In this study the results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e., thermal oil/Al2O3and thermal oil/TiO2are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1%, and 5% by weight within temperature range from 20°C to 60°C. Measurement devices were carefully calibrated by comparison obtained results for pure base liquid (thermal oil) with manufacturer’s data. The results obtained for tested nanofluids were compared with predictions made by use of existing models for liquid/solid particles mixtures.
In this paper, effects of non-Fourier thermal wave interactions in a thin film have been investigated. The non-Fourier, hyperbolic heat conduction equation is solved, using finite difference method with an implicit scheme. Calculations have been carried out for three geometrical configurations with various film thicknesses. The boundary condition of a symmetrical temperature step-change on both sides has been used. Time history for the temperature distribution for each investigated case is presented. Processes of thermal wave propagation, temperature peak build-up and reverse wave front creation have been described. It has been shown that (i) significant temperature overshoot can appear in the film subjected to symmetric thermal load (which can be potentially dangerous for reallife application), and (ii) effect of temperature amplification decreases with increased film thickness.
By simulating the actual working conditions of a cable, the temperature variation rule of different measuring points under different load currents was analyzed. On this basis, a three-dimensional finite element model (FEM) was established, and the difference and influence factors between the simulation temperature and the experimental measured value were discussed, then the influence of thermal conductivity on the operating temperature of the conductor layer was studied. Finally, combined with the steady-state thermal conductivity model and the experimental measured data, the relation between thermal conductivity and load current was obtained.
Powdered polyaniline (PANI) was synthesised chemically with different doping anions namely hydrochloric acid, sulphuric acid and para-toluenesulfonic acid (pTSA). Two-step synthetic procedure was utilised at low temperature. The highest reaction efficiency was found for chlorine-doped PANI. Structural characterization with FTIR revealed the vibration bands characteristic to formation of the emeraldine salt. The surface morphology of doped PANIs was studied by SEM images which showed near globular shape and porous structures with different size of the aggregated particles. They were smaller for Cl–- or pTS–-doped PANI while for SO42– the size was markedly larger. The XRD patterns revealed that there are ordered regions especially for pTS– doped PANI, while the highest conductivity value was recorded for Cl– doped one followed by organic pTS– doped and SO42– doped one.
The 13th-century Persian poet Saʿdi from Shiraz is considered to be one of the most prominent representatives of medieval Persian ethical literature. His works full of moralizing anecdotes were well known and widely read not only in Persia, but in the other parts of the Islamic world as well. Due to his highly humanistic approach, the relations between people were one of the most important issues discussed by the poet. This article is an attempt to define the status of ‘speech’ in Saʿdi’s moral imagination and to show how it becomes a key instrument in shaping relations with others. In the poet’s opinion, the right words reasonably spoken, just like an appropriate silence, shape the relationship between people and help them avoid conflict and open dispute. Quarrels and confrontations, according to the poet, not only damage a person literally by exposing his flaws and imperfections of character, thereby compromising his reputation (aberu), but may also undermine the basis of social life, generating hostility between people. That is why Saʿdi urges his readers to use soft and gentle speech in dealing with people and always behave in a conciliatory manner in response to aggression and rudeness. Highlighting the moral aspect of speech, Saʿdi shows how kind words form an invisible veil between people, which should be preserved if man desires to maintain his image, good name and dignity.
Transverse effective thermal conductivity of the random unidirectional fibre-reinforced composite was studied. The geometry was circular with random patterns formed using random sequential addition method. Composite geometries for different volume fraction and fibre radii were generated and their effective thermal conductivities (ETC) were calculated. Influence of fibre-matrix conductivity ratio on composite ETC was investigated for high and low values. Patterns were described by a set of coordination numbers (CN) and correlations between ETC and CN were constructed. The correlations were compared with available formulae presented in literature. Additionally, symmetry of the conductivity tensor for the studied geometries of fibres was analysed.
