The scope of this work is to investigate the precipitation of two Al-Mg-Si alloys with and without Cu and excess Si by using the differential scanning calorimetry (DSC), transmission electron microscopic (TEM), Vickers hardness measurement and X-ray diffraction. The analysis of the DSC curves found that the excess Si accelerate the precipitation and the alloy contain the excess Si and small addition of copper has higher aging-hardness than that of free alloy (without excess Si and Cu) at the same heat treatment condition. The sufficient holding time for the precipitation of the β'' phase was estimated to be 6 hours for the alloy aged at 100°C and 10 hours for the alloy aged at 180°C. The low Copper containing Al-Mg-Si alloy gives rise to the forming a finer distribution of β (Mg2Si) precipitates which increases the hardness of the alloy. In order to know more about the precipitation reactions, concern the peaks on the DSC curve transmission electron microscopy observation were made on samples annealed at temperatures (250°C, 290°C and 400°C) just above the corresponding peaks of the three phases β'', β' and β respectively.
Cast magnesium matrix composites reinforced with silicon carbide particles were investigated by using Raman microscopy. 3C, 4H and 6H polytypes of SiC particles were identified in the investigated composites. Additionally, Mg2Si compound was detected by Raman microscopy in the composites microstructure.
The effect of combination grain refinement with AlTi5B1 master (55 ppm) and Sr-modification with AlSr5 master (20, 30, 40, 50 and 60 ppm) on the microstructure, tensile and hardness properties of AlSi7MgTi cast alloy were systematically investigated. Eutectic silicon was studied by optical and scanning electron microscopy after standard (0.5% HF) and deep etching (HCl). Morphology of eutectic Si changes from compact plate-like (as-cast state) to fibbers (after modification). Si-fibbers in samples with 50 and 60 ppm Sr coarsen probably as a result of over-modification. The optimum mechanical properties has the experimental material which was grain refined and modified with 40 ppm of Sr (UTS = 220.6 MPa; ductility = 6.1%, and 82.3 HBW 5/250/15).
Secondary or multiple remelted alloys are common materials used in foundries. For secondary (recycled) Al-Si-Cu alloys, the major problem is the increased iron presence. Iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which may negatively affect the structure. The paper deals with effect of multiple remelting on the microstructure of the AlS9iCu3 alloy with increased iron content to about 1.4 wt. %. The evaluation of the microstructure is focused on the morphology of iron-base intermetallic phases in caste state, after the heat treatment (T5) and after natural aging. The occurrence of the sludge phases was also observed. From the obtained results can be concluded that the multiple remelting leads to change of chemical composition, changes in the final microstructure and also increases sludge phases formation. The use of heat treatment T5 led to a positive change of microstructure, while the effect of natural aging is beneficial only to the 3rd remelting.
In this work, the effect of the microstructure on corrosion behavior of selected Mg- and Al-based as cast alloys, was evaluated. The electrochemical examinations were carried out, and then a morphology of corrosion products formed due to local polarization on materials surface, was analyzed. It was documented that the presence of Mg2Si phase plays an important role in the corrosion course of Mg-based alloy. A selective etching was observed in sites of Mg2Si precipitates having “Chinese script”- like morphology. Analogous situation was found for Al-based alloy, where the key role was played by cathodic θ-CuAl2 phase.
Iron is presented as an impurity in Al-Si alloys and occurs in the form of the β-Al5FeSi phase formations. The presence of iron and other elements in the alloy causes the formation of large intermetallic phases. Due to the high brittleness of this phase, it reduces the mechanical properties and increases the porosity. Manganese is used to inhibit the formation of this detrimental phase. It changes the morphology of the phase to polyhedral crystals, skeletal formations, or Chinese script. The present article deals with the influence of various amounts of manganese (0.1; 0.2; 0.4; 0.6 wt. %) on the formation of iron-based intermetallic phases in the AlSi7Mg0.3 alloy with different levels of iron content (0.4; 0.8, 1.2 wt. %). The increase of iron content in each alloy caused the creation of more intermetallic compounds and this effect has been more significant with higher concentrations of manganese. In alloys where the amount of 1.2 wt. % iron is present, the shape of eutectic silicon grain changes from angular to short needle type.
