Petrographic and physico-chemical analyses of ashes are carried out on a large scale and presented in numerous scientific papers. The mentioned ashes are obtained from filters and electrostatic precipitators mounted in large industrial installations. The large-scale analysis of the ashes obtained directly from grate furnaces or blast furnaces mounted in low-power boilers started with combating smog and low-stack emissions. The collection of ash samples from household furnaces usually involves the analysis of the combustion of waste in low-power boilers. This is justified in the case of old type boilers, which were designed to use virtually any fuel. Currently, new types of boilers, designed to burn dedicated fuels, are offered on the market. The aim is to use only renewable fuels (biomass) or fossil fuels with high quality parameters, which are more environment-friendly, e.g. eco-pea coal, lignite briquettes, or peat briquettes. The authors of the study focused on examining the ash obtained from boilers for burning wood pellets by performing microscopic analysis of residues after biomass combustion. The above mentioned analysis provides a comprehensive information on the efficiency of the combustion process, the content of contaminants remaining in the ash, and the suitability of ash for other applications. The entire process, from the moment of collecting the samples to the execution of the analysis takes up to 12 hours, which ensures a quick decision on furnace adjustment or fuel change. The ash components were determined based on the results obtained by the Fly-Ash Working Group of the International Committee for Coal and Organic Petrology (ICCP). The mentioned classification has been supplemented with new key elements occurring in ashes resulting from the combustion of wood pellets in household boilers. This allowed determining the percentage content of characteristic components in the tested material, which can be used as a specific benchmark when issuing opinions on the quality and efficiency of the boiler and the combusted pellets.
Wood pellets are classified as a solid biomass type. They are one of the most popular bio-heating fuels used in Europe, especially in the small heating sector, where pellets are burned in low-power domestic boilers. The pellets and automatic pellet-fired heating devices gained popularity due to the increasing air pollution (smog) problem and the low emission limiting campaigns associated with it. Wood pellets are formed as a result of small forestry particles mechanical compression (mainly conifers originated) and they are listed among renewable energy sources. The purpose of the presented studies was to compare the quality of wood pellets used for pellet-fired boilers and to identify, qualitatively and quantitatively, impurities marked in the samples obtained from the domestic market. The application of petrographic analyses, applied so far in relation to fossil fuels, is a presented work innovation for wood pellets. The microscopic analyses were performed on both certified (ENplus/DINplus) and uncertified wood pellets available on the market. Unfortunately, the analysis revealed that the quality requirements were not met, because of the unacceptable contamination presence. The unacceptable organic inclusions in the analyzed samples are fossil coals and their derivatives, coke, and polymeric materials of natural origin. Unacceptable inorganic inclusions determined in the analyzed samples were: glass, slag, rust, pieces of metal, stone powder, plastic, and polymeric materials of inorganic origin.
The article presents the results of tests of the application of magnetic fuel activators, which improve the efficiency of metallurgical furnaces and positively affect the ecological aspects of their work. Energy indicators for metallurgical furnaces during operation before and after installation of magnetic fuel activators as well as the results of composition and concentration of emitted pollutants are included in the paper. The magnetic activation of liquid and gaseous fuels modifies their structure. As a result of the activation, the fuel mixture is selectively saturated with oxygen in the zone of free fuel flow. The combustion conditions were close to optimal, which is confirmed by the reduction of pollutants in the exhaust gases. Fuel saving in the combustion process is also a measurable economic effect. The tests included ovens of several types: pusher furnace, one and two chamber furnaces and a furnace with a rotary shaft. Several-month measurement cycles were carried out on each of them. The experiments consisted in the analysis of gas and heat consumption per month in individual furnaces before and after the use of magnetic fuel activators. The effectiveness of using activators was determined on the basis of the results of the tests carried out. As a result of a twelve-month test cycle on the pusher type furnace, a 36% reduction in gas consumption and a 22% reduction in heat consumption were achieved. After a seventeen-month measurement cycle on chamber furnaces, a 35% reduction in gas consumption and 6% in heat consumption were achieved. The tests on furnaces with a rotary shaft lasted fourteen months and showed a reduction in gas consumption by 8%. An improvement in the composition of fumes in the furnace atmosphere was achieved in all units with magnetic activators installed, as well as a reduction in the emission of harmful pollutants into the atmosphere from the installation.
