The objective of this work is to present an energy analysis of different absorption refrigerating systems operating with diverse refrigerants. Also is applied the method of experimental design to optimize configurations proposed by the absorption pairs used and the operating conditions. Both acceptable coefficient of performance and low operating generator temperature are scrutinised. Therefore, a computer program is developed. An investigation of the thermodynamic properties is presented. Results show the coefficient of performance evolution versus respectively the evaporator temperature, temperature of condensation and generator temperature. A particular interest is devoted to the intermediate pressure effect on the performance of different systems. In order to better converge in the selection of the configuration and the refrigerant, which can ensure a high coefficient of performance associated to relatively low operating generator temperature the plan of experiments has been developed, taking in account all parameters influencing the system performance and the function of operating temperature. Results show that the refrigerating machine containing a compressor between the evaporator and the absorber has a coefficient of performance quite acceptable and that it can work at low generator temperature for about 60 ◦C and using the NH3/LiNO3 as refrigerant.
The presented article describes the method for determining one of the trace elements occurring in coalbismuth. The subjects of the analysis were coal type 34, 35 and their fly ashes derived from Jastrzębska Spółka Węglowa. The main reason for the research was the extensive use of bismuth in many industry sectors. Additionally, bismuth is on the list of deficit elements, therefore the possibility of obtaining an alternative for its recycling source of it is needed, is required. The research was carried out using atomic absorption spectrometry with electrothermal atomization in a graphite cuvette. The samples were incinerated at 800°C and microwave mineralization in a high-pressure closed system was performed until the spectrometric analysis was achieved. In order to achieve mineralization, a mixture of HF and HNO3 acids was used to turn the samples into acidic solutions. The preparation of the samples was based on available literature data and own observations. In the experiment, the effects of the additive modifier was modified by changing the temperature in further steps: drying, incineration, cooling, atomization and burning were described. In addition, the palladium modifier was used in order to limit secondary reactions and enable the evaporation of matrix components. The measurement conditions which are presented in this article allow for a linear calibration curve to be established. However, this is not clear and the definitive method for determining the bismuth in coal is carried out through the use of ET-AAS.
Twenty-eight two-, three-, four-, and five-component amine mixtures have been evaluated as possible activators of CO2 absorption into aqueous carbonate/bicarbonate solutions. Measurements were per- formed using a pressure autoclave with a sparger at conditions close to industrial ones. On the basis of these results, a formula for a new, more efficient amine activator named INS13 was developed. The activator was tested both in a pilot plant and on an industrial scale in an ammonia plant producing 300 tons/day of ammonia. Activator INS13 was applied in a number of ammonia plants in Poland and abroad.
CO2 emission from combustion fossil fuels is considered as the primary factor in the global warming. Different methods for separation CO2 from combustion flue gases are extensively used across the world. The aim of this study is to analyze the most important technological solutions of CO2 separation. For this reason chemical absorption, physical absorption, adsorption approach, membrane filtration and cryogenic process were researched. Concluding, selection of the right method for carbon dioxide capture separation is a complex issue and a range of technological and economic factors should be taken into consideration prior to application on the industrial scale.
The present study examines some durability aspects of ambient cured bottom ash geopolymer concrete (BA GPC) due to accelerated corrosion, sorptivity, and water absorption. The bottom ash geopolymer concrete was prepared with sodium based alkaline activators under ambient curing temperatures. The sodium hydroxide used concentration was 8M. The performance of BA GPC was compared with conventional concrete. The test results indicate that BA GPC developes a strong passive layer against chloride ion diffusion and provides better protection against corrosion. Both the initial and final rates of water absorption of BA GPC were about two times less than those of conventional concrete. The BA GPC significantly enhanced performance over equivalent grade conventional concrete (CC).
A concept of a highly sensitive and fast-response airborne optoelectronic hygrometer, based on the absorption spectroscopy with laser light tuned to an intense ro-vibronic absorption line of H2O in the 1391– 1393 nm range is presented. The target application of this study is airborne atmospheric measurements, in particular at the top of troposphere and in stratosphere. The cavity ring-down spectroscopy was used to achieve high sensitivity. In order to avoid interference of the results by water desorbed from the instrument walls, the open-path solution was applied. Tests of the instrument, performed in a climatic chamber, have shown some advantages of this concept over typical hygrometers designed for similar applications.