The paper deals with the influence of manganese in AlSi7Mg0.3 alloy with higher iron content. Main aim is to eliminate harmful effect of intermetallic – iron based phases. Manganese in an alloy having an iron content of about 0.7 wt. % was graded at levels from 0.3 to 1.4 wt. %. In the paper, the effect of manganese is evaluated with respect to the resulting mechanical properties, also after the heat treatment (T6). Morphology of the excluded intermetallic phases and the character of the crystallisation of the alloy was also evaluated. From the obtained results it can be concluded that the increasing level of manganese in the alloy leads to an increase in the temperature of the β-Al5FeSi phase formation and therefore its elimination. Reducing the amount of β-Al5FeSi phase in the structure results in an improvement of the mechanical properties (observed at levels of 0.3 to 0.8 wt. % Mn). The highest addition of Mn (1.4 wt.%) leads to a decrease in the temperature corresponding to the formation of eutectic silicon, which has a positive influence on the structure, but at the same time the negative sludge particles were also present
Manganese is an effective element used for the modification of needle intermetallic phases in Al-Si alloy. These particles seriously degrade mechanical characteristics of the alloy and promote the formation of porosity. By adding manganese the particles are being excluded in more compact shape of “Chinese script” or skeletal form, which are less initiative to cracks as Al5FeSi phase. In the present article, AlSi7Mg0.3 aluminium foundry alloy with several manganese content were studied. The alloy was controlled pollution for achieve higher iron content (about 0.7 wt. % Fe). The manganese were added in amount of 0.2 wt. %, 0.6 wt. %, 1.0 wt. % and 1.4 wt. %. The influence of the alloying element on the process of crystallization of intermetallic phases were compared to microstructural observations. The results indicate that increasing manganese content (> 0.2 wt. % Mn) lead to increase the temperature of solidification iron rich phase (TAl5FeSi) and reduction this particles. The temperature of nucleation Al-Si eutectic increase with higher manganese content also. At adding 1.4 wt. % Mn grain refinement and skeleton particles were observed.
The paper deals with squeeze casting technology. For this research a direct squeeze casting method has been chosen. The influence of process parameters variation (casting temperature, mold temperature, pressure) on mechanical properties and structure will be observed. The thicknesses of the individual walls were selected based on the use of preferred numbers and series of preferred numbers (STN ISO 17) with the sequence of 3.15, 4.00, 5.00, 6.00 and 8.00 mm. The width of each wall was 22 mm with a length of 100 mm. As an experimental material was chosen the AlSi12 and AlSi7Mg0.3 alloys. The mechanical properties (UTS, E) for individual casting parameters and their individual areas of different thicknesses were evaluated. In the structure the influence of pressure on the change of the eutectic morphology, the change of the volume of eutectic and the primary alpha phase, the effect of the pressure on the more fine-grain and the regularization of the structure were evaluated.
The article presents results of pitting corrosion studies of selected silicon cast irons. The range of studies included low, medium and high silicon cast iron. The amount of alloying addition (Si) in examined cast irons was between 5 to 25 %. Experimental melts of silicon cast irons [1-3] were conducted in Department of Foundry of Silesian University of Technology in Gliwice and pitting corrosion resistance tests were performed in Faculty of Biomedical Engineering in Department of Biomaterials and Medical Devices Engineering of Silesian University of Technology in Zabrze. In tests of corrosion resistance the potentiostat VoltaLab PGP201 was used. Results obtained in those research complement the knowledge about the corrosion resistance of iron alloys with carbon containing Si alloying addition above 17 % [4-6]. Obtained results were supplemented with metallographic examinations using scanning electron microscopy. The analysis of chemical composition for cast irons using Leco spectrometer was done and the content of alloying element (silicon) was also determined using the gravimetric method in the laboratory of the Institute of Welding in Gliwice. The compounds of microstructure were identify by X-ray diffraction.
The article presents crystallization process of silicon molybdenum ductile cast iron (SiMo). The alloy with 5% silicon content and with variable amounts of Mo in a range of 0-1% was chosen for the research. The carbon content in the analysed alloys did not exceed 3,1%. The studies of crystallization process were based on thermal – derivative analysis (TDA). Chemical composition of all examined samples was analysed with the use of LECO spectrometer. Additionally, the carbon and the sulphur content was determined basing on carbon and sulphur LECO analyser. For metallographic examination, the scanning electron microscopy (SEM) with EDS analyser was used. Disclosed phases have been also tested with the use of X-ray diffraction. The results allowed the description of crystallization processes of silicon molybdenum ductile cast iron using thermal – derivative analysis (TDA). Conducted studies did not allow for the clear identification of all complex phases containing molybdenum, occurring at the grain boundaries. Therefore, the further stages of the research could include the use of a transmission electron microscope to specify the description of complex compounds present in the alloy.
