In spite of the fact that in most applications, magnesium alloys are intended for operation in environments with room temperature, these alloys are subject to elevated temperature and oxidizing atmosphere in various stages of preparation (casting, welding, thermal treatment). At present, the studies focus on development of alloys with magnesium matrix, intended for plastic forming. The paper presents results of studies on oxidation rate of WE43 and ZRE1 magnesium foundry alloys in dry and humidified atmosphere of N2+1%O2. Measurements of the oxidation rate were carried out using a Setaram thermobalance in the temperature range of 350-480°C. Corrosion products were analyzed by SEM-SEI, BSE and EDS. It was found that the oxide layer on the WE43 alloy has a very good resistance to oxidation. The high protective properties of the layer should be attributed to the presence of yttrium in this alloy. On the other hand, a porous, two-layer scale with a low adhesion to the substrate forms on the ZRE1 alloy. The increase in the sample mass in dry gas is lower than that in humidified gas.
Magnesium alloys thanks to their high specific strength have an extensive potential of the use in a number of industrial applications. The most important of them is the automobile industry in particular. Here it is possible to use this group of materials for great numbers of parts from elements in the car interior (steering wheels, seats, etc.), through exterior parts (wheels particularly of sporting models), up to driving (engine blocks) and gearbox mechanisms themselves. But the use of these alloys in the engine structure has its limitations as these parts are highly thermally stressed. But the commonly used magnesium alloys show rather fast decrease of strength properties with growing temperature of stressing them. This work is aimed at studying this properties both of alloys commonly used (of the Mg-Al-Zn, Mn type), and of that ones used in industrial manufacture in a limited extent (Mg-Al-Sr). These thermomechanical properties are further on complemented with the microstructure analysis with the aim of checking the metallurgical interventions (an effect of inoculation). From the studied materials the test castings were made from which the test bars for the tensile test were subsequently prepared. This test took place within the temperature range of 20°C – 300°C. Achieved results are summarized in the concluding part of the contribution.
To the main advantages of magnesium alloys belongs their low density, and just because of such property the alloys are used in aviation and rocket structures, and in all other applications, where mass of products have significant importance for conditions of their operation. To additional advantages of the magnesium alloys belongs good corrosion resistance, par with or even surpassing aluminum alloys. Magnesium is the lightest of all the engineering metals, having a density of 1.74 g/cm3 . It is 35% lighter than aluminum (2.7 g/cm3 ) and over four times lighter than steel (7.86 g/cm3 ). The Mg-Li alloys belong to a light-weight metallic structural materials having mass density of 1.35-1.65 g/cm3 , what means they are two times lighter than aluminum alloys. Such value of mass density means that density of these alloys is comparable with density of plastics used as structural materials, and therefore Mg–Li alloys belong to the lightest of all metal alloys. In the present paper are discussed melting and crystallization processes of ultra-light weight MgLi12,5 alloys recorded with use of ATND methods. Investigated magnesium alloy was produced in Krakow Foundry Research Institute on experimental stand to melting and casting of ultra-light weight alloys. Obtained test results in form of recorded curves from ATND methods have enabled determination of characteristic temperatures of phase transitions of the investigated alloy.
Experimental Mg-Al-RE type magnesium alloys for high-pressure die-casting are presented. Alloys based on the commercial AM50 magnesium alloy with 1, 3 and 5 mass % of rare earth elements were fabricated in a foundry and cast in cold chamber die-casting machines. The obtained experimental casts have good quality surfaces and microstructure consisting of an α(Mg)-phase, Al11RE3, Al10RE2Mn7 intermetallic compound and small amount of α+γ eutectic and Al2RE phases.
The article presents tests results of the influence of deformation methods on the microstructure and properties of alloy WE43. There were direct extrusion tests and extrusion with KoBo method performed. An assessment of the influence of the methods of deformation on the microstructure and the mechanical properties of the achieved rods from alloy WE43 was conducted. There was an analysis of microstructure carried out with the use of light and scanning microscopy techniques in the initial state and after plastic deformation. Static tensile test was conducted in temperature of 350°C at a speed of 0.0001 m·s–1 and microhardness measurements were performed of HV0.2. On the basis of the achieved mechanical tests results it was stated that in the temperature of 350°C for samples deformed with the use of KoBo method there was an effect of superplastic flow found. The value of elongation achieved was 250% which was 3 times higher than in case of classic extrusion (80%).
