The determination of the content of ecotoxic elements directly in flue gas is important for determining its actual emission from coal combustion. Moreover, in the BAT for large combustion plants conclusions adopted in 2017, apart from tightening of pollutants emission standards, i.e. SO 2, NO x and dusts, and setting emission limits, among others, for mercury, the monitoring of the actual emission of toxic elements has been established with the use of specific analytical methods. The review and comparison of available methods of analyzing the content of elements in flue gases in accordance with American and European standards has been presented in the article. Moreover, the factors influencing the quality of the obtained measurement results were identified.
Evaluation apprehension is the anxiety arising from a concern that one’s knowledge or expertise may be evaluated unfavorably by an audience. In this regard, the educational field comprising students’ discussions, lectures, presentations, and interactions is not an exception. Plethora of studies on student apprehension demonstrated that the construct is under the influence of different factors and can create various consequences. The aim of the present review is to complement and encapsulate previous research on student apprehension by providing an updated review on the concept in different disciplines. Data from 30 studies published in Elsevier, Springer, Taylor & Francis, and System were coded based on a coding scheme. The studies were broadly classified into four categories in the realm of education in terms of students’ disciplines; namely, Second/Foreign Language Learning (9 studies), Accounting and Finance (4 studies), Medicine, Nursing, and Pharmacy (6 studies), and miscellaneous disciplines (11 studies). The focus of this review pivoted around antecedents and consequences of student apprehension in each field. The analysis demonstrated the multidimensional nature of the construct caused by a host of variables and resulting in a multitude of ramifications. Based on these findings, some implications and strategies for mitigating student evaluation apprehension are presented.
The existing Polish gravity control (POGK) established in the last few years of 20th century according to the international standards is spanned on 12 absolute gravity stations surveyed with four different types of absolute gravimeters. Relative measurements performed by various groups on nearly 350 points of POGK with the use of LaCoste&Romberg (LCR) gravimeters were linked to those 12 stations. The construction of the network, in particular the limited number of non homogeneously distributed absolute gravity stations with gravity determined with different instruments in different epochs is responsible for systematic errors in g on POGK stations. The estimate of those errors with the use of gravity measurements performed in 2007-2008 is given and their possible sources are discussed. The development of absolute gravity measurement technologies, in particular instruments for precise field absolute gravity measurements, provides an opportunity to establish new type of gravity control consisting of stations surveyed with absolute gravimeters. New gravity control planned to be established in 2012-2014 will consist of 28 fundamental points (surveyed with the FG5 – gravimeter), and 169 base points (surveyed with the A10 gravimeter). It will fulfill recent requirements of geodesy and geodynamics and it will provide good link to the existing POGK. A number of stations of the new gravity control with precisely determined position and height will form the national combined geodetic network. Methodology and measurement schemes for both absolute gravimeters as well as the technology for vertical gravity gradient determinations in the new gravity control were developed and tested. The way to assure proper gravity reference level with relation to ICAG and ECAG campaigns as well as local absolute gravimeter comparisons are described highlighting the role of metrology in the project. Integral part of the project are proposals of re-computation of old gravity data and their transformation to a new system (as 2nd order network) as well as a definition of gravity system as “zero-tide” system. Seasonal variability of gravity has been discussed indicating that the effects of environmental changes when establishing modern gravity control with absolute gravity survey cannot be totally neglected .
A new method for computation of positive realizations of given transfer matrices of fractional linear continuous-time linear systems is proposed. Necessary and sufficient conditions for the existence of positive realizations of transfer matrices are given. A procedure for computation of the positive realizations is proposed and illustrated by examples.
Conventionally, the filtering technique for attitude estimation is performed using gyros or attitude dynamics models. In order to extend the application range of an attitude filter, this paper proposes a quaternionbased filtering framework for gyroless attitude estimation without an attitude dynamics model. The attitude estimation system is established based on a quaternion kinematic equation and vector observation models. The angular velocity in the system is determined through observation vectors from attitude sensors and the statistical properties of the angular velocity error are analysed. A Kalman filter is applied to estimate the attitude error such that the effect from the angular velocity error is compensated with its statistical properties at each sampling moment. A numerical simulation example is presented to illustrate the performance of the proposed algorithm.