The paper presents an analysis of the effect of shape of primary silicon crystals on the sizes of stresses and deformations in a surface layer of A390.0 alloy by Finite Elements Method (FEM). Analysis of stereological characteristics of the studied alloy, performed based on a quantitative metallographic analysis in combination with a statistical analysis, was used for this purpose. The presented simulation tests showed not only the deposition depth of maximum stresses and strains, but also allowed for determining the aforementioned values depending on the shape of the silicon crystals. The studied material is intended for pistons of internal combustion engines, therefore the analysis of the surface layer corresponded to conditions during friction in a piston-cylinder system of an internal combustion engine having power of up to 100 kW. The obtained results showed important differences in the values of stresses and strains up to 15% between various shape of the silicon crystals. Crystals with sharp edges caused higher stresses and deformation locally than those with rounded shapes.
The purpose of this study is to identify relationships between the values of the fluidity obtained by computer simulation and by an experimental test in the horizontal three-channel mould designed in accordance with the Measurement Systems Analysis. Al-Si alloy was a model material. The factors affecting the fluidity varied in following ranges: Si content 5 wt.% – 12 wt.%, Fe content 0.15 wt.% – 0.3wt. %, the pouring temperature 605°C-830°C, and the pouring speed 100 g · s–1 – 400 g · s–1. The software NovaFlow&Solid was used for simulations. The statistically significant difference between the value of fluidity calculated by the equation and obtained by experiment was not found. This design simplifies the calculation of the capability of the measurement process of the fluidity with full replacement of experiments by calculation, using regression equation.
Paper describes the results of Fe80Si11B9 amorphous ribbon investigation after pulsed laser interference heating and conventional annealing. As a result of interference heating periodically placed laser heated microareas were obtained. Structure characterisation by scanning and transmission electron microscopy showed in case of laser heated samples presence of crystalline nanostructure in amorphous matrix. Microscopy observations showed significant difference in material structure after laser heating – nanograin structure, and material after annealing – dendritic structure. Magnetic force microscopy investigation showed expanded magnetic structure in laser heated microareas, while amorphous matrix did not give magnetic signal. Change of magnetic properties was examined by magnetic hysteresis loop measurement, which showed that the laser heating did not have a significant influence on soft magnetic properties.
The paper presents the influence of modification with phosphorus (CuP10) on the tribological properties of the alloy AlSi17Cu5Mg coupled abrasively with cast-iron EN GJL-350. Tests of coefficient of friction and wear of mass were conducted on tribological tester T-01. An important aspect in the assessment of the tribological properties is the analysis of initial material microstructure in reference to silumin which underwent modification with phosphorus. It was found that the difference in structure of tested materials, mainly sizes of primary silicon crystals significantly influences the tribological properties whereas the speed change of the friction knot does not have such big influence.
The chosen, typical causes of quality defects of cast-iron „alphin” rings embedded in aluminum cast are being presented in this paper. Diffusive joint of those inserts with the pistons casts is being used, due to extreme work conditions of destructive influence of the fuel mix and variable thermo-mechanical loads, which reign in the combustion motor working chamber.
In the dissertation it has been shown, that so called “time-thermal treatment” (TTT) of the alloy in liquid state as overheating the metal with around 250o C above Tliq. and detailing it in temperature for 30 to 40 minutes has the influence on changing the crystallization parameters (Tliq., TEmin. , TEmax., TE(Me), TSol.). It was ascertained, that overheating the AlSi17Cu5Mg alloy substantially above Tliq. results with microcrystalline structure. Evenly distributed in the eutectic warp primeval silicon crystals and supersaturated with alloying additives of base content (Cu, Mg, Fe) of α(Al) solution, ensures not only increase durability in ambient temperature, but also at elevated temperature (250o C), what due to it’s use in car industry is an advantage.
