The aim of the study was to determine the effect of adding bio-components in the form of methyl esters of corn oil to the milesPLUS diesel oil on its fractional composition. The corn biofuel was produced in-house by using an own-design GW-200 reactor. The diesel fuel evaporated at temperatures ranging from 162 to 352oC. The addition of 7, 20 and 40% of a bio-component in principle does not affect the deterioration of the starting point distillation temperatures. They affect the temperature at the end of distillation to a greater extent, resulting in temperatures exceeding 360oC.