An emerging ultrasonic technology aims to control high-pressure industrial processes that use liquids at pressures up to 800 MPa. To control these processes it is necessary to know precisely physicochemical properties of the processed liquid (e.g., Camelina sativa oil) in the high-pressure range. In recent years, Camelina sativa oil gained a significant interest in food and biofuel industries. Unfortunately, only a very few data characterizing the high-pressure behavior of Camelina sativa oil is available. The aim of this paper is to investigate high pressure physicochemical properties of liquids on the example of Camelina sativa oil, using efficient ultrasonic techniques, i.e., speed of sound measurements supported by parallel measurements of density. It is worth noting that conventional low-pressure methods of measuring physicochemical properties of liquids fail at high pressures. The time of flight (TOF) between the two selected ultrasonic impulses was evaluated with a cross-correlation method. TOF measurements enabled for determination of the speed of sound with very high precision (of the order of picoseconds). Ultrasonic velocity and density measurements were performed for pressures 0.1–660 MPa, and temperatures 3–30XC. Isotherms of acoustic impedance Za, surface tension #27; and thermal conductivity k were subsequently evaluated. These physicochemical parameters of Camelina sativa oil are mainly influenced by changes in the pressure p, i.e., they increase about two times when the pressure increases from atmospheric pressure (0.1 MPa) to 660 MPa at 30XC. The results obtained in this study are novel and can be applied in food, and chemical industries.
The aim of this work is the development of Cu-Al2O3 composites of copper Cu-ETP matrix composite materials reinforced by 20 and 30 vol.% Al2O3 particles and study of some chosen physical properties. Squeeze casting technique of porous compacts with liquid copper was applied at the pressure of 110 MPa. Introduction of alumina particles into copper matrix affected on the significant increase of hardness and in the case of Cu-30 vol. % of alumina particles to 128 HBW. Electrical resistivity was strongly affected by the ceramic alumina particles and addition of 20 vol. % of particles caused diminishing of electrical conductivity to 20 S/m (34.5% IACS). Thermal conductivity tests were performed applying two methods and it was ascertained that this parameter strongly depends on the ceramic particles content, diminishing it to 100 Wm-1K-1 for the composite material containing 30 vol.% of ceramic particles comparing to 400 Wm-1K-1 for the unreinforced copper. Microstructural analysis was carried out using SEM microscopy and indicates that Al2O3 particles are homogeneously distributed in the copper matrix. EDS analysis shows remains of silicon on the surface of ceramic particles after binding agent used during preparation of ceramic preforms.
Heavy metal pollutants in the leachate of waste landfill are a potential threat to the environment. In this study, the feasibility of using municipal sewage sludge as barrier material for the containment of heavy metal pollutants from solid waste landfills was evaluated by compaction test and hydraulic conductivity test concerning compaction property, impermeability and heavy metal retardation. Results of the compaction test showed that the maximum dry density of 0.79 g·cm−3 was achieved at the optimum water content of about 60%. The hydraulic conductivities of compacted sewage sludge permeated with synthetic heavy metal solutions were in the range of 1.3×10−8 – 6.2×10−9 cm·s−1, less than 1.0 ×10−7cm·s−1 recommended by regulations for barrier materials. Chemical analyses on the effluent from the hydraulic conductivity tests indicated that the two target heavy metals, Zn and Cd in the permeants were all retarded by compacted sewage sludge, which might be attributed to the precipitation and adsorption of heavy metal ions. The results of this study suggest that specially prepared material from sewage sludge could be used as a barrier for waste landfills for its low permeability and strong retardation to heavy metal pollutants.
The objective of this paper is to evaluate the self- healing properties of a commercially-available geosynthetic clay liner (GCL) using flexible-wall permeameter. The GCLs are produced by the same factory, but the contents of bentonite are different. Also the hydraulic conductivities (HC) of GCLs with no defect are different. In this study, specimens were completely saturated under the backpressure of 20 kPa before the test. Permeability tests were performed on GCL specimens with penetrating flaw and also on specimens permeated with distilled water and CaCl2 solutions. The test results were presented and discussed. Experimental results showed that the GCL with penetrating flaw did not exhibit complete self-healing in the case of flaw. After 120 days, the hydraulic conductivity increased by approximately an order of magnitude. In addition, CaCl2 solutions had a significant influence on the hydraulic conductivity. The research findings might be of interest to researchers and engineers who design liners for landfills and other liquid containment facilities
This article presents test results for hydraulic conductivity and porosity structure of hardening slurries prepared of Portland cement, betonite, water and fluidal ashes from the combustion of hard and brown coal. The slurries were exposed to persistent filtering action (180 days) of liquids chemically aggressive to cement binders, i.e. distilled water, 0.5% solution of nitric acid, 1% solution of sodium sulphate, 1% solution of magnesium nitrate and 1% solution of ammonium nitrate. Samples exposed to filtration of tap water constituted the reference base. The research was into relations between hydraulic conductivity and pore structure parameters in slurries, as well as into the influence of the type of aggressive medium on leak tightness of slurries (their porosity and hydraulic conductivity).