This paper describes experiments on the application of sodium bicarbonate desulphurisation in the coal-fuel boiler. The boiler has been in operation for several years now and it has refiably fulfilled the original assignment to reduce SO2 emissions from the value of 1200 - 1500 mg/Nm3 to 400 mg/Nm3. Higher desulphurisation efficiency is determined only by the ratio of Na/S sorbent dosage. The resulting product of desulphurisation is stored together with fly ash in underground mines, and has no influence on the groundwater. Positive experience of the tests and boiler operation lies in higher reactivity of sodium and sulphur as compared with conventional methods based on limestone. Within the scope of the secondary measures of elimination of sulphur oxides in combustion products, an experimental dry-method desulphurisation of combustion products was performed by blasting an agent containing sodium bicarbonate NaHCO3 (99.6 %) into the flue ways before the electrostatic precipitator in a coal-fuel furnace with the steam output of 220 t/h.
The paper presents the possible applications of using acoustic diagnostics in inspecting the technical condition of an internal combustion engine with autoignition on the example of the Fiat drive unit with common rail system. As a result of measuring the sound pressure level for specific faults and comparing the noise generated by the motor running smoothly, the detailed maps of changes in the acoustic spectrum are possible to generate. These results may be helpful in the future diagnostics of internal combustion engines. In the paper, the results of scientific work in the area of research, design and operation of internal combustion engines, conducted at the Department of Automotive Engineering, in cooperation with the Laboratory of Hydraulic Drives & Vibroacoustics of Machines at the Wroclaw University of Technology are included.
Natural gas combustion was carried out in air enriched with oxygen in the amount of 25 and 29% with addition of CO2 in place of part of nitrogen. The research was carried out at different flow rates of gas and oxygen excess ratios. The concentration of CO and NOx was analyzed. It has not been proved that the increased oxygen concentration influences significantly the CO concentration. However, the addition of CO2 caused a substantial variability of CO concentration in the exhaust gas, in contrast to the concentration of NOx which decreased monotonically. Model calculations, performed with use of FactSage, indicate an increase in the concentration of CO not only for the air enriched with oxygen, but after adding CO2 too, as well
The primary methods of reducing nitrogen oxides, despite the development of more advanced technologies, will continue to be the basis for NOx reduction. This paper presents the results of multivariate numerical studies on the impact of air staging on the flue gas temperature and composition, as well as on NOx emissions in a OP 230 boiler furnace. A numerical model of the furnace and the platen superheater was validated based on measurements using a 0-dimensional model of the boiler. Numerical simulations were performed using the ANSYS Workbench package. It is shown that changes in the distribution of air to OFA nozzles, the angle of the air outflow from the nozzles and the nozzle location involve a change in the flue gas temperature and in the volume of NOx and CO emissions at the furnace outlet.
CO, NO, NO2 and dust concentrations from combustion of deciduous wood (birch, beech, lime-tree) logs and pellets in two heating boilers (15 and 25 KW), situated in a heat station were investigated. Time dependences of pollutant concentrations as well as the impact of temperature in the combustion chamber and oxygen concentration on pollutant concentrations were presented. Pollutant emission indices have been estimated.
In this paper some issues of the transition process from air- to oxy-combustion were investigated. Advantages of flexible combustion were described. Flexible combustion tests carried out at four European plants and five plants outside Europe of different scales of process and test parameters were presented. An analysis of the transition time from air to oxy-combustion of different laboratory and pilot scale processes was carried out. The “first-order + dead time” approach was used as a model to describe transition process. Transitional periods between combustion modes and characteristic parameters of the process were determined. The transition time depends not only on the facility’s capacity but also it is impacted by specific operational parameters.
