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Abstract

The paper discusses the feasibility, effectiveness and validity of a gas turbine power plant, operated according to the Brayton comparative cycle in order to develop low-potential waste heat (160◦C) and convert it into electricity. Fourteen working fluids, mainly with organic origin have been examined. It can be concluded that low molecular weight working fluids allow to obtain higher power efficiency of Brayton cycle only if conversions without taking into account internal losses are considered. For the cycle that takes into account the compression conversion efficiency in the compressor and expansion in the gas turbine, the highest efficiency was obtained for the perfluoropentane working medium and other substances with relatively high molecular weight values. However, even for the cycle using internal heat recovery, the thermal efficiency of the Brayton cycle did not exceed 7%.The paper discusses the feasibility, effectiveness and validity of a gas turbine power plant, operated according to the Brayton comparative cycle in order to develop low-potential waste heat (160◦C) and convert it into electricity. Fourteen working fluids, mainly with organic origin have been examined. It can be concluded that low molecular weight working fluids allow to obtain higher power efficiency of Brayton cycle only if conversions without taking into account internal losses are considered. For the cycle that takes into account the compression conversion efficiency in the compressor and expansion in the gas turbine, the highest efficiency was obtained for the perfluoropentane working medium and other substances with relatively high molecular weight values. However, even for the cycle using internal heat recovery, the thermal efficiency of the Brayton cycle did not exceed 7%.
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Abstract

SI engines are highly susceptible to excess emissions when started at low ambient temperatures. This phenomenon has multiple air quality and climate forcing implications. Direct injection petrol engines feature a markedly different fuelling strategy, and so their emissions behaviour is somewhat different from indirect injection petrol engines. The excess emissions of direct injection engines at low ambient temperatures should also differ. Additionally, the direct injection fuel delivery process leads to the formation of PM, and DISI engines should show greater PM emissions at low ambient temperatures. This study reports on laboratory experiments quantifying excess emissions of gaseous and solid pollutants over a legislative driving cycle following cold start at a low ambient temperature for both engine types. Over the legislative cycle for testing at -7°C (the UDC), emissions of HC, CO, NOx and CO2 were higher when tested at -7°C than at 24°C. Massive increases in emissions of HC and CO were observed, together with more modest increases in NOx and CO2 emissions. Results from the entire driving cycle showed excess emissions in both phases (though they were much larger for the UDC). The DISI vehicle showed lower increases in fuel consumption than the port injected vehicles, but greater increases in emission of HC and CO. DISI particle number emissions increased by around 50%; DISI particle mass by over 600%. The observed emissions deteriorations varied somewhat by engine type and from vehicle to vehicle. Excesses were greatest following start-up, but persisted, even after several hundred seconds’ driving. The temperature of the intake air appeared to have a limited but significant effect on emissions after the engine has been running for some time. All vehicles tested here comfortably met the relevant EU limits, providing further evidence that these limits are no longer challenging and need updating.
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Abstract

In this study a two-step short wet etching was implemented for the black silicon formation. The proposed structure consists of two steps. The first step: wet acidic etched pits-like morphology with a quite new solution of lowering the texturization temperature and second step: wires structure obtained by a metal assisted etching (MAE). The temperature of the process was chosen due to surface development control and surface defects limitation during texturing process. This allowed to maintain better minority carrier lifetime compared to etching in ambient temperature. On the top of the acidic texture the wires were formed with optimized height of 350 nm. The effective reflectance of presented black silicon structure in the wavelength range of 300-1100 nm was equal to 3.65%.
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