Several surface measurement methods for determining the volume of deep or layered stone exist. One of the key indicators of coal extraction efficiency in open cast mining is to determine the volume of excavated rock. Procedures for determining the volume have been used for many centuries. Determining the extracted volume or layered material has been a periodically recurring role of mine -surveying practice, and mine surveyors apply different methods for its determination. The incorrect determination of the rock volume may result in large economic losses of the mining enterprise. The choice of the method for determining the volume depends on the deadline by which the determined volume has to be submitted to the superior components or the mining enterprise management, as well as on the requirements for accuracy of the volume determination, and a financial limit beyond which this volume determination has to be done. Secondary conditions for determining the volumes include the level of personnel training in the individual procedures and methods of measuring and calculating volumes, the technical standards of the enterprise, the applied instrumentation, hardware and software. The article compares the values of the accurately defined mathematical solid (a cylindrical segment) to the methods of calculating the volume normally used in mining and surveying practice and programs commonly used to calculate volumes in order to determine the threshold value of the systematic deviation in input measurements to determine the volume. The mathematical model is the basis for determining the correct volumes of the extracted material. The surface of the drawn or layered material does not form a smooth surface as a mathematical model. The process of determining volume errors on the mathematical model has been verified on the real body of coal deposition. The comparison of the determination of the errors between the digital terrain model on the mathematical body and the real homogenization coal stock is presented at the Conclusion of the article.
Bogusław Wolniewicz presented his axiological system in four volumes of Filozofia i wartości (“Philosophy and Values”: 1993, 1998, 2003, 2016). For Wolniewicz, just as for his mentor Henryk Elzenberg, axiology is openly assertive and encompasses a painful confrontation of opposite moral beliefs. Wolniewicz’s vision of the reality is gloom, bitter, dramatic and deeply pessimistic. In history he detects unwelcome contributions of demonic powers (Manichaeism), he also believes that human moral character is genetically given and immutable (determinism), that some people are deprived of conscience (dualism), and that the tendency toward evil cannot be reformed (non-meliorism), human reason is not sufficient for a morally good action (voluntarism), while the so-called free will is no more than a manifestation of instincts (irrationalism). Everyone follows their pleasure (hedonism), but not everyone seeks pleasure in the same actions. In particular, some people take pleasure in cruel and destructive behaviour (demonism), while some others mind their own business (utilitarianism), and rare are those who devote themselves to higher values (perfectionism). Religion is a human invention and it emerges as a natural phenomenon in reaction to the fact of mortality. The institution of the Church should nevertheless be honored even by nonbelievers because it supports conservative values. In contemporary Western civilization a crisis can be observed between the conservative part of society (‘right-handed orientation’) and the liberal one (‘left-handed orientation’). Hateful emotions appear on both sides and are dangerous to Western unity. Conservative orientation is attached to the idea of fate, i.e. irrational power that occasionally turns human life into tragedy (fatalism). Wolniewicz’s vision is close to the theology of St. Augustine (original sin, predestination, radical dualism of good and evil) but without a consolation in hope for immortality.
The changes in the paralinguistic (social, economic, cultural) and linguistic sphere influence the quantitative and qualitative changes in a categorically diversified onomastic resource and the communicative flow of its elements on three levels of linguistic contact — nationwide, local and individual. The flow is additionally determined in the sphere of spontaneous everyday communication and in higher communicative functions (official linguistic behaviour). The accumulation of determinants which allow the usage of appropriate names and appellative forms (official and unofficial, e.g. diminutives, feminisms) involves the application of cumulative research methods, including psycho-, socio- and pragmalinguistic description of proper names functioning in communication. The contemporary theory of discourse in its three dimensions — formal, functional and interactional gives this possibility. It also requires the constant specification and standardization of Neoslavonic onomastic terminology.