The aim of the paper is a comparative study of co-firing high shares of wooden and agro-biomass with hard coal under oxy-fuel and air conditions in the laboratory scale reactor for pulverised fuels. The investigations of co-combustion behaviour NOx and SO2 emission and burnout were carried out for selected blends. Detailed investigations were concentrated on determining the effect of dosing oxygen method into the burner on NOx emission. The paper presents the results of co-firing blends with 20 and 50% share of biomass by mass in air and oxy-combustion condition. Biomass oxy-cofiring integrated with CCS (CO2 capture) technology could be a carbon negative technology. The reduction of NOx emissions in the conditions of oxy-co-firing is dependent on the concentration of oxygen in the primary stream of oxidiser. A significant reduction of NOx was achieved in the case of low oxygen concentration in the primary stream for each investigated blends. Co-firing of biomass with coal in an oxygen enriched atmosphere enhances combustion behaviour, lowers fuel burnout and as a result increases of the boiler efficiency.
Generally, the temperature of flue gases at the furnace outlet is not measured. Therefore, a special computation procedure is needed to determine it. This paper presents a method for coordination of the numerical model of a pulverised fuel boiler furnace chamber with the measuring data in a situation when CFD calculations are made in regard to the furnace only. This paper recommends the use of the classical 0-dimensional balance model of a boiler, based on the use of measuring data. The average temperature of flue gases at the furnace outlet tk" obtained using the model may be considered as highly reliable. The numerical model has to show the same value of tk" . This paper presents calculations for WR-40 boiler. The CFD model was matched to the 0-dimensional tk" value by means of a selection of the furnace wall emissivity. As a result of CFD modelling, the flue gas temperature and the concentration of CO, CO2, O2 and NOx were obtained at the furnace chamber outlet. The results of numerical modelling of boiler combustion based on volumetric reactions and using the Finite-Rate/Eddy-Dissipation Model are presented.
The paper presents the results of the mechanical, electrical, CCSEM and XRD measurements of hard coal, conducted in simulated conditions of sintering in atmospheres of O2/CO2,. The changes of the coal ash resistivity are correlated with the content of the oxides and with the sintering temperature determined by the mechanical test and Leitz method. The SEM-EDS analysis was conducted for deposits on the probe. The changes of the measured ash samples, observed during sintering process in O2/CO2 atmosphere, were discussed in the ash microstructure point of view.
In this work problems associated with requirements related to pollution emissions in compliance with more restrictive standards, low-emission combustion technology, technical realization of the monitoring system as well as algorithms allowing combustion process diagnostics are discussed. Results of semi-industrial laboratory facility and industrial (power station) research are presented as well as the possibility of application of information obtained from the optical fibre monitoring system for combustion process control. Moreover, directions of further research aimed to limit combustion process environmental negative effects are presented.
Due to the fact that the landfill deposition of municipal waste with the higher heating value (HHV) than 6 MJ/kg in Poland is prohibited, the application of waste derived fuels for energy production seems to be good option. There is a new combined-heat-and-power (CHP) plant in Zabrze, where varied solid fuels can be combusted. The formation of ashes originating from the combustion of alternative fuels causes a need to find ways for their practical application and demands the knowledge about their properties. Therefore, the present work is devoted to studying the co-combustion of solid recovered fuel (SRF) and coal, its impact on fly ash quality and the potential application of ashes to synthesis zeolites. The major objectives of this paper is to present the detail characteristics of ash generated during this process by using the advanced instrumental techniques (XRF, XRD, SEM, B ET, TGA). The co-combustion were carried out at 0.1 MWth fluidized bed combustor. The amount of SRF in fuel mixture was 1, 5, 10 and 20%, respectively. The focus is on the comparison the ashes depending on the fuel mixture composition. Generally, the ashes characterise high amounts of SiO2, Al2O3 and Fe2O3. It is well observed, that the chemical composition of ashes from co-combustion of blends reflects the amount of SRF addition. Considering the chemical composition of studied ashes, they can be utilize as a zeolites A. The main conclusions is that SRF can be successfully combusted with coal in CFB technology and the fly ashes obtained from coal + SRF fuel mixtures can be used to synthesis zeolites.