This paper describes a new contactless conductivity detector, whose electrodes are constructed of microchannels filled with solution of KCl - called pseudoelectrodes. The lab-on-a-chip microdevice was fabricated in poly(dimethylsiloxane) PDMS, using a moulding technique. The mould was made from a dry negative photoresist with a thickness of 50 μm. During the tests, the dimension! and arrangement of pseudoelectrodes` microchannels were evaluated. The analyte was pumped into the microchannel using a syringe pump with a flow rate of 50 μL/min. Reproducible!changes of the signal were obtained.
The article presents the prototype of a measurement system with a hot probe, designed for testing thermal parameters of heat insulation materials. The idea is to determine parameters of thermal insulation materials using a hot probe with an auxiliary thermometer and a trained artificial neural network. The network is trained on data extracted from a nonstationary two-dimensional model of heat conduction inside a sample of material with the hot probe and the auxiliary thermometer. The significant heat capacity of the probe handle is taken into account in the model. The finite element method (FEM) is applied to solve the system of partial differential equations describing the model. An artificial neural network (ANN) is used to estimate coefficients of the inverse heat conduction problem for a solid. The network determines values of the effective thermal conductivity and effective thermal diffusivity on the basis of temperature responses of the hot probe and the auxiliary thermometer. All calculations, like FEM, training and testing processes, were conducted in the MATLAB environment. Experimental results are also presented. The proposed measurement system for parameter testing is suitable for temporary measurements in a building site or factory.
In this study, agar-based nanocomposite films containing ultra-porous silica aerogel particles were fabricated by gel casting using an aqueous agar/silica aerogel slurry. The silica aerogel particles did not show significant agglomeration and were homogeneously distributed in the agar matrix. Transmission electron microscopy observations demonstrated that the silica aerogel particles had a mesoporous microstructure and their pores were not incorporated into the agar polymer molecules. The thermal conductivities of the agar and agar/5 wt.% silica aerogel nanocomposite films were 0.36 and 0.20 W·m–1·K–1, respectively. The transmittance of the agar films did not decrease upon the addition of silica aerogel particles into them. This can be attributed to the anti-reflection effect of silica aerogel particles.
This article presents ways of possible utilization and application of fl uidal combustion wastes as active additives to hardening slurries which are used to seal environment protection structures, i.e. cut-off walls in waste dumps and wastewater treatment plants. Cut-off walls are often exposed to fi ltrating action of eluates - polluted (aggressive) waters. Results of hydraulic conductivity tests of slurries after their long-term (210 days) fi ltration with eluates from a municipal waste dump and with tap water are presented. Porosity tests were also conducted to show the porosity structure of the fi ltered slurries. Additionally, compressive strength of slurries maturing in tap water and waste dump eluates was tested in parallel.
In the present article, we introduced a new model of the equations of general ized thermoelasticity for unbounded orthotropic body containing a cylindrical cavity. We applied this model in the context of generalized thermoelasticity with phase-lags under the effect of rotation. In this case, the thermal conductivity of the material is considered to be variable. In addition, the cylinder surface is traction free and subjected to a uniform unit step temperature. Using the Laplace transform technique, the distributions of the temperature, displacement, radial stress and hoop stress are determined. A detailed analysis of the effects of rotation, phase-lags and the variability thermal conductivity parameters on the studied fields is discussed. Numerical results for the studied fields are illustrated graphically in the presence and absence of rotation.
The article presents a novel method that allows measurement of thermal conductivity that is based on Stefan-Boltzmann law. The developed method can be used to determine thermal conductivity of ceramic investment casting molds. The methodology for conducting thermal conductivity tests of ceramic material samples is presented. Knowledge of the value of thermal capacity and thermal conductivity as a function of temperature enables computer simulations of the process of cooling and solidification of liquid metal in a mold.