Paper present a thermal analysis of laser heating and remelting of EN AC-48000 (EN AC-AlSi12CuNiMg) cast alloy used mainly for casting pistons of internal combustion engines. Laser optics were arranged such that the impingement spot size on the material was a circular with beam radius rb changes from 7 to 1500 m. The laser surface remelting was performed under argon flow. The resulting temperature distribution, cooling rate distribution, temperature gradients and the depth of remelting are related to the laser power density and scanning velocity. The formation of microstructure during solidification after laser surface remelting of tested alloy was explained. Laser treatment of alloy tests were perform by changing the three parameters: the power of the laser beam, radius and crystallization rate. The laser surface remelting needs the selection such selection of the parameters, which leads to a significant disintegration of the structure. This method is able to increase surface hardness, for example in layered castings used for pistons in automotive engines.
This paper considers the assessment of attenuation in aluminium alloys castings and in cast iron prepared by gravity casting method and by casting under pressure. The issue of ultrasound attenuation is important in setting the conditions of non-destructive (NDT) testing, especially in casted materials. The characteristics of the ultrasonic technique and ultrasonic attenuation and the calculation of the attenuation and the velocity of ultrasound are presented in the theoretical part of this paper. For experimental measurements, cylindrical castings from AlSi alloy (a hypoeutectic alloy with a silicon content of about 7% - AlSi7 and a eutectic alloy with a silicon content of about 12% - AlSi12) and from grey and ductile cast iron were made. The ultrasonic records of the casting control, the calculation of ultrasound attenuation for individual samples are listed and described in the experimental part. The evaluation of measurements and comparison of calculated ultrasound attenuation is at the end of this article.
Detailed studies on the effects of pulsed laser interference heating on surface characteristics and subsurface microstructure of amorphous Fe80Si11B9 alloy are reported. Laser interference heating, with relatively low pulsed laser energy (90 and 120 mJ), but with a variable number (from 50-500) of consecutive laser pulses permitted to get energy accumulation in heated areas. Such treatment allowed to form two- Dimensional micro-islands of laser-affected material periodically distributed in amorphous matrix. The crystallization process of amorphous FeSiB ribbons was studied by means of scanning and transmission electron microscopy. Detailed microstructural examination showed that the use of laser beam, resulted in development of nanostructure in the heated areas of the amorphous ribbon. The generation of nanocrystalline seed islands created by pulsed laser interference was observed. This key result may evidently give new knowledge concerning the differences in microstructure formed during the conventional and lased induced crystallization the amorphous alloys. Further experiments are needed to clarify the effect of pulsed laser interference crystallization on magnetic properties of these alloys.
Casting porosity is the main factor influencing the fatigue properties of Al-Si alloys. Due to the increasing use of aluminum castings, porosity characterization is useful for estimating their fatigue strength. In principle, a combination of metallographic techniques and statistical pore analysis is a suitable approach for predicting the largest defect size that is critical for the casting. Here, the influence of modifiers and casting technology on the largest pore size population in AlSi7Mg alloy specimens is obtained and discussed adopting the Murakami's approach. However, porosity evaluation is a challenge in the case of microshrinkage pores, which are frequently found in industrial castings. Their complicated morphology prevents a reliable definition of an equivalent defect size based on metallographic techniques. This contribution reports the application of X-ray tomography to the 3D reconstruction of real pores in cast Al-Si alloys and provides insight into the complication of microshrinkage pore sizing by metallography.
In this study, metal matrix composite materials containing melt-spun Al-20Si-5Fe alloys and boron carbide was produced by high energy ball milling and then hot pressing at 200 MPa pressure and 450°C. Mechanical and microstructural characterizations were performed by using an optical microscopy, X-Ray diffractometer, and dynamic microhardness tester. It was observed that boron carbide particles were homogenously distributed in the microstructure and values of microhardness and elastic modules were averagely 830 MPa and 42 GPa, respectively.
The paper deals with influence of multiple remelting on AlSi9Cu3 alloy with higher iron content on chosen mechanical properties. Multiple remelting may in various ways influence mechanical, foundry properties, gas saturation, shrinkage cavity, fluidity etc. of alloy. Higher presence of iron in Al-Si cast alloys is common problem mainly in secondary (recycled) aluminium alloys. In Al-Si alloy the iron is the most common impurity and with presence of other elements in alloy creates the intermetallic compounds, which decreases mechanical properties. Iron in the used alloy was increased to about 1.4 wt. %, so that the influence of increased iron content can be investigated. In the paper, the effect of multiple remelting is evaluated with respect to the resulting mechanical properties in cast state, after the heat treatment (T5) and after natural aging. From the obtained results it can be concluded that the multiple remelting leads to change of chemical composition and affect the mechanical properties.