Results of the study examining carbon monoxide and nitric oxide concentrations while burning different types of agricultural biomass: coffee husk pellets alone or in combination with wheat straw pellets and cherry stones, sewage sludge pellets, corn stover briquettes and a mixture of rye straw briquettes and miscanthus briquettes were presented. The combustion was performed in a 50 kW boiler type Biowarmer with a cast-iron moving step grate. The temperature in the combustion chamber did not exceed 800 ◦C. For all biomass types, only brittle slag was generated in the furnace, which was easily broken by a reciprocating movement of the grate. Carbon monoxide concentration in the flue gas except for the case of sewage sludge pellet firing did not exceed the permitted value of 3000 mg/m3 and nitric oxide concentration 515 mg/m3, both presented for 10% O2 concentration in the flue gas based in dry gas. Hydrocarbon concentrations for all test runs were close to zero.
Tests for combustion of hay and sunflower husk pellets mixed with wood pellets were performed in a horizontal-feed as well as under-feed (retort) wood pellet furnace installed in boilers with a nominal heat output of 15 and 20 kW, located in a heat station. During the combustion a slagging phenomenon was observed in the furnaces. In order to lower the temperature in the furnace, fuel feeding rate was reduced with unaltered air stream rate. The higher the proportion of wood pellets in the mixture the lower carbon monoxide concentration. The following results of carbon monoxide concentration (in mg/m3 presented for 10% O2 content in flue gas) for different furnaces and fuel mixtures (proportion in wt%) were obtained: horizontal-feed furnace supplied with hay/wood: 0/100 - 326; 30/70 - 157; 50/50 - 301; 100/0 - 3300; horizontal-feed furnace supplied with sunflower husk/wood: 50/50 - 1062; 67/33 - 1721; 100/0 - 3775; under-feed (retort) furnace supplied with hay/wood: 0/100 - 90; 15/85 - 157; 30/70 - 135; 50/50 - 5179; under-feed furnace supplied with sunflower husk/wood: 67/33 - 2498; 100/0 - 3128. Boiler heat output and heat efficiency was low: 7 to 13 kW and about 55%, respectively, for the boiler with horizontal-feed furnace and 9 to 14 kW and 64%, respectively, for the boiler with under-feed furnace.
This paper presents possibilities for of numerical modelling of biomass combustion in a commercially available boiler. A sample of biomass was tested with respect to its physical and chemical properties. Thermogravimetry studies of biomass were carried out. Computer simulation makes it possible to analyse complex phenomena which are otherwise difficult to observe. The aim of this work was to model biomass combustion to predict the amount of pollutants generated (NOx, CO, SO2) in the exhaust gases coming out from boilers The calculations were made using the CHEMKIN program. Results of calculations were performed taking into account the influence of temperature, pressure and residence time.
Whereas the use of biofuels has attracted increasing attention, the aim of this paper is to investigate the possibility of using sewage sludge as biofuel. Preparation of untreated and stabilised sludge with natural additives is described, as well as combusting method applied and experimental results of combusting are presented based on the assessment of composition of emitted pollutants and their concentrations in the exhaust gas. NOx formation in the exhaust gas has been analysed in depth. The results of investigations have shown that the use of dried sewage sludge possesses a positive energy balance. Therefore, the sludge may be used as fuel. The obtained experimental results demonstrate that during combustion, pollutant concentrations vary depending on oxygen content (O2), while formation of nitrogen oxides is strongly influenced by fuel-bound nitrogen. Also, a generalized equation of calculating fuel bound nitrogen conversion into NOx is presented.