Henri Bergson as well as Gaston Milhaud undertake a radical critique of the conception of radical determinism because they both think that mind is able to act in a free and creative manner. In the article, I examine to what degree their arguments, aimed to prove this autonomy, converge. I inquire whether their endorsement of freedom of the mental acts led the two philosophers to the same conclusions regarding the cognitive extent of the intellect and therefore the parallel description of the status of scientific cognition.
The normative system of Bogusław Wolniewicz (1927–2017) can be subsumed under three categories: (1) pessimism (fatalism, or ‘tychism’ in Wolniewicz’s terms), (2) moral determinism (‘non-meliorism’), (3) conservatism (‘right-hand orientation’). Ad (1) Wolniewicz was pessimistic in two ways: he believed human life to be tragic (fatalism) and was also convinced that most people are guided by bad instincts (dualism). Ad (2) Wolniewicz believed that moral character was biologically determined and immutable. But his strong position on this subject ignores the classical view of Aristotle or the Stoics for whom moral character (or conscience) was acquired by habit and shaped deliberately. Ad (3) I suggest that a good historical example of conservative tendency was Critias of Athens. His famous fragment of the Sisyphus contains the idea of a supremacy of laws over human passions, and reduces religion to a supportive role with respect to ethics and politics. Wolniewicz’s dualism of right-hand and left-hand orientation encourages me to distinguish between a right-wing and a left-wing perception of value. For a leftist, value is intensity of a chosen feature (progressive value), whereas for a rightist, value is an area of freedom between inacceptable extremities (modular value). On these premises I propose a simple model of axiological conflict between left-wing and right-wing citizens.
Single-frame methods of determining the attitude of a nanosatellite are compared in this study. The methods selected for comparison are: Single Value Decomposition (SVD), q method, Quaternion ESTimator (QUEST), Fast Optimal Attitude Matrix (FOAM) − all solving optimally the Wahba’s problem, and the algebraic method using only two vector measurements. For proper comparison, two sensors are chosen for the vector observations on-board: magnetometer and Sun sensors. Covariance results obtained as a result of using those methods have a critical importance for a non-traditional attitude estimation approach; therefore, the variance calculations are also presented. The examined methods are compared with respect to their root mean square (RMS) error and variance results. Also, some recommendations are given.
The aim of this article is to classify the armed conflict between Ukraine and Russia in light of international law. Firstly, the Russian armed activities are qualified through the lens of use of force and it is shown that Russia committed an aggression. Secondly, the Russian- Ukrainian conflict is qualified according to the law of armed conflict, not only identifying the applicable norms of law of armed conflict but examining whether atrocities have been committed and whether they are war crimes or mere crimes or acts of terror. The article posits that there is an international armed conflict between Russia and Ukraine and in addition a non-international one between Ukrainian insurgents and governmental forces. The methodology used in the article is legal analysis of documents and international law doctrine.
The paper presents a detailed description of one of the newest methods of vacuum saturation of reinforcing preforms in gypsum molds. As an appropriate selection of the infiltration time is a crucial problem during realization of this process, aim of the analysis shown in the paper is to present methods of selection of subatmospheric pressure application time, a sequence of lowering and increasing pressure, as well as examining influence of structure of reinforcing preforms on efficiency of this process. To realize the aim, studies on infiltration of reinforcing preforms made of a corundum sinter of various granulation of sintered particles with a model alloy were conducted. The infiltration process analysis was carried out in two stages. The first stage consisted in investigation of influence of lengthening of sucking off air from the reinforcing preforms on efficiency of this process. In the second stage, an analysis of influence of a two-staged infiltration process on saturation of the studied materials was conducted. Because the studied preforms were of similar porosity, the obtained differences of the saturation level of particular preforms have shown, that the saturation process is influenced mostly by size of pores present in the reinforcement. Because of these differences, each reinforcement type requires individual selection of time and sequence of the saturation process. For reinforcements of higher pore diameter, it is sufficient to simply increase air sucking off time to improve the saturation, while for reinforcement of smaller pore diameter, it is a better solution to apply the two-staged process of sucking off air. Application of the proposed analysis method allows not only obtaining composite castings of higher quality, but also economical optimization of the whole process.