Sound diffusers, in particular those based on changes in the phase of the reflected wave (Schroeder diffusers), have recently gained greatly in popularity in acoustics as an effective means to eliminate defects and improve the acoustic performance of interiors. This paper draws attention to a possibility of shaping acoustic parameters of sound diffusers and fundamental errors made in applying diffusers. Also, an often neglected issue of sound absorption by diffusers has been tackled. The presented results of laboratory measurements indicate a great significance of the diffusers' rigidity and geometry on their absorption coefficient at low frequencies. The effect of arrangement of elements on the diffusion coefficient was analysed for two types of elements based on the prime number N = 7.
The present paper is comparing the results of research studies carried out for three road acoustic screens of different design and different number of damping layers. For the tests, we selected timber or steel screens with a traditional multilayer structure and also one innovative type of simplified design. With respect to particular panels, their sound absorption properties were investigated in the reverberation chamber after they had been subjected to simulated weathering. In the process, two screens were subjected to the aging tests of 50–500 cycles in a special climatic chamber, and the innovative screens were subjected to 1000 cycles. The procedure was repeated every 50 or 100 cycles in order to obtain the changes of acoustic characteristics. The changes taking place in the absorbing material were also investigated with the use of scanning electron microscopy method (SEM). Basing on the obtained results and on the statistical analysis, the capability to maintain acoustic properties by the panels during their service life in natural conditions was estimated. For that purpose, linear statistical models were worked out, which were then applied to estimate the value of the single number sound absorption coefficient after successive aging cycles as well as the predicted time periods of acoustic class changes.
Measurements of the absorption rate of carbon dioxide into aqueous solutions of N-methyldiethanoloamine (MDEA) and 2-ethylaminoethanol (EAE) have been carried out. On this basis a mathematical model of the performance of an absorption column operated with aqueous solution of a blend of the above amines at elevated temperatures and pressures have been proposed. The results of simulations obtained by means of this model are described. The work is a part of a wider program, aimed at the development of a new process.
Studies to find alternative low environmental-impact materials for acoustic absorbers are still progressing, particularly those originated from natural materials. However, most of the established works are mainly focused on the fibrous-type absorbers. Discussion on the non-fibrous-type absorbers is still lacking and this therefore becomes the objective of this paper. Use of bamboo by utilizing its hollow structure to absorb sound energy is discussed here. The normal incidence absorption coefficient was measured based on the length and diameter of the bamboo, as well as different arrangement of the bamboo structure subjected to the incidence sound, namely, axial, transverse, and crossed-transverse arrangements. The trend of absorption coefficient appears in peaks and dips at equally spacing frequencies. For all arrangements the peak of absorption can reach above 0.8. Introducing an air gap behind the bamboo shifts the peak absorption to lower frequency. Covering the front surface of the absorber improves the sound absorption coefficient for axial arrangement by widening the frequency range of absorption also towards lower frequency range. The transverse arrangement is found to have average absorption coefficient peaks of 0.7 above 1.5 kHz. By arranging the bamboo structure with crossed-transverse arrangement, the suppressed absorption peaks in normal transverse arrangement can be recovered.
Fabric covering is often used by designers, as it can easily mask acoustic structures that do not match an interior. However, in the case of sound diffusers based on change in the phase of the reflected wave, the use of fabric covering is not without its effect on acoustics. It reduces the effectiveness of these structures and raises acoustic absorption. In the paper, the authors analyzed the acoustical properties of a selected fabric used to cover sound diffusers. Sound absorption and scattering coefficients for a system composed of sound diffusers and a fabric situated at different distances d were measured. The results were compared to the sound absorption predicted on the basis of Kuttruff’s and Mechel’s theoretical models. Analysis of the results indicates that the fabric has a significant influence on the system’s acoustic parameters. It is also observed, that fabric applied directly on a phase grating diffuser, produces higher absorption than when it is at some distance from it.
Sound absorption coefficient is a commonly used parameter to characterize the acoustic properties of sound absorbing materials. It is defined within the frequency range of 100-5 000 Hz. In the industrial conditions, many appliances radiating acoustic energy of the frequency range of above 5000 Hz are used and at the same time it is known that a noise within the frequency range of 5 000-50 000 Hz can have a harmful effect on people,hence there is a need to define the coefficient in this frequency range. The article presents a proposal for a method of measurement of the sound absorption coefficient of materials in the frequency range from 5 000 Hz to 50 000 Hz. This method is a modification of the reverberation method with the use of interrupted noise.
