of waste fractions used for the production of alternative fuel, was carried out. In addition, the benefits for the society and the environment from the processing of alternative fuels for energy purposes, including, among others: reducing the cost of waste disposal, limiting the negative impact on water, soil and air, reducing the amount of waste deposited, acquisition of land; reduction of the greenhouse effect, facilitating the recycling of other fractions, recovery of electricity and heat, and saving conventional energy carriers, were determined. The analysis of risk factors is carried out separately for plants processing waste for alternative fuel production and plants producing energy from this type of fuel. Waste processing plants should pay attention to investment, market (price, interest rate, and currency), business climate, political, and legal risks, as well as weather, seasonal, logistic, technological, and loss of profitability or bankruptcy risks. Similar risks are observed in the case of energy companies, as they operate in the same external environment. Moreover, internal risks may be similar; however, the specific nature of the operation of each enterprise should be taken into account. Energy companies should pay particular attention to the various types of costs that may threaten the stability of operation, especially in the case of regulated energy prices. The risk associated with the inadequate quality of the supplied and stored fuels is important. This risk may disrupt the technological process and reduce the plant’s operational efficiency. Heating plants and combined heat and power plants should also not underestimate the non-catastrophic weather risk, which may lead to a decrease in heat demand and a reduction in business revenues. A comprehensive approach to risk should protect enterprises against possible losses due to various types of threats, including both external and internal threats.
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The paper illustrates a case study of fluid selection for an internal combustion engine heat recovery organic Rankine cycle (ORC) system having the net power of about 30 kW. Various criteria of fluid selection are discussed. Particular attention is paid to thermodynamic performance of the system and human safety. The selection of working fluid for the ORC system has a large impact on the next steps of the design process, i.e., the working substance affects the turbine design and the size and type of heat exchangers. The final choice is usually a compromise between thermodynamic performance, safety and impact on natural environment. The most important parameters in thermodynamic analysis include calculations of net generated power and ORC cycle efficiency. Some level of toxicity and flammability can be accepted only if the leakages are very low. The fluid thermal stability level has to be taken into account too. The economy is a key aspect from the commercial point of view and that includes not only the fluid cost but also other costs which are the consequence of particular fluid selection. The paper discusses various configurations of the ORC system – with and without a regenerator and with direct or indirect evaporation. The selected working fluids for the considered particular power plant include toluene, DMC (dimethyl carbonate) and MM (hexamethyldisiloxane). Their advantages and disadvantages are outlined.
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Abstrakt

Polish brines are highly mineralized and can potentially be used for recovery of selected useful elements such as magnesium and potassium. They also contain a number of other elements, including iodine, bromine, boron, and strontium. The results of the examination of the chemical composition of groundwater from the Mesozoic formations (bromine, iodine, lithium, magnesium, and strontium content) of northern and central Poland were analyzed. The basic statistical parameters of the content of these elements (Br, I, Mg) in brines of the Triassic, Jurassic, and Cretaceous deposits and the content of lithium and strontium in waters of the entire Mesozoic formations were determined. In order to indicate aquifers that are the most suitable for the recovery of bromine, iodine, lithium, magnesium, and strontium, the relationship between concentrations and the depth of retention and dependencies between selected chemical components of these waters were analyzed. It has been found that the mineralization and concentrations of magnesium, bromine, and iodine increase with the age of aquifers, where these waters occur. Triassic waters are the most prospective for bromine and magnesium recovery among all analyzed aquifers. Furthermore, a relationship between the content of bromine, strontium, and magnesium has also been observed. The increase in the content of individual elements observed for lithium, strontium, and bromine with the increasing depth indicates a potential abundance of waters occurring at significant depths. The presented analysis is an approximation of the content of bromine, iodine, lithium, magnesium, and strontium; however, it may be the basis for further studies on the perspectives of using brines from the Mesozoic deposits of central and northern Poland as a source of chemical raw materials.
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The present work deals with ultrasound assisted crystallisation of lactose from lactose solution. The crystallisation of lactose was completed rapidly by applying the ultrasound waves in the presence of an anti-solvent (n-propanol), at the room temperature (30±3°C). The yield of lactose was found to be more than 85% (w/w) in 4 minutes of sonication. The spread of the crystal size distribution was found to decrease with increase in sonication time.
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Copper slag is a by-product obtained during smelting and refining of copper. Copper smelting slag typically contains about 1 wt.% copper and 40 wt.% iron depending upon the initial ore quality and the furnace type. Main components of copper slag are iron oxide and silica. These exist in copper slag mainly in the form of fayalite (2FeO ·SiO2). This study was intended to recover pig iron from the copper smelting slag by reduction smelting method. At the reaction temperature of below 1400°С the whole copper smelting slag was not smelted, and some agglomerated, showing a mass in a sponge form. The recovery behavior of pig iron from copper smelting slag increases with increasing smelting temperature and duration. The recovery rate of pig iron varied greatly depending on the reaction temperature.
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Considering the advantages of hollow fiber supported liquid membrane (HFSLM), it has been applied for extraction of Co(II) with a motivation to extract cobalt from various waste resources. Extraction efficiency and transport behavior of Co(II) through HFSLM containing Cyanex 272 diluted in kerosene were investigated. Experiments were performed as a function of aqueous feed solution velocity (1000 mL/min) for both feed and strip, pH of feed solution in the range of 4.00-6.75, the carrier concentration of 25-1000 mol/m3, and acid concentration in strip solution of 1-500 mol/m3on. The mass transfer rate or flux JCo(II), which is a function of metal concentration, volume of solution, and membrane area were analyzed. The optimum condition for extraction of Co(II) was pH of 6.00, Cyanex 272 concentration of 500 mol/m3 and H2SO4 concentration of 100 mol/m3.
