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Abstract

The paper analyses a possibility of utilising the information which is contained in DIPPR database for a calculation of the speed of sound, which is absent there. As an example, liquid hydrocarbons are considered: n-hexane, 1-hexene, cyclohexane, cyclohexene, benzene, and 1-hexanols, as well as representatives of n-alkanes with various hydrocarbon chain lengths. It is shown that the Brelvi-O’Connell correlation for the reduced bulk modulus, supplied with the correlations for the internal pressure at the normal boiling temperature, results in the values having accuracy comparable with other DIPPR data for the region below the boiling point bounded by the values of the reduced density around ρr ≈ 3.5. The source of errors originated from the Brelvi-O’Connell correlation for larger reduced densities is discussed.
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Abstract

IIn this short communication, we revise a correlation for the saturated liquid isothermal compressibility based on the data available in DIPPR (Postnikov, 2016) which considers the molecular non-sphericity and addresses a problem of predicting speeds of sound in saturated long-chained alkanes. In addition, we correct a misprint appeared in the cited work and provide programming code used for the realisation of the proposed calculations.
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