Magnesium alloys are one of the lightest of all the structural materials. Because of their excellent physical and mechanical properties the alloys have been used more and more often in various branches of industry. They are cast mainly (over 90%) on cold and hot chamber die casting machines. One of the byproducts of casting processes is process scrap which amounts to about 40 to 60% of the total weight of a casting. The process scrap incorporates all the elements of gating systems and fault castings. Proper management of the process scrap is one of the necessities in term of economic and environmental aspects. Most foundries use the process scrap, which involves adding it to a melting furnace, in a haphazard way, without any control of its content in the melt. It can lead to many disadvantageous effects, e.g. the formation of a hard buildup at the bottom of the crucible, which in time makes casting impossible due to the loss of the alloy rheological properties. The research was undertaken to determine the effect of an addition of the process scrap on the mechanical properties of AZ91 and AM50 alloys. It has been ascertained that the addition of a specific amount of process scrap to the melt increases the mechanical properties of the elements cast from AZ91 and AM50 alloys. The increase in the mechanical properties is caused mainly by compounds which can work as nuclei of crystallization and are introduced into the scrap from lubricants and anti-adhesive agents. Furthermore carbon, which was detected in the process scrap by means of SEM examination, is a potent grain modifier in Mg alloys [1-3]. The optimal addition of the process scrap to the melt was determined based on the statistical analysis of the results of studies of the effect of different process scrap additions on the mean grain size and mechanical properties of the cast parts.
This work presents the results of the research of the effect of the inoculant Emgesal Flux 5 on the microstructure of the magnesium alloy AZ91. The concentration of the inoculant was increased in samples in the range from 0.1% to 0.6%. The thermal processes were examined with the use of Derivative and Thermal Analysis (DTA). During the examination, the DTA samplers were preheated up to 180 °C. A particular attention was paid to finding the optimum amount of inoculant, which would cause fragmentation of the microstructure. The concentration of each element was verified by means of a spark spectrometer. In addition, the microstructures of the samples were examined with the use of an optical microscope, and an image analysis with a statistical analysis using the NIS–Elements program were carried out. Those analyses aimed at examining the differences between the grain diameters of phase αMg and eutectic αMg+γ(Mg17Al12) in the prepared samples as well as the average size of each type of grain by way of measuring their perimeters. This paper is an introduction to a further research of grain refinement in magnesium alloys, especially AZ91. Another purpose of this research is to achieve better microstructure fragmentation of magnesium alloys without the related changes of the chemical composition, which should improve the mechanical properties.
In this work, the effect of the microstructure on corrosion behavior of selected Mg- and Al-based as cast alloys, was evaluated. The electrochemical examinations were carried out, and then a morphology of corrosion products formed due to local polarization on materials surface, was analyzed. It was documented that the presence of Mg2Si phase plays an important role in the corrosion course of Mg-based alloy. A selective etching was observed in sites of Mg2Si precipitates having “Chinese script”- like morphology. Analogous situation was found for Al-based alloy, where the key role was played by cathodic θ-CuAl2 phase.
This paper discusses the joining of AZ91 magnesium alloy with AlSi17 aluminium alloy by compound casting. Molten AZ91 was cast at 650oC onto a solid AlSi17 insert placed in a steel mould under normal atmospheric conditions. Before casting, the mould with the insert inside was heated up to about 370oC. The bonding zone forming between the two alloys because of diffusion had a multiphase structure and a thickness of about 200 µm. The microstructure and composition of the bonding zone were analysed using optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. The results indicate that the bonding zone adjacent to the AlSi17 alloy was composed of an Al3Mg2 intermetallic phase with not fully consumed primary Si particles, surrounded by a rim of an Mg2Si intermetallic phase and fine Mg2Si particles. The bonding zone near the AZ91 alloy was composed of a eutectic (an Mg17Al12 intermetallic phase and a solid solution of Al and Si in Mg). It was also found that the compound casting process slightly affected the AZ91alloy microstructure; a thin layer adjacent to the bonding zone of the alloy was enriched with aluminium.