Participants in the study were recreational runners who completed measures of their orientation to exercise, the Five Factor Model of personality, self-efficacy as a specific adaptation (a socio-cognitive construct of personality) and measures of subjective well-being (life satisfaction) and eudaimonic well-being (life engagement). Consistent with previous research, task-oriented (internally focused) motivation to exercise was positively related to extraversion and to conscientiousness, and ego-oriented (externally focused) motivation was positively related to extraversion. Also consistent with previous research, self-efficacy and measures of well-being were positively related to extraversion and conscientiousness. Mediational analyses found that well-being mediated relationships between task-oriented motives and both extraversion and conscientiousness. Self-efficacy mediated the relationship between ego-oriented motives and extraversion. The implications of these results for the study individual differences in exercise motivation are discussed.
The sustainable development of human activities is directly related to the protection of the environment by lowering the anthropogenic stress. Pharmaceuticals – due to their growing consumption (use in medicine, veterinary, animal production, cosmetics) and their incomplete removal in wastewater treatment plants – are classiﬁed as a group of new and rapidly emerging pollutants which have been proven to have a negative impact onto water organisms. In order to ensure the proper protection of human health and the environment there is an urgent necessity of determining pharmaceuticals in clinical, cosmetic, food and environmental samples. Gas (GC) and high performance liquid chromatography (HPLC) are valuable techniques for such determination, especially when they are coupled with mass spectrometry (GC-MS; LC-MS) or tandem mass spectrometry (GC-MS/MS; LC-MS/MS). The purpose of this paper is to present an analysis of sustainability features of analytical techniques in the light of necessity to determine trace amounts of pharmaceuticals in the aforementioned different matrices. Using the Delphi method we performed an analysis of the key sources of the competitive advantages of the application of GC and GC-MS techniques for determining the pharmaceutical residue in clinical, cosmetic, food and environmental samples – compared to techniques based on HPLC or LC-MS. The analysis covered the following areas: (i) the features of the technique, (ii) the price, and (iii) the applicability in various sectors of economy.
States and individuals are the essential building blocks of international law. Normally, their identity seems to be solidly established. However, modern international law is widely permeated by the notion of freedom from natural or societal constraints. This notion, embodied for individuals in the concept of human rights, has enabled human beings to overcome most of the traditional ties of dependency and being subjected to dominant social powers. Beyond that, even the natural specificity of a human as determined by birth and gender is being widely challenged. The law has made far-going concessions to this pressure. The right to leave one’s own country, including renouncing one’s original nationality, epitomizes the struggle for individual freedom. On the other hand, States generally do not act as oppressive powers but provide comprehensive protection to their nationals. Stateless persons live in a status of precarious insecurity. All efforts should be supported which are aimed at doing away with statelessness or non-recognition as a human person through the refusal to issue identity documents. Disputes about the collective identity of States also contain two different aspects. On the one hand, disin tegrative tendencies manifest themselves through demands for separate statehood by min ority groups. Such secession movements, as currently reflected above all in the Spanish provin ce of Catalonia, have no basis in in ternational law except for situations where a group suffers grave structural discrimin ation (remedial secession). As the common homeland of its citizens, every State also has the right to take care of its sociological identity. Many controversies focus on the distin ction between citizens and aliens. This distin ction is well rooted in domestic and in ternational law. Changes in that regard cannot be made lightly. At the universal level, international law has not given birth to a right to be granted asylum. At the regional level, the European Union has put in to force an extremely generous system that provides a right of asylum not only to persons persecuted in dividually, but also affords “subsidiary protection” to persons in danger of bein g harmed by military hostilities. It is open to doubt whether the EU in stitutions have the competence to assign quotas of refugees to in dividual Member States. The relevant judgment of the Court of Justice of the European Union of 6 September 2017 was hasty and avoided the core issue: the compatibility of such decisions with the guarantee of national identity established under Article 4(2) of the EU Treaty.