Recently, a new class of ceramic foams with porosity levels up to 90% has been developed as a result of the association of the gelcasting process and aeration of the ceramic suspension. This paper presents and discusses original results advertising sound absorbing capabilities of such foams. The authors man- ufactured three types of alumina foams in order to investigate three porosity levels, namely: 72, 88, and 90%. The microstructure of foams was examined and typical dimensions and average sizes of cells (pores) and cell-linking windows were found for each porosity case. Then, the acoustic absorption coefficient was measured in a wide frequency range for several samples of various thickness cut out from the foams. The results were discussed and compared with the acoustic absorption of typical polyurethane foams proving that the alumina foams with high porosity of 88-90% have excellent sound absorbing properties competitive with the quality of sound absorbing PU foams of higher porosity.
The paper presents results of experimental studies on removal of NOx from flue gas via NO ozonation and wet scrubbing of products of NO oxidation in NaOH solutions. The experiment was conducted in a pilot plant installation supplied with flue gas from a coal-fired boiler at the flow rate 200 m3/h. The initial mole fraction of NOx,ref in flue gas was approx. 220 ppm, the molar ratio X = O3/NOref varied between 0 and 2.5. Ozone (O3 content 1÷5% in oxygen) was injected into the flue gas channel before the wet scrubber. The effect of the mole ratio X, the NaOH concentration in the absorbent, the liquid-to-gas ratio (L/G) and the initial NOx concentration on the efficiency of NOx removal was examined. Two domains of the molar ratio X were distinguished in which denitrification was governed by different mechanisms: for X ≤ 1.0 oxidation of NO to NO2 predominates with slow absorption of NO2, for X >> 1.0 NO2 undergoes further oxidation to higher oxides being efficiently absorbed in the scrubber. At the stoichiometric conditions (X = 1) the effectiveness of NO oxidation was better than 90%. However, the effectiveness of NOx removal reached only 25%. When ozonation was intensified (X ≥ 2.25) about 95% of NOx was removed from flue gas. The concentration of sodium hydroxide in the aqueous solution and the liquid-to-gas ratio in the absorber had little effect on the effectiveness of NOx removal for X > 2.
The results of experimental investigations on the removal of NOx from gases applying ozone as the oxidizing agent and the absorption of higher nitrogen oxides in the sodium hydroxide solutions are presented. The experiment was conducted using a pilot plant installation with the air flow rate 200 m3/h, being a prototype of a boiler flue gas duct and a FGD scrubber. It was shown that in the range of [NOref] = 50 ÷ 250 ppm the mechanism of NO ozonation depends on the molar ratio X = O3/NOref: for X ≤ 1.0 oxidation of NO to NO2 predominates and NO2 is poorly absorbed, for X >> 1.0 NO2 undergoes further oxidation to N2O5, which is efficiently absorbed in the scrubber. The stoichiometric molar ratio of complete conversion of NO into N2O5 is X = 1.5, in these studies to reach the effectiveness η ≥ 90% the molar ratio X was much higher (2.75).
The solution of applications for air pollution control in foundries for iron and non-ferrous metals may not only be understood as the observance of requested emission limit values at the stack outlet. An effective environmental protection already starts with the greatest possible capture of pollutants at the source with at the same time minimisation of the volume flow necessary for this. Independent of this, the downstream installed filtration system has to realise a degree of separation of definitely above 99%. Furthermore, when selecting the filter construction, attention has to be paid to a high availability. An even temporarily production without filter will more and more no longer be accepted by residents and authorities. Incidents at the filter lead to a shutdown of the whole production. Additional measures for heat recovery while preparing concepts for filtration plants help to reduce the energy consumption and serve for a sustained conservation of environment. A consequent consideration of the items above is also condition for the fact that environmental protection in foundries remains affordable. The lecture deals with the subjects above from the point of view of a plant constructor.
Results of an extensive research program, aimed at finding new, more efficient activators of carbon dioxide absorption into aqueous carbonate/bicarbonate solutions are presented. Both single amines (2-ethyl-aminoethanol, 2-isopropyl aminoethanol, piperazine, tetraethylenepentamine, N-ethyl-piperazine and glicyne) and amine mixtures have been investigated. Absorption rate measurements were conducted in a laminar-jet absorber. Reaction rate constants for the particular activators were determined. Mixtures of aliphatic amines with cyclic amines, as well as mixtures of cyclic amines with cyclic amines were found to exhibit synergetic effect. Such amine mixtures might be used as new promoters for CO2 absorption in carbonate solutions in the modified Benfield process.
The paper describes an integrated laser absorption system as a potential tool for breath analysis for clinical diagnostics, online therapy monitoring and metabolic disorder control. The sensors operate basing on cavity enhanced spectroscopy and multi-pass spectroscopy supported by wavelength modulation spectroscopy. The aspects concerning selection of operational spectral range and minimization of interference are also discussed. Tests results of the constructed devices collected with reference samples of biomarkers are also presented. The obtained data provide an opportunity to analyse applicability of optoelectronic sensors in medical screening.