The work presents the test result of the influence of cooling rate on the microstructure of AZ91 alloy, Vickers micro-hardness and Brinell hardness. Studies cooling and crystallization of AZ91 alloy was cast into the ceramic shells pre-heated to 180 ° C and then air-cooled at ambient temperature or intensively super cooled in the liquid coolant. The TDA method was applied to record and characterize the thermal effect resulting from the phase transformations occurring during the crystallization of AZ91 alloy. The kinetics and dynamics of the thermal processes of crystallization of AZ91 alloy in the ceramic shells were determined. Metallographic tests were performed with the use of an optical microscope. A comparison of these test results with the thermal effect recorded by way of the TDA method was made. Influence of cooling rate of AZ91 on HV0, 01 micro-hardness and Brinell hardness alloy was examined.
The work presents the results of the investigations of the effect of inhibitors coated on the internal walls of a ceramic mould on the quality of the obtained casts made of the AM60 alloy containing additions of chromium and vanadium. In order to reduce the reactivity of magnesium alloy cast by the technology of investment casting with the material of the mould and the ambient atmosphere, solid inhibitors were applied in the form of a mixture of KBF4 and H3BO3 after the stage of mould baking and before the mould’s being filled with the liquid alloy. For the purpose of examining the effect of the inhibitors on the surface quality of the obtained casts, profilometric tests were performed and the basic parameters describing the surface roughness, Ra, Rz and Rm, were determined.
The work presents the results of examinations concerning the influence of various amounts of home scrap additions on the properties of castings made of MgAl9Zn1 alloy. The fraction of home scrap in the metal charge ranged from 0 to 100%. Castings were pressure cast by means of the hot-chamber pressure die casting machine under the industrial conditions in one of the domestic foundries. The examinations consisted in the determination of the following properties: tensile strength Rm, yield strength Rp0.2, and the unit elongation A5, all being measured during the static tensile test. Also, the hardness measurements were taken by the Brinell method. It was found that the mechanical properties (mainly the strength properties) are being improved up to the home scrap fraction of 50%. Their values were increased by about 30% over this range. Further rise in the home scrap content, however, brought a definite decrease in these properties. The unit elongation A5 exhibited continual decrease with an increase in the home scrap fraction in the metal charge. A large growth of hardness was noticed for the home scrap fraction increasing up to the value of 50%. Further increasing the home scrap percentage, however, did not result in a significant rise of the hardness value any more.
The work presents the results of examinations concerning the influence of various amounts of home scrap additions on the porosity of castings made of MgAl9Zn1 alloy. The fraction of home scrap in the metal charge ranged from 0 to 100%. Castings were pressure cast by means of the hot-chamber pressure die casting machine under the industrial conditions in one of the domestic foundries. Additionally, for the purpose of comparison, the porosity of specimens cut out directly of the MgAl9Zn1 ingot alloy was also determined. The examinations consisted in the qualitative assessment of porosity by means of the optical microscopy and its quantitative determination by the method of weighting specimens in air and in water. It was found during the examination that the porosity of castings decreases with an increase in the home scrap fraction in the metal charge. The qualitative examinations confirmed the beneficial influence of the increased home scrap fraction on the porosity of castings. It was concluded that the reusing of home scrap in a foundry can be a good way of reduction of costs related to the production of pressure castings.
The results of estimation of home scrap addition in charge influence on durability and wear of casting instrumentation life in the highpressure casting technology using the hot chamber machine of alloy of AZ91 are presented. The wear of the following elements of the casting instrumentation so-called "casting set" as: syphon, plunger, sliding-rings, nozzle and injection moulding nozzle was estimated. A wear was estimated quantitative by registering the number of mould injections for different charges to the moment of element damage supervision. A damage had to be at such level that liquidated an element from further exploitation and necessary was an exchange on new or regeneration. In a final result allowed it the detailed determination of durability of the applied rigging elements in dependence on the type of the applied type of melt. It is noticed, that together with the increase of home-scrap participation in the charge wear of pressure machine instrumentation elements increases.