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In the paper, the extended finite element method (XFEM) is combined with a recovery procedure in the analysis of the discontinuous Poisson problem. The model considers the weak as well as the strong discontinuity. Computationally efficient low-order finite elements provided good convergence are used. The combination of the XFEM with a recovery procedure allows for optimal convergence rates in the gradient i.e. as the same order as the primary solution. The discontinuity is modelled independently of the finite element mesh using a step-enrichment and level set approach. The results show improved gradient prediction locally for the interface element and globally for the entire domain.
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New technologies and the globalization of the electrical and electronic equipment market cause a continuous increase in the amount of electrical and electronic waste. They constitute one of the waste groups that grows the fastest in quantity. The development of the new generation of electrical and electronic devices is much faster than before. Recently attention has been concentrated on hydrometallurgical methods for the recovery of metals from electronic waste. In this article the role of an oxidizing agent, mainly ozone and hydrogen peroxide was presented in hydrometallurgical processes. Leaching process of printed circuits boards (PCBs) from used cell phones was conducted. The experiments were carried out in the presence of sulfuric acid and ozone as an oxidizing agent for various temperatures, acid concentration, ozone concentration. As a result, the concentrations of copper, zinc, iron and aluminum in the obtained solution were measured. The obtained results were compared to results obtained earlier in the presence of hydrogen peroxide as an oxidizing agent and discussed.
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The scope of work included the launch of the process of refining slag suspension in a gas oven using a variety of technological additives. After the refining process (in the context of copper recovery), an assessment of the effect of selected reagents at the level of the slag refining suspension (in terms of copper recovery). Method sieve separated from the slag waste fraction of metallic, iron - silicate and powdery waste. Comparison of these photographs macroscopic allowed us to evaluate the most advantageous method of separating metallic fraction from the slag. After applying the sample A (with KF2 + NaCl) we note that in some parts of the slag are still large amounts of metallic fraction. The fraction of slag in a large majority of the elements has the same size of 1 mm, and a larger portion of the slag, the size of which is from 2 to 6 mm. Definitely the best way is to remove the copper by means of the component B (with NaCl ) and D (with KF2 ). However, as a result of removing the copper by means of component C (with CaO) were also obtained a relatively large number of tiny droplets of copper, which was problematic during segregation. In both cases we were able to separate the two fractions in a fast and simple manner.
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The end−Permian mass extinction constituted a major event in the history of crinoids. It led to the demise of the major Paleozoic crinoid groups including cladids, disparids, flexibles and camerates. It is widely accepted that a single lineage, derived from a late Paleozoic cladid ancestor (Ampelocrinidae), survived this mass extinction. Holocrinid crinoids ( Holocrinus , Holocrinida) along with recently described genus Baudicrinus (Encrinida), the only crinoid groups known from the Early Tria ssic, are considered the stem groups for the post−Paleozoic monophyletic subc lass Articulata. Here, we report preliminary data on unexpectedly diverse crinoid faunas comprisin g at least four orders from the Lower Triassic (Induan and Olenekian) of Svalbard, extending their stratigraphic ranges deeper into the early Mesozoic. These findings strongly imply that the recovery of crinoids in the aftermath of the end−Permian extinction began much earlier at higher palaeolatitudes than in the central Tethys.
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In view of the permanent increase of the municipal solid waste incineration (MSWI) residues amount, the numerous attempts to find a way of their recovery have been undertaken. In this paper the idea of the recovery of the MSWI residues in Kłodawa salt mine is presented. The idea is to fill the waste in underground workings, close and/or backfill the underground excavations with self-solidifying mixture prepared on the basis of MSWI grained solid residues. Two techniques are proposed: 1) hydraulic backfill technique (HBT) where the mixture is prepared in the surface installation and pumped down into the underground workings through shaft and the pipelines and 2) dry waste technique (DWT), where dry grained waste is dropped into the mine by pneumatic pipeline transport, then supplied to the underground mixture-preparing- installation and pumped as a thin liquid or paste into the selected workings. The description of the technology is preceded by general characteristic of the hardening backfill in underground mines and by characteristic of MSWI residues, drafted on the basis of the literature review.
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Electronic Double-Layer Capacitors (EDLC), called Supercapacitors (SC), are electronic devices that are capable to store a relatively high amount of energy in a small volume comparing to other types of capacitors. They are composed of an activated carbon layer and electrolyte solution. The charge is stored on electrodes, forming the Helmholtz layer, and in electrolyte. The capacitance of supercapacitor is voltage- dependent. We propose an experimental method, based on monitoring of charging and discharging a supercapacitor, which enables to evaluate the charge in an SC structure as well as the Capacitance-Voltage (C-V) dependence. The measurement setup, method and experimental results of charging/discharging commercially available supercapacitors in various voltage and current conditions are presented. The total charge stored in an SC structure is proportional to the square of voltage at SC electrodes while the charge on electrodes increases linearly with the voltage on SC electrodes. The Helmholtz capacitance increases linearly with the voltage bias while a sublinear increase of total capacitance was found. The voltage on SC increases after the discharge of electrodes due to diffusion of charges from the electrolyte to the electrodes. We have found that the recovery voltage value is linearly proportional to the initial bias voltage value.
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