The absorption of sound in air represents one of the main problems of the scale model measurements. This absorption, especially at higher frequencies, is considerably greater than the value determined by the law of acoustical similarity between the full scale and the scale model. Different alternatives are applied for compensation of the excess air absorption including a numerical compensation. In this paper, a modified approach to numerical compensation is proposed. It is based on compensation of the sound decay only, and not background noise. As a consequence, there is no an increase of background noise in the compensated impulse response. The results obtained by the proposed procedure are compared to the corresponding ones obtained by the other procedures.
Characterization of sound absorbing materials is essential to predict its acoustic behaviour. The most commonly used models to do so consider the flow resistivity, porosity, and average fibre diameter as parameters to determine the acoustic impedance and sound absorbing coefficient. Besides direct experimental techniques, numerical approaches appear to be an alternative to estimate the material's parameters. In this work an inverse numerical method to obtain some parameters of a fibrous material is presented. Using measurements of the normal incidence sound absorption coefficient and then using the model proposed by Voronina, subsequent application of basic minimization techniques allows one to obtain the porosity, average fibre diameter and density of a sound absorbing material. The numerical results agree fairly well with the experimental data.
This paper presents the results of measurements of the sound absorption coefficient of auditorium seats carried out in the laboratory using two methods. In the first one, small blocks of seats in various arrangements were studied in a reverberation chamber to determine the absorption coefficient of an auditorium of infinite dimensions. The results were compared to the values of the absorption coefficient measured using the second method, which involved samples enclosed within a frame screening the side surfaces of other auditorium blocks. The results of both methods allowed for the assessment of the sound absorption coefficient of an auditorium of any dimensions while taking into account the sound absorption by the side surfaces. The method developed by the authors will simplify the currently known measurement procedures.
The sound absorption property of polyurethane (PU) foams loaded with natural tea-leaf fibers and luffa cylindrica (LC) has been studied. The results show a significant improvement in the sound absorption property parallel to an increase in the amount of tea-leaf fibers (TLF). Using luffa-cylindrica as a filler material improves sound absorption properties of soft foam at all frequency ranges. Moreover, an increase in the thickness of the sample resulted in an improvement of the sound absorption property. It is pleasing to see that adding tea-leaf fibers and luffa-cylindrica to the polyurethane foam demonstrate a significant contribution to sound absorption properties of the material and it encourages using environmental friendly products as sound absorption material in further studies.
In the paper the results of measurements of CO2 absorption rate in aqueous potassium carbonate solutions containing cyclohexylamine, diethanolamine, 2-methylaminoethanol and triethylenetetramine as activators have been presented. Enhnancement mass transfer factors as well as reaction rate constants have been determined. Results show that among the tested activators triethylenetetramine and 2-methyl-aminoethanol may be used (instead of diethanolamine) as new promotors in a modified BENFLIELD process.
Macroporous silica fibers having spherical cavities were fabricated by electrospinning using the spinning solution prepared from the mixed dispersion of tetraethylorthosilicate (TEOS) and polystyrene nanospheres as precursor and sacrificial templates, respectively, by injection through metallic nozzle. By applying electric field, the electro-spun fibers obtained by evaporation-driven self-assembly were collected on flat substrate or rotating drum, followed by the removal of the templates by calcination. The sound absorption coefficient of the porous fibers was measured by impedance tube, and the measured value was larger than 0.9 at high frequency region of incident waves. The surface of the resulting fibers was modified using fluorine-containing silane coupling agent to produce superhydrophobic fibrous materials to prevent the infiltration of humidity.
We fabricated two different kinds of composite materials for absorbing microwave in a frequency range of 2 to 18 GHz using coaxial airline and thru-reflect-line (TRL) method. The composite materials having carbon nanotube (CNT) with carbonyl iron (CI) or iron oxide (Fe3O4) were fabricated by mixing each components. Magnetic properties were measured by SQUID equipment. Complex permittivity and complex permeability were also obtained by measuring S-parameters of the toroidal specimen dispersing CI/CNT and Fe3O4/CNT into the 50 weight percent (wt%) epoxy resin. The real permittivity was improved by mixing the CNT however, the real permeability was same as pure magnetic powders. The CI/CNT had a maximum value of real permittivity and real permeability, 11 and 1.4 at 10 GHz, respectively. The CNT composites can be adapted to the radar absorbing materials, band width 8-12 GHz.