This study presents the rheological properties of sewage sludge after conditioning with the application of biomass ash. The impact of sewage sludge pre-treatment on its viscosity, ﬂow curves and thixotropy was investigated. The increase of shear stress and the decrease of viscosity were observed with the increase of shear rate. Obtained results were compared with raw sewage sludge and the sludge after modiﬁcation by means of polyelectrolyte in the dosage of 1.5 g (kg d.m.)-1. The ﬁndings proved that samples of raw and conditioned sewage sludge had thixotropic characteristics. The correlation between moisture content and capillary suction time reduction as well as selected rheological parameters were also determined. On the basis of the obtained results it was stated that the Ostwald de Vaele model best ﬁts the experimental data.
A ccording to the Polish Geological and Mining Law the granting of a concession for the exploration of a hydrocarbon deposit and the production of hydrocarbons from a deposit, or a concession for the production of hydrocarbons from a deposit in Poland is proceeded according to a tender procedure or open door procedure (upon a request of an entity). O n June 28, 2018 the Polish Minister of the Environment announced 5 tender areas. These areas (promising for discoveries of conventional and unconventional oil and gas deposits) were selected by the geologists of the Polish Geological Institute-NRI and Department of Geology and Geological Concessions of the Ministry of the Environment based on the geological data resources stored in the National Geological Archive. These are: Bestwina-Czechowice, Królówka, Pyrzyce, Złoczew i Żabowo. The main exploration target on the areas located in central and north-western Poland (Pyrzyce, Żabowo and Złoczew) is related to Permian Rotliegend sandstones and carbonates of the Zechstein/Main Dolomite. The Bestwina-Czechowice and Królówka areas (southern Poland) are prospective for conventional and hybrid-type accumulations of gas in the Miocene of the Carpathian Foredeep below the Carpathian Overthrust and in the Paleozoic-Mesozoic basement. The beginning of the 4th bidding round for hydrocarbon concessions is planned in Q4 2019. The entity can also choose the area and apply for a license submitting an application to the Ministry of the Environment. The area indicated by the entity cannot be the subject of a tender or any other concession, and the maximum acreage is 1,200 km2.
In the Polish sector of the Magura Nappe have long been known and exploited carbonate mineral waters, saturated with carbon dioxide, known as the “shchava (szczawa)”. These waters occur mainly in the Krynica Subunit of the Magura Nappe, between the Dunajec and Poprad rivers, close to the Pieniny Klippen Belt (PKB). The origin of these waters is still not clear, this applies to both “volcanic” and “metamorphic” hypotheses. Bearing in mind the case found in the Szczawa tectonic window and our geological and geochemical studies we suggest that the origin of the carbon dioxide may be linked with the thermal/pressure alteration of organic matter of the Oligocene deposits from the Grybów Unit. These deposits, exposed in several tectonic windows of the Magura Nappe, are characterized by the presence of highly matured organic matter – the origin of the hydrocarbon accumulations. This is supported by the present-day state of organic geochemistry studies of the Carpathian oil and gas bed rocks. In our opinion origin of the carbon-dioxide was related to the southern, deep buried periphery of the Carpathian Oil and Gas Province. The present day distribution of the carbonated mineral water springs has been related to the post-orogenic uplift and erosion of the Outer (flysch) Carpathians.