The paper reports the study of the complexation processes in aqueous solution of α-CD and DMSO. Cyclodextrins (CDs) (sometimes called cycloamyloses) are cyclic oligosaccharides formed by glucose units interconnected by α-(1,4) linkages; α-CD is one of three the most common CDs. It consists of six glucopyranose units. The speed of ultrasonic waves has been measured by the resonance method on ResoscanTM System apparatus. Some collateral data, such as density and heat capacity of the system, have also been measured. On the basis of the experimental data the excess adiabatic compressibility was determined. The extremes of the excess adiabatic compressibility function for different mixture compositions allowed us to establish the composition of molecular complexes formed in the solution. The obtained results suggest the formation of the α-CD with DMSO inclusion complexes with chemical stoichiometric ratio value of 1:1.
The objective of this work is to present an energy analysis of different absorption refrigerating systems operating with diverse refrigerants. Also is applied the method of experimental design to optimize configurations proposed by the absorption pairs used and the operating conditions. Both acceptable coefficient of performance and low operating generator temperature are scrutinised. Therefore, a computer program is developed. An investigation of the thermodynamic properties is presented. Results show the coefficient of performance evolution versus respectively the evaporator temperature, temperature of condensation and generator temperature. A particular interest is devoted to the intermediate pressure effect on the performance of different systems. In order to better converge in the selection of the configuration and the refrigerant, which can ensure a high coefficient of performance associated to relatively low operating generator temperature the plan of experiments has been developed, taking in account all parameters influencing the system performance and the function of operating temperature. Results show that the refrigerating machine containing a compressor between the evaporator and the absorber has a coefficient of performance quite acceptable and that it can work at low generator temperature for about 60 ◦C and using the NH3/LiNO3 as refrigerant.
The policy of sustainable development seeks to improve energy efficiency of industrial equipment. Efforts to improve energy efficiency also apply to the paint shops, where the recovery of waste heat is sought. The main source of a large amount of low-temperature waste heat in the paint shop is the spray booth. The second place where a large amount of low temperature waste heat is released is the room where the compressed air is prepared. Low energy efficiency of air compressors requires a large electric power supply. As a result, the emitted large heat fluxes become waste energy of the technological process. Heat is equivalent to up to 93% of the electric power supplied in the air compression process. There are solutions for recovering heat from compressors coming from the oil cooling water, but then the waste heat from the cooling of the compressed air and from the electric motor is released into air in the room. A method for recovering low-temperature waste heat from the air preparation room by means of an air-source heat pump has been proposed. An energy balance of the air compression and dehumidification process for the paint shop was made. A Matlab’s built-in numerical model includes air compressor and dehumidifier, heat recovery and accumulation for the purposes of use in the spray booth. A simulation experiment was carried out on the effectiveness of heat recovery from the air preparation room. The use of combined energy management in paint shops was proposed.
IIn this short communication, we revise a correlation for the saturated liquid isothermal compressibility based on the data available in DIPPR (Postnikov, 2016) which considers the molecular non-sphericity and addresses a problem of predicting speeds of sound in saturated long-chained alkanes. In addition, we correct a misprint appeared in the cited work and provide programming code used for the realisation of the proposed calculations.
Filtration process is one of the basic and essential processes in technological systems for treatment of municipal, community and industrial wastewater treatment. Filtration process is a subject of numerous published research and theoretical elaborations. This publication concerns theoretical analysis with basic character, and is a verification of theoretical analysis and physical equations describing process of filtration aided with empirical formulas.
This study investigates several factors that have not been specified in the standard for dynamic stiffness, compressibility, and long-term deformation; these factors can be used to evaluate the acoustic and physical performances of resilient materials. The study is intended to provide basic data for deriving the factors that need to be additionally reviewed through the standards. Since magnitude of dynamic stiffness changes with an increase in loading time, it is necessary to examine the setting of the loading time for a load plate under test conditions. Samples of size 300×300 mm, rather than 200×200 mm, yielded more reliable results for compressibility measurement. Since the test to infer long-term deformation of resilient materials after a period of 10 years in some samples showed variation characteristics different from those specified in the standards, it is recommended that the test method should be reviewed through ongoing research.
Multilayered composites based on light metals are promising materials in many applications. In the present work the 15-layered clad, composed of alternately stacked of Ti(Gr.1) and AA1050-H24 alloy sheets of 1 mm thick has been investigated with respect to determination of the kinetic of the Al3Ti phase growth. The defect-free multilayered composite was successfully formed by explosive welding technology. Then EXW samples were modified via annealing at the temperature of 600oC in closed die under pressure of 44 MPa for various times ranged between 1 and 10 h. Transmission and Scanning Electron Microscopy examinations were conducted in order to study the kinetic of the elements migration across the interfaces between the layers of the Al/Ti composite. The macro-scale observations of samples after EXW revealed that wavy interfaces were always formed in layers near the explosive charge. The increase of the distance from the top surface leads to flattening of the interface with very thin reaction layer between Al and Ti sheets. During annealing the kinetic of the Al3Ti phase growth is similar near all interfaces and coincides with data from other works. It was found that despite the loading after 10 h of annealing still only small part of Al-sheets undergoes dissolution and the width of the reaction layer does not exceed 5-8 µm.
The properties, superior calorific value (SCV) and the compressibility factor (z), of 77 natural gas (NG) samples are calculated from two different calibration approaches of gas chromatography, based on ISO 6974-2. The method A uses an analytical curve with seven points that the best adjust is confirmed by Analysis of Variance (ANOVA); it is required when the composition of the natural gas varies. The method B uses a single point calibration, with an allowed tolerance between the calibration gas mixture and sample mole fraction, so it is used to analyze constant natural gas streams. From natural gas composition analyzed by both methods, exceeding the method B allowed tolerance; SCV, z and its uncertainties are calculated and compared. The results show that all samples that comply with Brazilian legislation can be analyzed by method B, because there are no metrological differences in terms of SCV and z, even though the allowed tolerance has been exceeded. This simplified methodology minimizes operator exposure, besides saving about US$ 50,000.00 per chromatograph.
An uniaxial compression mechanical model for the roof rock-coal (RRC) composite sample was established in order to study the effects of height ratio of roof rock to coal on the structural strength of composite sample. The composite sample strengths under different height ratios were established through stress and strain analysis of the sample extracted from the interface. The coal strength near the interface is enhanced and rock strength near the interface weakened. The structural strength of composite sample is synthetically determined by the strengths of rock and coal near and far away from the interface. The area with a low strength in composite sample is destroyed firstly. An analytical model was proposed and discussed by conducting uniaxial compression tests for sandstone-coal composite samples with different height ratios, and it was found that the structural strength and elastic modulus decrease with a decrease in height ratio. The coal strengths far away from the interface determine the structural strengths of composite sample under different height ratios, which are the main control factor for the structural strength in this test. Due to its lowest strength, the rock near the interface first experienced a tensile spalling failure at the height ratio of 9:1, without causing the structural failure of composite sample. The coal failure induces the final failure of composite sample.