Until now, dust arising from lime manufacture has been considered harmless to the environment so it has been investigated marginally from the standpoint of environmental protection, especially when it came to magnetic properties and heavy metal content. The aim of the research was filling the gap in this area. The research comprised measurements of magnetic susceptibility, the content of heavy metals, reaction (pH) and specific conductivity of lime dust and also raw material and fuel used for lime production. The samples were taken from one of the lime plants located in Opole Province. Similar investigations were also performed for dust taken from the nearby cement plant using dry method of cement production. It was proven that magnetic susceptibility, heavy metal content and conductivity of lime dust was lower in comparison to cement dust, which resulted from the fact that the lime plant used neither low raw materials nor additives. Due to the high atmosphere dust level in the vicinity of the investigated plants, extremely basic reaction of the tested dust and high content of metals, the studied dust cause alkalization of soils and contribute to the increase of heavy metal content in soils, posing a threat to the environment.
Heat and mass transfer stretched flow of an incompressible, electrically conducting Jeffrey fluid has been studied numerically. Nanoparticles are suspended in the base fluid and it has many applications such as cooling of engines, thermal absorption systems, lubricants fuel cell, nanodrug delivery system and so on. Temperature dependent variable thermal conductivity with Rosseland approximation is taken into account and suction effect is employed in the boundary conditions. The governing partial differential equations are first transformed into set of ordinary differential equations using selected similarity transformations, which are then solved numerically using Runge-Kutta-Felhberg fourth-fifth order method along with shooting technique. The flow, heat and mass transfer characteristics with local Nusselt number for various physical parameters are presented graphically and a detailed discussion regarding the effect of flow parameters on velocity and temperature profiles are provided. It is found that, increase of variable thermal conductivity, radiation, Brownian motion and thermophoresis parameter increases the rate of heat transfer. Local Nusselt number has been computed for various parameters and it is observed that, in the presence of variable thermal conductivity and Rosseland approximation, heat transfer characteristics are higher as compared to the constant thermal conductivity and linear thermal radiation.
In this study, two different compositions of submicron-structured titanium (760 nm) and micron-structured chromium (4.66 μm) powders were mixed to fabricate Cr-31.2 mass% Ti alloys by vacuum hot-press sintering. The research imposed various hot-press sintering pressures (20, 35 and 50 MPa), while the sintering temperature maintained at 1250°C for 1 h. The experimental results showed that the optimum parameters of the hot-press sintered Cr-31.2 mass% Ti alloys were 1250°C at 50 MPa for 1 h. Also, the relative density reached 99.94%, the closed porosity decreased to 0.04% and the hardness and transverse rupture strength (TRS) values increased to 81.90 HRA and 448.53 MPa, respectively. Moreover, the electrical conductivity is enhanced to 1.58 × 104 S·cm–1. However, the grain growth generated during the high-temperature and high-pressure of the hot-press sintering process resulted in the grain coarsening phenomenon of the Cr-31.2 mass% Ti alloys after 1250°C hot-press sintering at 50 MPa for 1 h. In addition, the Cr-31.2 mass% Ti alloys were fabricated with the submicron-structured titanium (760 nm) and chromium (588 nm) powders showed more effective compaction than the micron-structured titanium (760 nm) and chromium (4.66 μm) powders did. The closed porosity decreases to 0.02% and the hardness values increase to 83.23 HRA. However, the agglomeration phenomenon of the Cr phase and brittleness of the TiCr2 Laves phases easily led to a slight decrease in TRS (400.54 MPa).
Free convection is one of the heat transfer modes which occurs within the heat-treated bundles of steel rectangular section. A comprehensive study of this phenomenon is necessary for optimizing the heating process of this type of charge. The free convection intensity is represented by the Rayleigh number Ra. The value of this criterion depends on the following parameters: the mean section temperature, temperature difference within the section, kinematic coefficient of viscosity, volume expansion coefficient and the Prandtl number. The paper presents the analysis of the impact of these factors on free convection in steel rectangular sections. The starting point for this analysis were the results of experimental examinations. It was found that the highest intensity of this process occurs for the temperature of 100°C. This is mainly caused by changes in the temperature difference observed in the area of sections and changes in kinematic coefficient of viscosity of air. The increase in the value of the Rayleigh number criterion at the initial stage is attributable to changes in the parameter of temperature difference within the section. After exceeding 100°C, the main effect on convection is from changes in air viscosity. Thus, with further increase in temperature, the Rayleigh number starts to decline rapidly despite further rise in the difference in temperature.