The article is focused onthe energetical balance of a technical system for the conversion of crushed tyres by pyrolysis. Process temperatures were set in the range from 500 to 650°C. Mass input of the material was 30 kg per hour. The aim of the article is to answer the following questions as regards the individual products: Under which process conditions can the highest quality of the individual products related to energy be reached? How does the thermal efficiency of the system change in reaction to various conditions of the process? On the basis of the experimental measurements and calculations, apart from other things, it was discovered that the pyrolysis liquid reaches the highest energetic value, i.e. 42.7 MJ.kg-1, out of all the individual products of the pyrolysis process. Generated pyrolysis gas disposes of the highest lower calorific value 37.1 MJ.kg-1 and the pyrolysis coke disposes of the maximum 30.9 MJ kg-1. From the energetic balance, the thermal efficiency of the experimental unit under the stated operational modes ranging from about 52 % to 56 % has been estimated. Individual findings are elaborated on detail in the article.
The impact of the fuel feeding mode (continuous or periodic with different stand-by/operation time ratios) on carbon monoxide (CO) and nitrogen oxides (NO, NOx) concentration values in the flue gas was analysed for coniferous wood pellet firing. Experiments were performed in a 25 kW water boiler equipped with an over-fed wood pellet furnace located in a full scale heat station simulating real-life conditions. Influence of oxygen concentration and temperature in the combustion chamber on carbon monoxide and nitrogen oxide concentrations was presented in diagrams. Dust and hydrocarbon concentrations were also monitored. It was concluded that the commonly used periodic fuel supply does not necessarily cause a significant increase of carbon monoxide concentration, as compared to the continuous fuel feeding mode. Continuous fuel supply can even induce higher carbon monoxide concentrations when fuel mass stream is not chosen properly. Each time new fuel type is used in a specific furnace, one should perform experiments to determine the adequate settings (stand-by/operation time ratio, fuel mass streams, air stream) to obtain the optimal, lowest possible emission for a certain boiler heat output
The paper presents results of coal behaviour during combustion in oxy-fuel atmosphere. The experiment was performed using 3 meter long Entrained Flow Reactor and 1 meter long Drop Tube Reactor. Three hard coals and two lignites were analysed in order to investigate NOx, SO2 emission and fly ash burnout. The measurements were performed along and at the outlet of a combustion chamber for one- and two - stage combustion. In the second stage of the experiment, kinetic parameters for nitrogen evolution during combustion in oxy - fuel and air were calculated and the division of nitrogen into the volatile matter and the char was measured. The conducted experiment showed that emissions in oxy - fuel are lower than those in air.
The work contains a description of a developed experimental and theoretical method of modeling of solid waste combustion in a device equipped with a moving grate and capability to optimize the work of waste incineration plant. Implementation of this issue was based on results of experimental studies made on a laboratory scale boiler. This was possible by defining and testing indicators of quantitative assessment of combustion such as: reaction front rate, ignition rate, the rate of combusted mass loss and the heat release rate. These indicators as measurable "criteria indicators" allow transfer of parameters from a laboratory-scale unit, working in the transient regime into an industrial full scale grate device working continuously in stable determined conditions. This allows for wide optimization possibilities in the operation of a waste incineration plant, in particular the combustion chamber, equipped with a moving grate system.
The present work focuses on analyses of the autoignition delay time predicted by the large eddy simulation (LES) method by applying different subgrid scales (SGS) models and two different discretization schemes. The analysed flow configuration is a two-phase chemically reacting turbulent flow with monodispersed evaporating fuel droplets. The impact of numerical procedure is investigated in a 3D flow domain with a temporally evolving mixing layer that constituted between the streams of fuel and oxidizer that moved in opposite directions. The upper stream of cold gas carries a dispersed fuel spray (ethanol at 300 K). The lower stream is a hot air at 1000 K. Three commonly used in LES, SGS models are investigated, namely: classical Smagorinsky model, model proposed by Vreman and the #27;-model proposed by Nicoud. Additionally, the impact of two discretization schemes, i.e., total variation diminishing (TVD) and weighted essentially nonoscillatory (WENO) is analysed. The analysis shows that SGS model and discretization scheme can play a crucial role in the predictions of the autoignition time. It is observed that for TVD scheme the impact of SGS model is rather small. On the contrary, when the WENO scheme is applied the results are much more dependent on the SGS model.